The chemistry of organic germanium, tin and lead compounds / Vol. 2 Part 1

This is the first book to deal with C-Ge, C-Sn and C-Pb bonds as functional groups. This concept helps to better understand the chemistry of these compounds, which find an increasing amount of applications. The volume concentrates on analytical aspects, and on safety and toxicology in the environment. [v. 1.] The Nature Of The C-m Bond (m = Ge, Sn, Pb) / Harold Basch And Tova Hoz -- Structural Aspects Of Compounds Containing C-e (e = Ge, Sn, Pb) Bonds / Kenneth M. Mackay -- Stereochemistry And Conformation Of Organogermanium, Organotin And Organolead Compounds / James A. Marshall And Jill A. Jablonowski -- Thermochemistry Of Organometallic Compounds Of Germanium, Tin And Lead / José A. Martinho Simões, Joel F. Liebman And Suzanne W. Slayden -- Esr Of Organogermanium, Organotin And Organolead Radicals / Jim Iley -- Photoelectron Spectroscopy (pes) Of Organometallic Compounds With C-m (m = Ge, Sn, Pb) Bonds / Carla Cauletti And Stefano Stranges -- Analytical Aspects Of Organogermanium Compounds / Jacob Zabicky And Sarina Grinberg -- Analytical Aspects Of Organotin Compounds / Jacob Zabicky And Sarina Grinberg -- Analytical Aspects Of Organolead Compounds / Jacob Zabicky And Sarina Grinberg -- Synthesis Of M(iv) Organometallic Compounds, Where M = Ge, Sn, Pb / John M. Tsangaris, Rudolph Willem And Marcel Gielen -- Acidity, Complexing, Basicity And H-bonding Of Organic Germanium, Tin And Lead Compounds : Experimental And Computational Results / Axel Schulz And Thomas M. Klapötke -- Substituent Effects Of Germanium, Tin And Lead Groups / Marvin Charton -- The Electrochemistry Of Alkyl Compounds Of Germanium, Tin And Lead / Michael Michman -- The Photochemistry Of Organometallic Compounds Of Germanium, Tin And Lead / Charles M. Gordon And Conor Long -- Syntheses And Uses Of Isotopically Labelled Organic Derivatives Of Ge, Sn And Pb / Kenneth C. Westaway And Helen Joly -- The Environmental Methylation Of Germanium, Tin And Lead / P.j. Craig And J.t. Van Elteren -- Toxicity Of Organogermanium Compounds / E. Lukevics And L.m. Ignatovich -- Organotin Toxicology / Larry R. Sherman -- Safety And Environmental Effects / Shigeru Maeda. V. 2. Genesis And Evolution In The Chemistry Of Organogermanium, Organotin And Organolead Compounds / Mikhail G. Voronkov And Klavdiya A. Abzaeva -- Similarities And Differences Of Organic Compounds Of Germanium, Tin And Lead / Mikhail G. Voronkov And Alexey N. Egorochkin -- Theoretical Studies Of Organic Germanium, Tin And Lead Compounds / Inga Ganzer, Michael Hartmann And Gernot Frenking -- Recent Advances In Structural Chemistry Of Organic Germanium, Tin And Lead Compounds / Karl W. Klinkhammer -- Gas-phase Chemistry And Mass Spectrometry Of Ge-, Sn- And Pb-containing Compounds / José M. Riveros And Keiko Takashima -- Further Advances In Germanium, Tin And Lead Nmr / Heinrich Chr. Marsmann And Frank Uhlig -- Recent Advances In Acidity, Complexing, Basicity And H-bonding Of Organo Germanium, Tin And Lead Compounds / Claudia M. Rienäcker And Thomas M. Klapötke -- Structural Effects On Germanium, Tin And Lead Compounds / Marvin Charton --^ Radical Reaction Mechanisms Of And At Organic Germanium, Tin And Lead / Marc B. Taraban, Olga S. Volkova, Alexander I. Kruppa And Tatyana V. Leshina -- Free And Complexed R3m Cations (m = Ge, Sn, Pb) / Ilya Zharov And Josef Michl -- Alkaline And Alkaline Earth Metal-14 Compounds : Preparation, Spectroscopy, Structure And Reactivity / Pierre Riviere, Annie Castel And Monique Riviere-baudet -- Spectroscopic Studies And Quantum-chemical Calculations Of Short-lived Germylenes, Stannylenes And Plumbylenes / Sergey E. Boganov, Mikhail P. Egorov, Valery I. Faustov And Oleg M. Nefedov -- Multiply Bonded Germanium, Tin And Lead Compounds / Norihiro Tokitoh And Renji Okazaki -- Unsaturated Three-membered Rings Of Heavier Group 14 Elements / Vladimir Ya. Lee And Akira Sekiguchi -- Cage Compounds Of Heavier Group 14 Elements / Akira Sekiguchi And Vladimir Ya. Lee -- Hypervalent Compounds Of Organic Germanium, Tin And Lead Derivatives / Yuri I. Baukov And Stanislav N. Tandura --^ Transition Metal Complexes Of Germanium, Tin And Lead / Hemant K. Sharma, Ionel Haiduc And Keith H. Pannell -- Synthetic Applications Of Organic Germanium, Tin And Lead Compounds (excluding R3mh) / Eric Fouquet -- Synthetic Uses Of R3mh (m = Ge, Sn, Pb) / Michael W. Carland And Carl H. Schiesser -- Trichlorogermane, A New Superacid In Organic Chemistry / Stanislav Kolesnikov, Stanislav N. Tandura And Oleg M. Nefedov -- The Photochemistry Of Organometallic Compounds Of Germanium, Tin And Lead / Conor Long And Mary T. Pryce -- Organometallic Polymers Of Germanium, Tin And Lead / Klaus Jurkschat And Michael Mehring -- Biological Activity Of Organogermanium Compounds / Edmunds Lukevics And Luba Ignatovich -- Biological Activity Of Organotin And Organolead Compounds / Edmunds Lukevics And Olga Pudova. Vol. 1 Edited By Saul Patai; V. 2 Edited By Zvi Rappoport. Vol. 2: Chichester ; New York : Wiley. An Interscience Publication. Includes Bibliographical References And Indexes. Cover Page......Page 1 THE CHEMISTRY OF FUNCTIONAL GROUPS......Page 3 Title Page......Page 4 ISBN 0471942073......Page 5 Contributing authors......Page 6 Foreword......Page 8 The Chemistry of Functional Groups: Preface to the series......Page 9 Contents......Page 11 List of abbreviations used......Page 13 1 The nature of the C-M bond (M= Ge, Sn, Pb)......Page 16 2 Structural aspects of compounds containing C-E (E= Ge, Sn, Pb) bonds......Page 112 3 Stereochemistry and conformation of organogermanium, organotin and organolead compounds......Page 210 4 Thermochemistry of organometallic compounds of germanium, tin and lead......Page 260 5 ESR of organogermanium, organotin and organolead radicals......Page 282 6 Photoelectron spectroscopy (PES) of organometallic compounds with C-M (M=Ge, Sn, Pb) bonds......Page 306 7 Analytical aspects of organo-germanium compounds......Page 354 8 Analytical aspects of organotin compounds......Page 380 9 Analytical aspects of organolead compounds......Page 444 10 Synthesis of M(IV) organometallic compounds, where M = Ge, Sn, Pb......Page 468 11 Acidity, complexing, basicityand H-bonding of organicgermanium, tinandleadcompounds: experimentalandcomputational results......Page 552 12 Substituent effects of germanium, tin and lead groups......Page 618 13 The electrochemistry of alkyl compounds of germanium, tin and lead......Page 680 14 The photochemistry of organometallic compounds of germanium, tin and lead......Page 738 15 Syntheses and uses of isotopically labelled organic derivatives of Ge, Sn and Pb......Page 774 16 The environmental methylation of germanium, tin and lead......Page 858 17 Toxicity of organogermanium compounds......Page 872 18 Organotin toxicology......Page 880 19 Safety and environmental effects......Page 886 Author index......Page 926 Subject index......Page 990 This volume covers such topics as the nature of the C-M bond; structural, spectroscopic and synthetic chemistry; pharmacology; toxicology; safety; and environmental aspects. The work should benefit the synthetic chemistry community as well as scientists working in organometallics. From the book cover" Excellent Read! Captures the spirit and times of Jesse Livermore, legendary trader. The book tracks two major market crashes, love affairs, the shooting of Jesse Jr. by his mother, and two family suicides ... Never a dull moment."