The Properties of Gases and Liquids, Fifth Edition

Must-have reference for processes involving liquids, gases, and mixtures Reap the time-saving, mistake-avoiding benefits enjoyed by thousands of chemical and process design engineers, research scientists, and educators. Properties of Gases and Liquids, Fifth Edition, is an all-inclusive, critical survey of the most reliable estimating methods in use today --now completely rewritten and reorganized by Bruce Poling, John Prausnitz, and John O’Connell to reflect every late-breaking development. You get on-the-spot information for estimating both physical and thermodynamic properties in the absence of experimental data with this property data bank of 600+ compound constants. Bridge the gap between theory and practice with this trusted, irreplaceable, and expert-authored expert guide -- the only book that includes a critical analysis of existing methods as well as hands-on practical recommendations. Areas covered include pure component constants; thermodynamic properties of ideal gases, pure components and mixtures; pressure-volume-temperature relationships; vapor pressures and enthalpies of vaporization of pure fluids; fluid phase equilibria in multicomponent systems; viscosity; thermal conductivity; diffusion coefficients; and surface tension. (20011201) Cover Page......Page 1 Title Page......Page 2 ISBN 0070116822......Page 3 Contents (with page links)......Page 5 Preface......Page 9 1-1 Introduction......Page 13 1-3 Types of Estimation......Page 15 1-4 Organization of the Book......Page 18 2-1 Scope......Page 23 2-2 Vapor-Liquid Critical Properties......Page 24 2-3 Acentric Factor......Page 45 2-4 Boiling and Freezing Points......Page 48 2-5 Discussion of Estimation Methods for Pure Component Constants......Page 55 2-6 Dipole Moments......Page 56 2-7 Availability of Data and Computer Software......Page 57 3-1 Scope and Definitions......Page 61 3-2 Estimation Methods......Page 65 3-3 Method of Joback......Page 66 3-4 Method of Constantinou and Gani (CG)......Page 68 3-5 Method of Benson [1968; 1969]......Page 74 3-6 Discussion and Recommendations......Page 106 3-7 Heat of Combustion......Page 107 4-2 Introduction to Volumetric Properties......Page 111 4-3 Corresponding States Principle......Page 115 4-4 Equations of State......Page 118 4-5 Virial Equation of State......Page 121 4-6 Analytical Equations of State......Page 127 4-7 Nonanalytic Equations of State......Page 135 4-8 Discussion of Equations of State......Page 141 4-9 PVT Properties of Liquids—General Considerations......Page 142 4-10 Estimation of the Liquid Molar Volume at the Normal Boiling Point......Page 143 4-11 Saturated Liquid Densities as a Function of Temperature......Page 145 4-12 Compressed Liquid Densities......Page 153 5-1 Scope......Page 163 5-2 Mixture Properties—General Discussion......Page 164 5-3 Corresponding States Principle (CSP): The Pseudocritical Method......Page 167 5-4 Virial Equations of State for Mixtures......Page 170 5-5 Analytical Equations of State for Mixtures......Page 174 5-6 Nonanalytic Equations of State for Mixtures......Page 180 5-7 Discussion of Mixture Equations of State......Page 184 5-8 Densities of Liquid Mixtures at Their Bubble Point......Page 185 5-9 Densities of Compressed Liquid Mixtures......Page 188 6-2 Fundamental Thermodynamic Relationships for Pure Components......Page 195 6-3 Departure Functions for Thermodynamic Properties......Page 198 6-4 Evaluation of Departure Functions for Equations of State......Page 200 6-5 Heat Capacities of Real Gases......Page 210 6-6 Heat Capacities of Liquids......Page 211 6-7 Partial Properties and Fugacities of Components in Mixtures......Page 220 6-8 True Critical Points of Mixtures......Page 224 7-2 Theory......Page 229 7-3 Correlation and Extrapolation of Vapor-Pressure Data......Page 231 7-4 Ambrose-Walton Corresponding-States Method......Page 235 7-5 Riedel Corresponding-States Method......Page 237 7-6 Discussion and Recommendations for Vapor-Pressure Estimation and Correlation......Page 239 7-7 Enthalpy of Vaporization of Pure Compounds......Page 241 7-8 Estimation of ΔH[sub(v)] from Vapor-Pressure Equations......Page 242 7-9 Estimation of ΔH[sub(v)] from the Law of Corresponding States......Page 244 7-10 ΔH[sub(v)] at the Normal Boiling Point......Page 247 7-11 Variation of ΔH[sub(v)] with Temperature......Page 251 7-12 Discussion and Recommendations for Enthalpy of Vaporization......Page 252 7-13 Enthalpy of Fusion......Page 253 7-14 Enthalpy of Sublimation; Vapor Pressures of Solids......Page 256 8-1 Scope......Page 263 8-2 Thermodynamics of Vapor-Liquid Equilibria......Page 271 8-3 Fugacity of a Pure Liquid......Page 273 8-5 Activity Coefficients; Gibbs-Duham Equation and Excess Gibbs Energy......Page 274 8-6 Calculation of Low-Pressure Binary Vapor-Liquid Equilibria with Activity Coefficients......Page 281 8-7 Effect of Temperature on Low-Pressure Vapor-Liquid Equilibria......Page 284 8-8 Binary Vapor-Liquid Equilibria: Low-Pressure Examples......Page 285 8-9 Multicomponent Vapor-Liquid Equilibria at Low Pressure......Page 294 8-10 Determination of Activity Coeffcients......Page 304 8-11 Phase Equilibrium with Henry's Law......Page 373 8-12 Vapor-Liquid Equilibria with Equations of State......Page 382 8-13 Solubilities of Solids in High-Pressure Gases......Page 420 8-14 Liquid-Liquid Equilibria......Page 421 8-15 Phase Equilibria in Polymer Solutions......Page 439 8-16 Solubilities of Solids in Liquids......Page 442 8-17 Aqueous Solutions of Electrolytes......Page 453 8-18 Concluding Remarks......Page 455 9-2 Definitions of Units of Viscosity......Page 467 9-3 Theory of Gas Transport Properties......Page 468 9-4 Estimation of Low-Pressure Gas Viscosity......Page 470 9-5 Viscosities of Gas Mixtures at Low Pressures......Page 481 9-6 Effect of Pressure on the Viscosity of Pure Gases......Page 495 9-7 Viscosity of Gas Mixtures at High Pressures......Page 513 9-8 Liquid Viscosity......Page 517 9-9 Effect of High Pressure on Liquid Viscosity......Page 521 9-10 Effect of Temperature on Liquid Viscosity......Page 522 9-11 Estimation of Low-Temperature Liquid Viscosity......Page 525 9-12 Estimation of Liquid Viscosity at High Temperatures......Page 541 9-13 Liquid Mixture Viscosity......Page 543 10-2 Theory of Thermal Conductivity......Page 565 10-3 Thermal Conductivities of Polyatomic Gases......Page 566 10-5 Effect of Pressure on the Thermal Conductivities of Gases......Page 582 10-6 Thermal Conductivities of Low-Pressure Gas Mixtures......Page 593 10-7 Thermal Conductivities of Gas Mixtures at High Pressures......Page 599 10-8 Thermal Conductivities of Liquids......Page 606 10-9 Estimation of the Thermal Conductivities of Pure Liquids......Page 608 10-10 Effect of Temperature on the Thermal Conductivities of Liquids......Page 615 10-11 Effect of Pressure on the Thermal Conductivities of Liquids......Page 616 10-12 Thermal Conductivities of Liquid Mixtures......Page 620 11-2 Basic Concepts and Definitions......Page 635 11-3 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Prediction from Theory......Page 639 11-4 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Empirical Correlations......Page 643 11-5 The Effect of Pressure on the Binary Diffusion Coefficients of Gases......Page 646 11-7 Diffusion in Multicomponent Gas Mixtures......Page 653 11-8 Diffusion in Liquids: Theory......Page 654 11-9 Estimation of Binary Liquid Diffusion Coefficients at Infinite Dilution......Page 655 11-10 Concentration Dependence of Binary Liquid Diffusion Coefficients......Page 667 11-11 The Effects of Temperature and Pressure on Diffusion in Liquids......Page 672 11-12 Diffusion in Multicomponent Liquid Mixtures......Page 675 11-13 Diffusion in Electrolyte Solutions......Page 677 12-2 Introduction......Page 691 12-3 Estimation of Pure-Liquid Surface Tension......Page 692 12-4 Variation of Pure-Liquid Surface Tension with Temperature......Page 701 12-5 Surface Tensions of Mixtures......Page 702 Appendix A: Property Data Bank......Page 719 Appendix B: Lennard-Jones Potentials as Determined from Viscosity Data......Page 779 Appendix C: Group Contributions for Multiproperty Methods......Page 781 C......Page 793 D......Page 794 E......Page 795 G......Page 796 L......Page 797 R......Page 798 T......Page 799 V......Page 800 W......Page 801 ABOUT THE AUTHORS......Page 803

latest Estimation Methods And Property Values

*validated Databank

*tested Estimation Methods

*pure Substances And Mixtures

*thermodynamics, Phase Equilibria, And More

*fully Worked Examples

*instantly Usable Information

bridge The Gap Between Theory And Practice With This Expert Guide. You’ll Reap The Time-saving, Mistake-avoiding Benefits Already Enjoyed By Thousands Of Chemical And Process Design Engineers, Research Scientists, And Educators. Trusted, Irreplaceable, And Expert-authored, This Is The Only Book That Includes A Critical Analysis Of Existing Methods As Well As Hands-on Practical Recommendations.

bruce E. Poling Is Professor Of Chemical Engineering And Associate Dean Of Engineering At The University Of Toledo (ohio). He Has Taught And Conducted Research For Over 30 Years In The Areas Of Thermodynamics, Physical Properties, And Process Design.

john M. Prausnitz Is Professor Of Chemical Engineering At The University Of California At Berkeley. He Has Extensive Physical Property Experience As A Consultant On Petroleum, Natural Gas, Petrochemical, Cryogenic, And Polymeric Processes. He Is A Member Of The National Academy Of Sciences And The National Academy Of Engineering.

john P. O’connell Is The Harry Douglas Forsythe Professor Of Chemical Engineering At The University Of Virginia. He Has 35 Years Of Experience In Teaching, Research, And Consulting In Physical Properties And Process Design.

kunesh, John - Aiche Journal

ever Since The First Edition Of This Work Was Published In 1958, It Has Been A Must Have In The Reference Library Of Chemical Engineers, Particularly Those Engaged In Process Design. It Has Long Been The Primary Reference For Anyone Who Must Estimate Physical Or Thermodynamic Properties Required For Equipment Design Knowing Little More Than The Chemical Formula Of The Materials To Be Handled. The Main Value Of This Book Over A Simple Bibliography That Can Now Be Generated By A Computer Search Is That The Authors Continue The Practice Started In The First Edition Of Publishing Tables Comparing The Results Of Using The Various Estimation Methods To Each Other And Experimental Data When Available And Then Make Recommendations As To Which Method Seems To Work Best Under Various Conditions.

the Need For Regular Updating Was Succintly Stated By Reid And Sherwood In Their Preface To The Second Edition In 1966 When They Commented That The Half Life Of Estimation Correlations Seemed To Be About Four Years. Although There Are Now More Fundamentally Based Properties Estimation Methods Than There Were Then, The Authors Note In Their Preface To The New Edition That ...most Estimation Methods Rely Heavily On Empiricism... Thus The Need For Periodic Updating Of This Work Continues.

space Does Not Permit Listing Chapter By Chapter The Significant Differences From The Previous Edition, But They Are Substantial. The Properties Data Bank In Appendix A Has Been Completed Revised.

this New Edition Should Be Added To The Library Of Anyone Who Must Estimate Physical Properties Of Materials To Be Processed.

Publisher's Products purchased from Third Party sellers are not guaranteed by the publisher for quality, authenticity, or access to any online entitlements included with the product. Updating their hefty reference approximately every decade since 1958, chemical engineers Poling (U. of Toledo), John M. Prausnitz (U. of California-Berkeley), and John P. O'Connell (U. of Virginia) describe and critically review various estimation procedures for a limited number of properties of gases and liquids. Among those properties are critical and other pure component properties; pressure-volume- temperature relationships and thermodynamic properties of pure components and mixtures; vapor pressures and phase-change enthalpies; standard enthalpies of formation; standard Gibbs energy of formation; heat capacity; surface tension; viscosity; thermal conductivity; diffusion coefficients; and phase equilibria. They compare most of the estimated properties to experimental findings to indicate reliability, and illustrate most methods with examples. -- The most all-inclusive, critical survey of the most reliable estimating methods in use today -- now completely rewritten and reorganized to reflected the late-breaking developments-- A must for design engineers and chemical engineers working with processes involving liquids, gases, and mixtures, this book delivers on-the-spot information for estimating both physical and thermodynamic properties in the absence of experimental data-- Provides an instant-access property data bank of 600+ compound constants-for calculating properties