Zeolites as catalysts, sorbents, and detergent builders [recurso electrónico] applications and innovations : proceedings of an international symposium, Würzburg, F.R.G., September 4-8, 1988

This new book will be welcomed by companies involved in catalysis and catalyst manufacturing, sorbent and detergent production, chemical and petroleum refining, and by research scientists in academia. It contains 76 original contributions of recent work on fundamental and technological aspects of zeolite research and application. Particular attention is paid to novel developments in zeolite catalysis, sorption on zeolites and use of zeolites as detergent builders. Problems of zeolite synthesis, structure, modification, ion exchange, diffusion and novel applications are also dealt with. Topics which are the subject of much current interest are also treated, e.g. new catalytic applications of zeolites in the synthesis of fine chemicals, novel formulations of detergent builders and industrially developed zeolite-based separation processes. The application of zeolites is also discussed from both economic and ecological points of view. The contributions cover a wide range of materials and results which are organised, to a large extent, in tables and figures and are identified by appropriate keywords. The meeting at which these contributions were presented was the latest in a series of smaller, more specialized zeolite meetings which are held in between the large International Zeolite Conferences. Participating in the symposium were experts from both industry and academia who gave invited lectures, oral and poster presentations. The resulting book provides a large body of helpful information for present and future work and development in zeolite research and applications. Content: Edited by Page iii Copyright page Page iv Preface Page xiii Hellmut G. Karge, Jens Weitkamp Acknowledgements Page xiv Hellmut G. Karge, Jens Weitkamp International Scientific Commettee Pages xiv-xv Executive Committee Page xv Financial Support Pages xv-xvi Skeletal Rearrangement Reactions of Olefins, Paraffins and Aromatics Over Aluminophosphate Based Molecular Sieve Catalysts Original Research Article Pages 1-17 Jule A. Rabo, Regis J. Pellet, Peter K. Coughlin, Edwar S. Shamshoum Catalytic and Physical Properties of Silicon-Substituted Alpo 4 -5 Molecular Sieves Original Research Article Pages 19-27 K.J. Chao, L.J. Leu On The Nature of the Catalytic Activity of SAPO-5 Original Research Article Pages 29-38 Ch. Minchev, V. Kanazirev, V. Mavrodinova, V. Penchev, H. Lechert Molecular Orbital Calculations on the Structural and Acidic Characteristics of Aluminophosphates (AlPO), Silicoaluminophosphates (SAPO) and Metaluminophosphate (MeAPO) Based Molecular Sieves Original Research Article Pages 39-48 R. Carson, E.M. Cooke, J. Dwyer, A. Hinchliffe, P.J. O'Malley Relation Between Paraffin Isomerisation Capability and Pore Architecture of Large-Pore Bifunctional Zeolites Original Research Article Pages 49-60 J.A. Martens, M. Tielen, P.A. Jacobs Respective Influences of the Geometric and Chemical Factors in the Conversion of Aromatics Over Acidic Zeolites Original Research Article Pages 61-70 F. Fajula, M. Lambret, F. Figueras Para-Selectivity of Pentasil Zeolites Original Research Article Pages 71-80 Jong-Ho Kim, Seitaro Namba, Tatsuaki Yashima Hydrogen Spillover in the Conversion of N-Alkanes on Zeolites Original Research Article Pages 81-90 K.-H. Steinberg, U. Mroczek, F. Roessner Intermediates in the Formation of Aromatics from Propene and 2-Propanol on H-Zsm-5 Zeolites Original Research Article Pages 91-98 H. Lechert, C. Bezouhanova, C. Dimitrov, V. Nenova Zeolite and Matrix Structures and Their Role in Catalytic Cracking Original Research Article Pages 99-113 C.J. Groenenboom Evaluation of Non-Commercial Modified Large Pore Zeolites in FCC Original Research Article Pages 115-125 E. Jacquinot, F. Raatz, A. Macedo, Ch. Marcilly Surface-Metals Interactions in Fluid Cracking Catalysts During the Upgrading of Vanadium Contaminated Gas Oils Original Research Article Pages 127-142 M.L. Occelli, J.M. Stencel Highly Dispersed Pt and Pt-Cr Clusters in Pentasils and Their Activity in Transformations of Lower Alkanes Original Research Article Pages 143-152 E.S. Shpiro, G.J. Tuleuova, V.I. Zaikovskii, O.P. Tkachenko, T.V. Vasina, O.V. Bragin, Kh.M. Minachev Conversion of Light Alkanes Into Aromatic Hydrocarbons. 3. Aromatization of Propane and Propene on Mixtures of HZSM5 and of Ga 2 O 3 Original Research Article Pages 153-162 N.S. Gnep, J.Y. Doyemet, M. Guisnet Shape-Selective Catalysis in Zeolites with Organic Substrates Containing Oxygen Original Research Article Pages 163-192 R.F. Parton, J.M. Jacobs, D.R. Huybrechts, P.A. Jacobs The Use of Zeolite Catalysts for the Synthesis of Nitrogen-Containing Organic Intermediates Original Research Article Pages 193-209 W.F. Hoelderich Comparison of the Alkylation of Anisole and Phenol with Methanol on Pentasil and Ultrastable Zeolites Original Research Article Pages 211-221 Rudy F. Parton, Julia M. Jacobs, Heidi Van Ooteghem, Peter A. Jacobs Acidity Effect of Zsm-5 Zeolites on Phenol Methylation Reaction Original Research Article Pages 223-230 N.S. Chang, C.C. Chen, S.J. Chu, P.Y. Chen, T.K. Chuang A New Catalyst for Mibk Synthesis—Palladium on Zsm-5 Zeolites Original Research Article Pages 231-239 P.Y. Chen, S.J. Chu, N.S. Chang, T.K. Chuang, L.Y. Chen Acetylene Hydration on Zeolite Catalysts: An I.R. Spectroscopic Study of the Surface Species Original Research Article Pages 241-249 Gy. Onyestyak, J. Papp Jr., D. Kallo Preparation and Characterization of Mo-Hy Zeolites Original Research Article Pages 251-258 A. Meszaros-Kis, J. Valyon Propylene Metathesis Reaction Over Mo/Y-Zeolites Original Research Article Pages 259-269 M. Łaniecki Molybdenum-Oxide-Modified Pentasil Zeolites Original Research Article Pages 271-280 I.M. Harris, J. Dwyer, A.A. Garforth, C.H. McAteer, W.J. Ball Surface and Catalytic Properties of the New Zeolite Type LZ 132 Original Research Article Pages 281-294 Z. Tvaruzkova, M. Tupa, P. Jirů, A. Nastro, G. Giordano, F. Trifiro Ptrh-Doped Zeolites as Three-Way-Catalysts: Sims Analysis as a Tool for the Selection of Suitable Zeolite Types Original Research Article Pages 295-304 C. Plog, J. Haas, J. Steinwandel Transformation of Ethanethiol Over Zeolites Original Research Article Pages 305-314 M. Ziólek, P. Decyk, M. Derewiński, J. Haber Study of the Structure and the Redox Reactivity of Nax Encapsulated Co(Ii)-Phthalocyanine Original Research Article Pages 315-325 G. Schulz-Ekloff, D. Wöhrle, V. Iliev, E. Ignatzek, A. Andreev Selective Reduction of Nitric Oxide Over Zeolite-Supported Iridium Catalyst Original Research Article Pages 327-336 Roar Myrdal, Stein Kolboe Metal-Doped Zeolites for Selective Catalytic Reduction of Nitrogen Oxides in Combustion Gases Original Research Article Pages 337-346 J. Haas, J. Steinwandel, C. Plog Preparation of Nihzsm-5 Catalyst for Isomerization of C 8 Aromatics. Solid-State Incorporation of Nickel Original Research Article Pages 347-353 B. WichterlovÁ, S. Beran, L. KubelkovÁ, J. Nováková, A. Smiešková, R. àebík Formation of Carbocations from C 6 Compounds in Zeolites Original Research Article Pages 355-364 Imre Kiricsi, Horst Förster, Gyula Tasi An Infrared and Catalytic Study of Isomorphous Substitution in Pentasil Zeolites Original Research Article Pages 365-375 M.F.M. Post, T. Huizinga, C.A. Emeis, J.M. Nanne, W.H.J. Stork Calorimetric Investigation of the Acidity of Dealuminated Y-Type Zeolites using Various Basic Probes Original Research Article Pages 377-387 A. Auroux, Z.C. Shi, N. Echoufi, Y. Ben Taarit The Acidity of a Modified Faujasite Structure, Zeolite CSZ-1 Original Research Article Pages 389-397 S. Cartlidge, R.L. Cotterman, M.L. Howes Control of catalytic properties of ZSM-5 made by fast and template- free synthesis. Original Research Article Pages 399-408 A. Tissler, P. Polanek, U. Girrbach, U. Müller, K.K. Unger Theoretical Studies of Bronsted Acidity in Zeolites Original Research Article Pages 409-419 R. Vetrivel, C.R.A. Catlow, E.A. Colbourn, M. Leslie Nmr and Ir Studies of Zeolites of the Erionite Type Original Research Article Pages 421-427 F. Roessner, K.-H. Steinberg, D. Freude, M. Hunger, H. Pfeifer Specific Platinum Particles Properties in Basic Zeolites Original Research Article Pages 429-438 A. de Mallmann, D. Barthomeuf Fundamental Research and Modeling for a Technical Process of Selective Adsorption of Normal Paraffins (“Parex”-Process of Ddr) by Zeolite A Original Research Article Pages 439-450 W. Schirmer, K. Fiedler, H. Stach, M. Suckow Sorbex Technology for Industrial Scale Separation Original Research Article Pages 451-467 J.A. Johnson, A.R. Oroskar Gas Oil Dearomatization by Adsorption Original Research Article Pages 469-476 A. Laktic, J. Mühl, I. Beck, M. Beer Modeling Diffusion Pathways in MFI Materials by Time-Resolved Powder Diffraction Techniques Original Research Article Pages 477-484 B.F. Mentzen Measurement of Intracrystalline Diffusivities of Hzsm-5 Zeolite At Higher Temperatures and Predictions of Shape Selectivity Original Research Article Pages 485-494 K. Hashimoto, T. Masuda, M. Kawase Measurement of Hydrocarbon Diffusion Coefficient in a Non-Isobaric Chromatographic Column of Zeolite Crystal Powder Original Research Article Pages 495-504 E. Aust, W. Hilgert, G. Emig Molecular Mobility of Benzene and p-Xylene in Mfi Type Zeolites Original Research Article Pages 505-517 M. Bulow, J. Caro, B. Röhl-Kuhn, B. Zibrowius Diffusion of n-HEXANE and 3-Methylpentane in H-Zsm-5 Crystals of Various Sizes Original Research Article Pages 519-531 P. Voogd, H. Van Bekkum A Comparative Study By Deuteron Solid State NMR Spectroscopy of The Dynamics of Benzene and Olefins in Faujasite- and Mordenite- Type Zeolites Original Research Article Pages 533-543 B. Boddenberg, R. Burmeister, G. Spaeth Probing the Hydrogen Sorption States in Zeolites a by Infrared Spectroscopy and Low-Temperature Gas Chromatography Supplemented by Theoretical Calculations Original Research Article Pages 545-554 H. Förster, W. Frede, G. Peters Fourier-Transform Infra-Red Photoacoustic Spectroscopy, A Useful Technique for the Study of Strongly Physisorbed Molecules Original Research Article Pages 555-566 J. Philippaerts, E.F. Vansant, Y.A. Yan Adsorption Properties of Large Crystals of ZSM-5 Zeolite As A Function of The Degree of Dealumination Original Research Article Pages 567-574 J. Kornatowski, M. Rozwadowski, A. Gutsze, K.E. Wisniewski Self-Consistent-Charge X α Calculations on Sorption Complexes of Nitrous Oxide Attached To Transition Metal Occupied Zeolite Clusters Original Research Article Pages 575-584 O. Zakharieva-Pencheva, M. Grodzicki, H. Förster IR Study of The Adsorption of Benzene on HZSM5 Original Research Article Pages 585-594 Andreas Jentys, Johannes A. Lercher Adsorption Separation of Methylnaphthalene Isomers on X and Y Zeolites Original Research Article Pages 595-606 V. Solinas, R. Monaci, E. Rombi, H. Morbidelli Oxygen Enrichment of Air With Molecular Sieve Zeolites Using The Psa/Vsa Technique Original Research Article Pages 607-614 Gerhard Reiss Adsorption and Diffusion of Different Hydrocarbons in MFI Zeolite of Varying Crystallite Sizes Original Research Article Pages 615-623 D.H. Lin, V. Ducarme, G. Coudurier, J.C. Vedrine High Resolution Sorption Studies of Argon and Nitrogen on Large Crystals of Aluminophosphate AlPO 4 -5 AND ZEOLITE ZSM-5 Original Research Article Pages 625-634 U. Müller, K.K. Unger, Dongfeng Pan, A. Mersmann, Y. Grillet, F. Rouquerol, J. Rouquerol A New Potential Large-Scale Application of Zeolites As Fire-Retardant Material Original Research Article Pages 635-644 H.K. Beyer, G. Borbéaly, P. Miasnikov, P. Róazsa Hindustrial Production of Zeolites Original Research Article Pages 645-659 E. Roland Calcium and Magnesium Exchange in Na-A, Na-X and Their Precursor Gels Original Research Article Pages 661-672 Lovat V.C. Rees Fundamentals of Phosphate Substitution in Detergents By Zeolites: cobuilders and optical brighteners Original Research Article Pages 673-690 M.J. Schwuger, M. Liphard Zeolite A - A Builder for Liquid Detergents? Original Research Article Pages 691-699 W. Leonhardt, B.-M. Sax Development and Performance of Zeolite-A-Built Non-Phosphate Detergents Original Research Article Pages 701-709 H. Upadek, P. Krings Simultaneous Separation of Suspended Solids, Ammonium and Phosphate Ions from Waste Water by Modified Clinoptilolite Original Research Article Pages 711-719 J. Olah, J. Papp, A. Meszaros-Kis, G.Y. Mucsi, D. Kallo Framework and Non-Framework Al Species in Dealuminated Zeolite Y Original Research Article Pages 721-734 P.J. Grobet, H. Geerts, M. Tielen, J.A. Martens, P.A. Jacobs Characterization of Calcined FAPO-5 Original Research Article Pages 735-747 S. Schubert, H.M. Ziethen, A.X. Trautwein, F. Schmidt, Huong-Xin Li, J.A. Martens, P.A. Jacobs Control of Pore-Opening Size of Zeolites Original Research Article Pages 749-758 Y.F. Chu, C.F. Keweshan, E.F. Vansant A New Structural-Modification Technique for Zeolites: Chemisorption of Si 2 H 6 Original Research Article Pages 759-767 Yongan Yan, J. Verbiest, J. Philippaerts, E.F. Vansant, P. De Hulsters Dealumination of the Zeolites Offretite and Erionite Studied by Solid-State 29 Si- and 27 Al-Mas Nmr Spectroscopy Original Research Article Pages 769-777 Karl Petter Lillerud, Michael Stöcker Galliation and 18 O-exchange Reactivities of ZSM-5 and ZSM-11 Original Research Article Pages 779-788 A. Endoh, K. Nishimiya, K. Tsutsumi, T. Takaishi Thermal Decomposition of Ironpentacarbonyl in Zeolites of Faujasite Type. A Study of the Influence of Argon, H 2 , H 2 /CO Gas Mixture and Various Si/Al Ratios Using Mössbauer, ESR and MASS Spectroscopy Original Research Article Pages 789-800 H.M. Ziethen, A.X. Trautwein Investigation of Ultra Stable Y by Differential Thermal Analysis after Injection of Water Vapour Original Research Article Pages 801-809 A. Yoshida, K. Inoue Properties of Hydrothermal Low-Damaged 5A and 10X Zeolites Original Research Article Pages 811-819 R. Schöllner, H. Siegel Phase Transformations and Changes in Lattice Parameters of ZSM-5 As A Function of Al Content and Temperature Original Research Article Pages 821-826 G.T. Kokotailo, L. Riekert, A. Tissler The Effect of Sorbates and Elevated Temperatures on the Structures of Some Zeolite Catalysts Original Research Article Pages 827-842 C.A. Fyfe, G.T. Kokotailo, H. Strobl, H. Gies, G.J. Kennedy, C.T. Pasztor, G.E. Barlow The Effect of Temperature and Sorption of P-Xylene and Benzene on The Structure of ZSM-5 Original Research Article Pages 843-848 G.T. Kokotailo, L. Riekert, A. Tissler The Characterization of Modified ZSM-5 Catalysts Prepared Via a Solid State Reaction for Propane Aromatization Original Research Article Pages 849-858 Yang Yashu, Guo Xiexian, Deng Maicun, Wang Limin, Fu Zaihui Author Index Pages 859-862 Subject Index Pages 863-867 Studies in Surface Science and Catalysis Pages 869-871 This new book will be welcomed by companies involved in catalysis and catalyst manufacturing, sorbent and detergent production, chemical and petroleum refining, and by research scientists in academia. It contains 76 original contributions of recent work on fundamental and technological aspects of zeolite research and application. Particular attention is paid to novel developments in zeolite catalysis, sorption on zeolites and use of zeolites as detergent builders. Problems of zeolite synthesis, structure, modification, ion exchange, diffusion and novel applications are also dealt with. Topics which are the subject of much current interest are also treated, e.g. new catalytic applications of zeolites in the synthesis of fine chemicals, novel formulations of detergent builders and industrially developed zeolite-based separation processes. The application of zeolites is also discussed from both economic and ecological points of view. The contributions cover a wide range of materials and results which are organised, to a large extent, in tables and figures and are identified by appropriate keywords. The meeting at which these contributions were presented was the latest in a series of smaller, more specialized zeolite meetings which are held in between the large International Zeolite Conferences. Participating in the symposium were experts from both industry and academia who gave invited lectures, oral and poster presentations. The resulting book provides a large body of helpful information for present and future work and development in zeolite research and applications