Thermal analysis : proceedings of the sixth International conference on thermal analysis, Bayreuth, Federal Republic of Germany, July 6-12, 1980. Vol. 1, Theory, instrumentation, applied sciences, industrial applications

Front Matter ....Pages I-XIII Front Matter ....Pages XV-XV Thermal Analysis in Inorganic Solid State Chemistry (H. R. Oswald)....Pages 1-12 Some Applications of Thermal Analysis to the Communications and Electronics Industry (P. K. Gallagher)....Pages 13-25 Front Matter ....Pages 27-27 Kinetic Compensation Effect: Facts and Fiction of Linear Plots Using Arrhenius Law (J. Šesták)....Pages 29-34 Regularities in the Kinetics of Thermal Dissociation of Solids (Janusz. J. Pysiak)....Pages 35-40 The Determination of the Straight Line Correlation Factors (Z. Sz. Kolenda, J. Norwisz, N. Hajduk)....Pages 41-50 Theoretical Thermogravimetric Analysis at Constant Heating Rates (C. Comel, J. Veron, C. Bouster, P. Vermande)....Pages 51-56 A Comparison of Different Methods for the Estimation of Kinetic Data (Jürgen Moll, Detlef Krug, Dorothee Zepf)....Pages 57-62 Experimental Requirements for the Determination of Kinetics and Mechanism for Decomposition Reactions of Solids (A. Reller, H. R. Oswald)....Pages 63-68 Some Remarks on the Applicability of the Arrhenius Model in Thermal Analysis (M. Arnold, G. E. Veress, J. Paulik, F. Paulik)....Pages 69-73 Kinetic Characterization of the Oscillatory Belousov-Zhabotinsky Reaction at Linearly Increased Temperature (E. Koch, B. Stilkerieg)....Pages 75-80 Characteristics of Interface Endothermic Reactions Reconsidered from a Few Simple Experiments (A. Mokhlisse, G. Bertrand, M. Lallemant, N. Roudergues)....Pages 81-86 Error Analysis in Thermal Purity Determinations (Gy. Kiss, K. Seybold, T. Meisel)....Pages 87-92 Influence of Experimental Variables on DSC Curves (A. A. van Dooren)....Pages 93-98 Influence of Mass and Grain Size on the Basic Geometry of the DTA Curve (Živan D. Živković)....Pages 99-104 A Comparison of DTA Evaluating Methods of DTA Experiments with Tertiary Butylperpivalate as a Testing Substance (R. B. Barendregt, J. Verhoeff, P. J. Van den Berg)....Pages 105-111 A Comparison of the Kinetics for the Thermal Decomposition of Ba(OH)2·H2O Obtained by TG and EGA Techniques (P. K. Gallagher, E. M. Gyorgy)....Pages 113-118 Kinetic Analysis from Thermogravimetric Traces (T. P. Prasad, M. S. R. Swami)....Pages 119-125 A Spline Interpolation Method to Study Kinetics from Isothermal and Non-Isothermal Thermogravimetry (C. G. R. Nair, P. M. Madhusudanan)....Pages 127-132 Improvement of Differential Correction Method for Evaluation of Kinetic Parameters from TG Curves (P. H. Fong, S. P. Wong, D. T. Y. Chen)....Pages 133-138 Relation between the Kinetics and Thermodynamics in the Endothermic Decomposition of Solids (Z. Jerman)....Pages 139-144 Determination of the Mechanism of Thermal Decomposition Reactions of Solids by Using the Cyclic and Constant Decomposition Rate Thermal Analysis Method (J. M. Criado)....Pages 145-148 A New Isothermal DTA Method for the Study of Surfactants at Liquid Surfaces (H. K. Cammenga, H.-J. Petrick)....Pages 149-154 The Ge-Sb-Bi Ternary Phase Diagram (S. Suriñach, M. D. Baró, F. Tejerina)....Pages 155-160 Front Matter ....Pages 161-161 Dehydration of Crystallization Water in Salts Using a New Designed Controlled-Water Vapor Micro DTA (M. Taniguchi, H. Moriguchi, S. Shimizu)....Pages 163-168 “Open System” DSC: A New Approach of Isothermal Investigations (Pierre Le Parlouër)....Pages 169-173 Thermovoltaic Detection: A New Technique for the Study of Thermal Decomposition Reactions (W. W. Wendlandt)....Pages 175-175 Thermal Hazard Evaluation by an Accelerating Rate Calorimeter (J. C. Tou, L. F. Whiting, D. I. Townsend)....Pages 177-182 Estimation of Instantaneous Caloric Effect in the Heat Exchange Type of Calorimetry (M. Nakanishi, S. Fujieda)....Pages 183-188 Thermoanalitical Investigations on Solid — Vapour Reactions (S. Gál, J. Sztatisz, L. Fodor)....Pages 189-194 Isothermal Thermogravimetric Analyzer Using Infrared Image Furnace and Microcomputer System (Akikazu Maesono, Masahiko Ichihasi, Koichiro Takaoka, Akira Kishi)....Pages 195-200 Temperature Calibration in Thermogravimetry (Paul D. Garn, Oscar Menis, Hans-Georg Wiedemann)....Pages 201-206 Convection Effects in Thermogravimetry: Significance and Corrections (Bengt O. Haglund, Torsten Luks)....Pages 207-212 Errors in Thermogravimetric Experiments Resulting from Adsorption on the Counterweight (E. Robens)....Pages 213-218 Microcomputer-Controlled Dilatometer with Infrared Rapid Heating System and Its Application (Akikazu Maesono, Masahiko Ichihashi, Akira Kishi, Koichiro Takaoka, Zenshiro Hara, Kiyoaki Akechi)....Pages 219-224 Dynamic Elasticity Measurements on Plastics (B. Andrejs, J. P. Schulz, E. Wappler)....Pages 225-230 Densification Studies of Ceramic Powder Compacts by Quasi-Isothermal Dilatometry (O. Toft Sørensen)....Pages 231-236 A Simultaneous TG-DTA System for Operation from -150°C to 1500°C (E. L. Charsley, J. Joannou, A. C. F. Kamp, M. R. Ottaway, J. P. Redfern)....Pages 237-244 Techniques for Coupling Mass Spectrometry to Thermogravimetry (Jen Chiu, A. J. Beattie)....Pages 245-249 Further Development and Application of a Combined System for Simultaneous Thermal Analysis and Mass Spectrometry (Erwin Kaisersberger)....Pages 251-257 High-Sensitivity Multichannel DTA Apparatus (Michio Maruta, Yoshiomi Kunimatsu, Kiyotsugu Yamada)....Pages 259-264 A Microcomputer Based DTA (R. L. Fyans, J. S. Mayer, W. P. Brennan)....Pages 265-271 New Control Module for DSC, DTA, TMA and TGA (E. Wappler, U. Kurpjuweit)....Pages 273-277 A New Instrument for Simultaneous Differential Thermal Analysis and Thermomicroscopy (W. Perron, G. Bayer, H. G. Wiedemann)....Pages 279-284 Transmitted Light Hot Stage Microscopy in the Temperature Range -180°C to 600°C (E. L. Charsley, A. C. F. Kamp, Jennifer A. Rumsey)....Pages 285-291 Application of Area-Thermocouples in the Thermal Analysis of Amorphous Thin Films (W. Ludwig)....Pages 293-298 A New Apparatus for Study of Stabilities in Horizontal Air Layers Heated from Below (B. Krstic)....Pages 299-304 Partial Pressure Measurement by the Flow Method (E. Marti, A. Geoffroy, B. F. Rordorf, M. Szelagiewicz)....Pages 305-312 Vapor Pressure Methods for Industrial Applications (B. F. Rordorf, A. Geoffroy, M. Szelagiewicz, E. Marti)....Pages 313-318 The Use of Subambient Thermal Volatilisation Analysis to Study Volatile Products of Polymer Degradation (I. C. McNeill)....Pages 319-324 Front Matter ....Pages 325-325 DTA/EGA Using a Specific Detector (S. B. Warrington, P. A. Barnes)....Pages 327-333 Quantitative Differential Thermal Analysis at Elevated Pressures (Prakash C. Jain, Deoraj Chaubey)....Pages 335-340 The Treatment of Thermoanalytical Data for Effective Presentation (J. S. Crighton, K. M. Li)....Pages 341-343 Equilibrium Shrinkage-Force Measurement — A Method Describing the State of Order of Pet-Fibres (Hans-Joachim Berndt, Gerhard Heidemann)....Pages 345-349 Thermometric Titrimetry — A Suitable Way into Thermochemistry (L. Stäudel, G. Thiel, H. Wöhrmann)....Pages 351-356 Sintering of Corundum with Ammonium Fluoride (A. M. Abdel Rehim)....Pages 357-362 Thermal Analysis of Concrete (A. Jarmontowicz, R. Krzywobłocka-Laurow)....Pages 363-367 Application of Thermal Analysis to the Investigation of Phase Composition of Autoclaved Cement Pastes and Mortars (Irena Stebnicka - Kalicka)....Pages 369-374 Effect of Elevated Temperatures on the Hydration of Cement Investigated by Emanation Thermal Analysis (Vladimír Balek, Jiří Dohnálek, Wolf-Dieter Emmerich)....Pages 375-380 A Thermogravimetric Method for Studying the Reaction between Fly-Ash and the Calcium Hydroxide Liberated on Hydration of Portland Cement (F. G. Buttler, S. R. Morgan)....Pages 381-386 Application of Temperature Programmed Sorption and Reaction and of DTA Data to the Characterization of Bismuth Molybdate Catalysts (A. Alsdorf, K. Habersberger, K.-H. Schnabel, W. Walkov)....Pages 387-392 Thermal Decomposition of Aqueous Manganese Nitrate Solutions (T. J. W. de Bruijn, W. A. de Jong, P. J. van den Berg)....Pages 393-398 Nitric Acid and Ammonia Concentrations as Factors Controlling the Thermal Decomposition of Ammonium Nitrate (A. Kołaczkowski, A. Biskupski)....Pages 399-402 Thermal Behaviour of Ge.25Te.60Se.15 Investigated by Emanation Thermal Analisis and DTA (Santiago Bordas, Montserrat Geli, Vladimir Balek, Miroslav Vobořil)....Pages 403-408 Differential Thermal Analysis of Phosphate-Stabilized Ca2SiO4 (R. Halle, V. Carin)....Pages 409-414 Phase Study of the Praseodymium-Oxygen System by the Multiple Thermal Analysis (Yasutoshi Saito, Seihiro Sasaki, Toshio Maruyama)....Pages 415-419 Investigation of the Decomposition of the Solid Solution of a Commercial Al-Zn-Mg Alloy (7015), by Means of DTA, Hardness and Conductivity Measurements (C. G. Cordovilla, E. Louis)....Pages 421-426 Thermal Investigation of Polyethylen Used in Power Cables (G. Liptay, L. Ligethy, E. Brandt-Petrik)....Pages 427-432 Low Temperature Regeneration of Activated Carbon. Kinetic Analysis of Thermodesorption of Phenol (V. Amicarelli, G. Baldassarre, L. Liberti)....Pages 433-438 Development of Temperature Distribution Inside the Reaction Zone of a Burning Cigarette (Richard R. Baker)....Pages 439-444 Thermal Analysis as an Aid to the Criminalist (R. Halonbrenner)....Pages 445-450 Front Matter ....Pages 451-451 Thermoanalytical Characterization of Curing Behavior of Clear Varnishes (H. Möhler, K. D. Gauler, A. Henig, G. Janik, M. Jäth)....Pages 453-460 Calorimetric Analysis of Polymer Fabrication (H. Weber, U. Guggisberg)....Pages 461-466 Thermo-Analytical Techniques in the Assessment of Mechanical Properties at Elevated Temperatures of Polyester-Glass Composites (P. K. Datta, T. R. Manley)....Pages 467-475 Thermal Analysis of RTV Silicone Rubbers usen in High Voltage Cable Accessories (G. Liptay, L. Ligethy, J. Nagy)....Pages 477-482 The New Method of the Power Current Electrotechnology — The Method of Thermal Analysis (Zbyněk Kraus, Václav Mentlík)....Pages 483-487 Objective Determination of the State of Insulations by the Difference Thermal Analysis (Václav Mentlík, Zbyněk Kraus)....Pages 489-492 A DSC Study of Glasses Obtained from Organometallic Gels (V. Gottardi, G. Scarinci, G. Carturan, A. Marchetti, V. Frosini)....Pages 493-497 Thermal Analysis Studies of the Decomposition of Ammonium Uranyl Carbonate (AUC) under Simulated Industrial Conditions (Lars Hälldahl, O. Toft Sörensen)....Pages 499-504 Thermal Studies of Contracting Gas Bubbles in Molten Glass (C. Parton, D. Dollimore)....Pages 505-509 Quantitative Phase Analysis in the System CaSO4.xH2O by TG-DTA Methods (Winfried Hädrich, Erwin Kaisersberger)....Pages 511-516 Reactivity of Lime and Related Materials with Sulphur Dioxide (D. R. Glasson, P. O’Neill)....Pages 517-522 Determination of Nitric Acid in Nitrating Mixtures (F. Oehme)....Pages 523-527 Water Determination by DIE Method (P. Marik-Korda)....Pages 529-534 Investigation of Vegetable Oils with Derivatograph (I. Buzás, S. Gál, J. Simon)....Pages 535-539 Differential Scanning Calorimetry — Scope and Limitations of Its Use as a Tool for Estimating the Reaction Dynamics of Potentially Hazardous Chemical Reactions (Ruedi Gygax, Max W. Meyer, Franz Brogli)....Pages 541-548 Differential Scanning Calorimetry — A Powerful Screening Method for the Estimation of the Hazards Inherent in Industrial Chemical Reactions (Franz Brogli, Ruedi Gygax, Max W. Meyer)....Pages 549-554 Non-Isothermal Kinetics — A Generalized Approach (Hem Shanker Ray)....Pages 555-559 Industrial Experience with Heat Flow Calorimetry (W. Regenass)....Pages 561-566 Thermoanalytical Study on Fertilizer Components and Their Mixtures (Maija-Liisa Friman, Markku Leskelä, Lauri Niinistö, Erkki Aalto, Antero Hörkkö, Juhani Poukari)....Pages 567-570 DSC Measurements on the Effect of Additives in Cutting Oils (U. Kurpjuweit, E. Wappler, W. Keil)....Pages 571-576 Thermoanalytical Study of β-FeOOH Obtained by Homogeneous Precipitation with Urea (Ma Emilia García-Clavel, Sara Goñi-Elizalde)....Pages 577-582 Thermal Analysis in Earth Sciences (G. Lombardi)....Pages 583-584 Back Matter ....Pages 585-612