Synthesis and Properties of Silicones and Silicone-Modified Materials (ACS Symposium Series (No. 838))

Content: Preface ; 1. Silicones and Silicone-Modified Materials: A Concise Overview ; SYNTHESIS ; 2. Controlled Synthesis of All Siloxane-Functionalized Architectures by Ring-Opening Polymerization ; 3. Novel Methods of Catalyzing Polysiloxane Syntheses ; 4. Anionic Ring-Opening Polymerization of cis-2,4,6-Trimethyl-2',4',6'-triphynel Cyclotrisiloxane (cis-P[3) in Cyclohexane ; 5. Ru-Catalyzed Hydrosilylation Polymerization: An Overview of RuH[2(CO)(PPh[3)[3-Catalyzed Hydrosilylation Copolymerizations of \*a,\*w-Dihydrido-oligo-dimethylsiloxanes and Polymerizations of \*w-Dimethylsilyloxy Ketones ; 6. Synthesis and Characterization of Siloxane-Containing Polymers Obtained by Dehydrocoupling Polymerization ; 7. Synthesis of Linear Copolysiloxanes with Regular Microstructures and Synthesis of Soluble Polysiloxanes with Trifunctional RSiO[3[/[2 (T) or Tetrafunctional SiO[4[/[2 (Q) Units ; 8. Polysiloxanes in Compressed Carbon Dioxide ; CHARACTERIZATION ; 9. Neutron Scattering Studies of Cyclic and Linear Poly(dimethylsiloxanes) ; 10. Photoexcitation and Photoemission Spectra of Phenyl-Substituted Cyclosiloxanes ; 11. Measuring the Size and Shape of Silicones: The Utilization of Chemometrics and Spectroscopy ; 12. Thermally Stable Siloxane Polymers for Gas Chromatography ; ELASTOMERS AND REINFORCEMENT ; 13. The Effect of Thermal Aging on the Non-Network Species in Room Temperature Vulcanized Polysiloxane Rubbers ; 14. Prediction of the Elastomeric Modulus of Poly(dimethylsiloxane) Networks Formed by Endlinking ; 15. Structure-Property Relationships for Poly(dimethylsiloxane) Networks In Situ Filled Using Titanium 2-Ethylhexoxide and Zirconium n-Butoxide ; 16. Modulus Reduction Mechanism of Trimethylsiloxy Silicates in a Polyorganosiloxane ; 17. NMR Spin Relaxation, Self-Diffusion and Viscosity Studies of Poly(dimethylsiloxane)s Blended with Silicate Nanoparticles ; SURFACES AND INTERFACES ; 18. Investigating the Energetics of Bioadhesion on Microengineered Siloxane Elastomers: Characterizing the Topography, Mechanical Properties, and Surface Energy and Their Effect on Cell Contact Guidance ; 19. Exploiting Favorable Silicone-Protein Interactions: Stabilization against Denaturation at Oil-Water Interfaces ; 20. Association of Siloxane Polymeric Surfactants in Aqueous Solution ; COPOLYMERS ; 21. Poly(amidoamine organosilicon) Dendrimers and Their Derivates of Higher Degree of Structural Complexity ; 22. Surfactant Properties of Poly(dimethylsiloxane)-Containing Block Copolymers from Living Radical Polymerization ; 23. Organic-Inorganic Hybrid Materials from Polysiloxanes and Polysilsesquioxanes Using Controlled/Living Radical Polymerization ; 24. Preparation and Properties of Silicone-Urea Copolymers Doped with Cobalt(II) Chloride ; 25. Block and Graft Copolymers Containing Poly(dimethylsiloxane) and Poly(4-vinyl-pyridine) Segments by Free Radical Polymerization ; 26. Poly(dimethylsiloxane)-graft- oligo(hexafluoropropeneoxide) Via Ring-Opening Polymerization ; 27. Silicone Graft Copolymers with Acrylonitrile, Chloroprene, Styrene, Methylmethacrylate, and an Olefin ; 28. Synthesis and Properties of Poly(butylene terephthalate)-Poly (dimethylsiloxane) Block Copolymers ; 29. The Synthesis of Vinyloxyacetate-Siloxane Copolymer and Its Absorption onto E Glass Fibers ; REINFORCING FILLERS ; 30. Silicification and Biosilicification: Part 2. Silicification at pH 7 in the Presence of a Cationically Charged Polymer in Solution and Immobilized on Substrates ; 31. Diffusion-Controlled Titanate-Catalyzed Condensation of Alkoxysilanes in Nonpolar Solvents ; Author Index ; Subject Index Overview Of Siloxane Polymers / James E. Mark -- From Sand To Silicones : An Overview Of The Chemistry Of Silicones / Larry N. Lewis -- Cationic Ring Opening Polymerization Of Cyclotrisiloxanes With Mixed Siloxane Units / J. Chojnowski, K. Kaźmierski, M. Cypryk, And W. Fortuniak -- Hydrogenated And Deuterated Cyclic Poly(dimethylsiloxanes) / Anthony C. Dagger And J. Anthony Semlyen -- Calculation Of A Reaction Path For Koh-catalyzed Ring-opening Polymerization Of Cyclic Siloxanes / J.d. Kress, P.c. Leung, G.j. Tawa, And P.j. Hay -- Mesophase Behavior And Structure Of Mesophases In Cyclolinear Polyorganosiloxanes / Yu. K. Godovsky, N.n. Makarova, And E.v. Matukhina -- Photoluminescence Of Phenyl- And Methylsubstituted Cyclosiloxanes / Udo Pernisz, Norbert Auner, And Michael Backer -- Synthesis And Characterization Of Amino Acid Functional Siloxanes / J.g. Matisons And A. Provatas --^ Telechelic Aryl Cyanate Ester Oligosiloxanes : Impact Modifiers For Cyanate Ester Resins / Steven K. Pollack And Zhidong Fu -- Uv Curable Silicones From Acryloxymethyldimethylacryloxysilane / H.k. Chu -- Advances In Non-toxic Silicone Biofouling Release Coatings / Tim Burnell, John Carpenter, Kathryn Truby, Judy Serth-guzzo, Judith Stein, And Deborah Wiebe -- Poly(dimethylsiloxane) Gelation Studies / R.f.t. Stepto, D.j.r. Taylor, T. Partchuk, And M. Gottlieb -- Nmr Spin-spin Relaxation Studies Of Reinforced Poly(dimethylsiloxane) Melts / Terence Cosgrove, Michael J. Turner, Ian Weatherhead, Claire Roberts, Tania Garasanin, Randall G. Schmidt, Glenn V. Gordon, And Jonathan P. Hannington -- Synthesis Of Organosilicon Linear Polymer With Octaorganooctasilsesquioxanes Structural Units In Main Chain / N.a. Tebeneva, E.a. Rebrov, And A.m. Muzafarov -- Halogenated Siloxane-containing Polymers Via Hydrosilylation Polymerization / J. Hu And D.y. Son --^ Radially Layered Poly(amidoamine-organosilicon) Copolymeric Dendrimers And Their Networks Containing Controlled Hydrophilic And Hydrophobic Nanoscopic Domains / Petar R. Dvornic, Agnes M. De Leuze-jallouli, Michael J. Owen, And Susan V. Perz -- Organic-inorganic Hybrid Polymers From Atom Transfer Radical Polymerization And Poly(dimethylsiloxane) / Krzysztof Matyjaszewski, Peter J. Miller, Guido Kickelbick, Yoshiki Nakagawa, Steven Diamanti, And Cristina Pacis -- Synthesis And Photoinitiated Cationic Polymerization Of Monomers Containing The Silsesquioxane Core / James V. Crivello And Ranjit Malik -- Low Modulus Fluorosiloxane-based Hydrogels For Contact Lens Application / J. Künzler And R. Ozark -- Fluorosilicones Containing The Perfluorocyclobutane Aromatic Ether Linkage / Dennis W. Smith, Jr., Junmin Ji, Sridevi Narayan-sarathy, Robert H. Neilson, And David A. Babb -- Surface Properties Of Thin Film Poly(dimethylsiloxane) / H. She, M.k. Chaudhury, And Michael J. Owen --^ Aggregation Structure And Surface Properties Of 18-nonadecenyltrichlorosilane Monolayer And Multilayer Films Prepared By The Langmuir Method / Ken Kojio, Atsushi Takahara, And Tisato Kajiyama -- An Investigation Of The Surface Properties And Phase Behavior Of Poly(dimethylsiloxane-b-ethyleneoxide) Multiblock Copolymers / Harri Jukarainen, Stephen J. Clarson, And Jukka V. Seppälä -- Poly(siloxyethylene Glycol) For New Functionality Materials / Yukio Nagasaki And Hidetoshi Aoki -- Polycarbonate-polysiloxane-based Interpenetrating Networks / Sylvie Boileau, Laurent Bouteiller, Riadh Ben Khalifa, Yi Liang, And Dominique Teyssié -- High Strength Silicone-urethane Copolymers : Synthesis And Properties / Emel Yilgör, Ayşen Tulpar, Şebnem Kara, And Iskender Yilgör -- Silicon-terminated Telechelic Oligomers By Acyclic Diene Metathesis Chemistry / K.r. Brzezinska, K.b. Wagener, And G.t. Burns --^ Hydrogen Bond Interactions And Self-condensation Of Silanol-containing Polymers In Polymer Blends And Organic-inorganic Polymeric Hybrids / Eli M. Pearce, T.k. Kwei, And Shaoxiang Lu -- A Review Of The Ruthenium-catalyzed Copolymerization Of Aromatic Ketones And 1,3-divinyltetramethyldisiloxane : Preparation Of Alt-poly(carbosilane-siloxanes) / William P. Weber, Hongjie Guo, Cindy L. Kepler, Timothy M. Londergan, Ping Lu, Jyri Paulsaari, Jonathan R. Sargent, Mark A. Tapsak, And Guohong Wang -- Block Copolymers Containing Silicone And Vinyl Polymer Segments By Free Radical Polymerization / D. Graiver, B. Nguyen, F.j. Hamilton, Y. Kim, And H.j. Harwood -- Synthesis Of Polymers Containing Silicon Atoms Of Regulated Structure / Yusuke Kawakami -- Investigation Of The Synthesis Of Bis-(3-trimethoxysilylpropyl)fumarate / Peter M. Miranda -- In Situ Formed Siloxane-silica Filler For Rubbery Organic Networks / Libor Matějka --^ From A Hyperbranched Polyethoxysiloxane Toward Molecular Forms Of Silica : A Polymer-based Approach To The Monitoring Of Silica Properties / V.v. Kazakova, E.a. Rebrov, V.b. Myakushev, T.v. Strelkova, A.n. Ozerin, L.a. Ozerina, T.b. Chenskaya, S.s. Sheiko, E. Yu. Sharipov, And A.m. Muzafarov -- Synthesis, Characterization, And Evaluation Of Siloxane-containing Modifiers For Photocurable Epoxy Coating Formulations / Mark D. Soucek, Shaobing Wu, And Srinivasan Chakrapani -- Tospearl, Silicone Resin For Industrial Applications / Robert J. Perry And Mary E. Adams -- Oxygen Gas Barrier Pet Films Formed By Deposition Of Plasma-polymerized Siox Films / N. Inagaki. Stephen J. Clarson, Editor ... [et Al.]. Includes Bibliographical References And Index.
Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcing fillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviews recent academic and technological developments behind silicones and silicone-modified materials. Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcing fillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviews recent academic and technological developments behind silicones and silicone-modified materials. Annotation Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcing fillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviewsrecent academic and technological developments behind silicones and silicone-modified materials. Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcingfillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviews recent academic and technological developments behind silicones and silicone-modified materials