Preparation of Catalysts V: Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Fifth International Symposium, Louv (Studies in Surface Science & Catalysis)

The organizers of this Fifth Symposium maintained their initial objectives, namely to gather experts from both industries and universities to discuss the scientific problems involved in the preparation of heterogeneous catalysts, and to encourage as much as possible the presentation of research work on catalysts of real industrial significance. Another highlight of these symposia was to reserve a substantial part of the program to new developments in catalyst preparation, new preparation methods and new catalytic systems. The fact that chemical reactions which were hardly conceivable some years ago have become possible today through the development of appropriate catalytic systems proves that catalysis is in constant progress. The papers in this volume deal with studies of unit operations in catalyst preparation, catalyst preparation via the sol-gel route, preparation of catalysts from layered structures and pillaring of clays, preparation and modification of zeolite-based catalysts, carbon supported catalysts, preparation of oxidation catalysts and novel and unusual preparation methods. Content: Edited by Page iii Copyright page Page iv Organizing Committee Page x Foreword Pages xi-xii B. Delmon, P. Grange, P.A. Jacobs, G. Poncelet Acknowledgements Page xiii Financial Support Page xiv Illustration of Process Scale-Up in Heterogeneous Catalyst Preparation Original Research Article Pages 1-17 I. Biay, G. Dessalces, C. Hypolite, F. Kolenda, J.P. Reymond Deposition Precipitation Onto Pre-Shaped Carrier Bodies. Possibilities and Limitations Original Research Article Pages 19-36 K.P. de Jong Influence of the Preparation Procedure on the Physical Properties, Surface Acidity and Dispersion of Mop/Al 2 O 3 Catalysts Original Research Article Pages 37-48 R. Prada Silvy, Y. Romero, J. Guaregua, R. Galiasso Synthesis Of Non-Stoichiometric Spinel-Type Phases: A Key Tool For The Preparation Of Tailored Catalysts With Specific Activity Original Research Article Pages 49-58 Michele Piemontese, Ferruccio Trifiro', Angelo Vaccari, Elisabetta Foresti, Massimo Gazzano Effect of Preparation Variables on Catalytic Behaviour of Copper/Zirconia Catalysts for the Synthesis of Methanol from Carbon Dioxide Original Research Article Pages 59-68 R.A. Koeppel, A. Baiker, Ch. Schild, A. Wokaun Preparation of Tio 2 —Al 2 O 3 by Impregnation with TiCl 4 —CCl 4 Original Research Article Pages 69-76 Liu Yingjun, Zhang Qinpei, Zhu Yongfa, Gui Linlin, Tang Youqi Interactions of the Impregnating Solution With the Support During the Preparation of Rh/Tio 2 Catalysts Original Research Article Pages 77-86 R.J. Fenoglio, W. Alvarez, G.M. Nuñez, D.E. Resasco Impregnation of Controlled-Porosity Silica: Cu/Sio 2 , Co/SiO 2 and Cu-Co/SiO 2 Investigation of the Parameters Affecting Selectivity in CO Hydrogenation Original Research Article Pages 87-93 M.A. Martin Luengo(Yates), Y. Wang, P.A. Sermon Selective Hydrogenation of Cyclododecatriene Isomers to Cyclododecene Catalysed by Cu-Al 2 O 3 . Original Research Article Pages 95-102 V. Di Castro, M. Gargano, N. Ravasio, M. Rossi Preparation and Characterization of Highly Selective Fe-Cu/Sio 2 Catalysts for Partial Hydrogenation of Alkynes Original Research Article Pages 103-112 Yuriko Nitta, Yoshifumi Hiramatsu, Yasuaki Okamoto, Toshinobu Imanaka Some Remarks on the Preparation of Fe-K/Ca-Cr Catalyst for Styrene Production Original Research Article Pages 113-122 Z. Dziewiçcki, E. Ozdoba Hydrogenation of 2 Ethyl Hexen-2-Al on Ni/Sio 2 Catalysts. Role of Preparation Parameters Original Research Article Pages 123-133 A.F. Da Silva Junior, V.M.M. Salim, M. Schmal, R. Frety Preparation and Properties of a Pt/Silica and its Comparison with Europt-1 Original Research Article Pages 135-144 S.D. Jackson, M.B.T. Keegan, G.D. Mclellan, P.A. Meheux, G. Webb, R.B. Moyes, P.B. Wells, R. Whyman, J. Willis Factors Analysis for Mechanical Strength in Pelleting Process of Fe-Based High Temperature Shift Catalyst Original Research Article Pages 145-153 Yongdan Li, Jiusheng Zhao, Liu Chang Studies on Pore Size Control of Alumina: Preparation of Alumina Catalyst Extrudates with Large Unimodal Pore Structure by Low Temperature Hydrothermal Treatment Original Research Article Pages 155-163 M. Absi-Halabi, A. Stanislaus, H. Al-Zaid Production of Nickel-on-Alumina Catalysts from Preshaped Support Bodies Original Research Article Pages 165-174 L.M. Knijff, P.H. Bolt, R. Van Yperen, A.J. Van Dillen, J.W. Geus Development of A Methodology for Investigating the Adsorption of Species Containing Catalytically Active Ions on the Surface of Industrial Carriers Original Research Article Pages 175-184 N. Spanos, Ch. Kordulis, A. Lycourghiotis Scaling Down of the Calcination Process for Industrial Catalyst Manufacturing Original Research Article Pages 185-203 G. Groen, J. Ferment, M.J. Groeneveld, J. Decleer, A. Delva Hydrothermal Sintering of the Active Phase in Alumina Supported Fixed Bed Nickel Catalysts During Reduction Original Research Article Pages 205-214 E.K. Poels, J.G. Dekker, W.A. Van Leeuwen The Influence of Silica Support on Polymerisation Catalyst Performance Original Research Article Pages 215-227 C.E. Marsden Preparation and Catalytic Effects of Ceo X -MO y -Al 2 O 3 (M=Ba,La,Zr and Pr) by an improved sol gel method for automotive catalysts Original Research Article Pages 229-238 K. Masuda, M. Kawai, K. Kuno, N. Kachi, F. Mizukami Influence Of Preparation Parameters On Pore Structure Of Silica Gels Prepared From Tetraethoxy Orthosilicate Original Research Article Pages 239-246 B. Handy, K.L. Walther, A. Wokaun, A. Baiker Aspects of the Synthesis of Aryl Sulfonic Acid Mels ® Catalysts Original Research Article Pages 247-267 David L. King, Michael D. Cooper, William A. Sanderson, Charles M. Schramm, Jere D. Fellmann Preparation of Basic Silicates and Their Use as Supports or Catalysts Original Research Article Pages 269-278 G.A. Martin, M.C. Durupty, C. Mirodatos, N. Mouaddib, V. Perrichon Soils as Unusual Catalysts Original Research Article Pages 279-286 Sergio A. Moya, Anselmo Flores, Mauricio Escudey Thermal Stability, Acidity and Cracking Properties of Pillared Rectorite Catalysts Original Research Article Pages 287-299 Mario L. Occelli Preparation and Properties of Large-Pore Re/Al-Pillared Montmorillonite. A Comparison of Re-Cations Original Research Article Pages 301-310 J. Sterte Preparation of Pillared Montmorillonite with Enriched Pillars Original Research Article Pages 311-318 E. Kikuchi, H. Seki, T. Matsuda Intercalation of La 2 O 3 and La 2 O 3 -NiO Oxidic Species into Montmorillonite Layered Structure Original Research Article Pages 319-328 A.K. Ladavos, P.J. Pomonis Mixed Al-Fe Pillared Laponites: Preparation, Characterization and Catalytic Properties in Syngas Conversion Original Research Article Pages 329-336 F. Bergaya, N Hassoun, L. Gatineau, J. Barrault Zirconium Pillared Clays. Influence of Basic Polymerization of the Precursor on Their Structure and Stability Original Research Article Pages 337-343 E.M. Farfan-Torres, O. Dedeycker, P. Grange Control of the Acidity of Montmorillonites Pillared by A1-Hydroxy Cationic Species Original Research Article Pages 345-353 D. Tichit, Z. Mountassir, F. Figueras, A. Auroux The Chemistry of the Dealumination of Faujasite Zeolites with Silicon Tetrachloride Original Research Article Pages 355-379 Johan A. Martens, Piet J. Grobet, Peter A. Jacobs Factors Affecting the Formation of Extra-Framework Species and Mesopores During Dealumination of Zeolite Y Original Research Article Pages 381-395 D. Goyvaerts, J.A. Martens, P.J. Grobet, P.A. Jacobs Treatment of Galloalumino-Silicate (Zsm-5 Type Zeolite) with Koh Solution. Dispersion of Aggregated Zeolites Into Small Particles Original Research Article Pages 397-406 J. Kanai, N. Kawata Design and Preparation of Vanadium Resistant FCC Catalysts Original Research Article Pages 407-419 D.J. Rawlence, K. Gosling, L.H. Staal, A.P. Chapple Double Substitution in Silicalite by Direct Synthesis: A New Route to Crystalline Porous Bifunctional Catalysts Original Research Article Pages 421-429 G. Bellussi, A. Carati, M.G. Clerici, A. Esposito Study on Titanium Silicalite Synthesis Original Research Article Pages 431-438 M. Padovan, F. Genoni, G. Leofanti, G. Petrini, G. Trezza, A. Zecchina Activated Carbon from Bituminous Coal Original Research Article Pages 439-448 J.A. Pajares, J.J. Pis, A.B. Fuertes, J.B. Parra, M. Mahamud, A.J. Péarez Carbon-Supported Palladium Catalysts. Some Aspects of Preparation in Connection with the Adsorption Properties of the Supports Original Research Article Pages 449-458 A.S. Lisitsyn, P.A. Simonov, A.A. Ketterling, V.A. Likholobov Preparation of Palloium-Copper Catalysts of Designed Surface Structure Original Research Article Pages 459-468 Zs. Bodnár, T. Mallát, S. Szabó, J. Petró Optimization and Characterization of Pt-Fe Alloys Supported on Charcoal Original Research Article Pages 469-478 P. Fouilloux, D. Goupil, B. Blanc, D. Richard Supported Metallic Catalysts Achieved through Graphite Intercalation Compounds Original Research Article Pages 479-485 F. Beguin, A. Messaoudi, A. Chafik, J. Barrault, R. Erre Preparation of Graphite-Iron-Potassium Catalysts for Ammonia Synthesis Original Research Article Pages 487-496 K. Kałucki, A.W. Morawski Synthesis of V-P-O Catalysts for Oxidation of C 4 Hydrocarbons Original Research Article Pages 497-506 V.A. Zazhigalov, G.A. Komashko, A.I. Pyatnitskaya, V.M. Belousov, J. Stoch, J. Haber Preparation of Well Dispersed Vanadia Catalysts by Ultra-High Intensity Grinding at Ambient Temperature Original Research Article Pages 507-516 Z. Sobalik, O.B. Lapina, V.M. Mastikhin Dispersion and Physico-Chemical Characterization of Iron Oxide on Various Supports Original Research Article Pages 517-525 Weijie Ji, Shikong Shen, Shuben Li, Hongli Wang The Use of Chelating Agents for the Preparation of Iron Oxide Catalysts for the Selective Oxidation of Hydrogen Sulfide Original Research Article Pages 527-536 P.J. Van Den Brink, A. Scholten, A. Van Wageningen, M.D.A. Lamers, A.J. Van Dillen, J.W. Geus Preparation of Oxidation Catalysts with a Controlled Architecture Original Research Article Pages 537-546 Y.L. Xiong, L.T. Weng, B. Zhou, B. Yasse, E. Sham, L. Daza, F. Gillambias, P. Ruiz, B. Delmon Structure and Selectivity Changes in Vanadia-Titania-Deno x Catalysts Original Research Article Pages 547-556 M. Kotter, H.-G. Lintz, T. Turek Binary Oxide Catalysts Synthesized by Sequential Precipitation Original Research Article Pages 557-565 C.S. Brooks Zro 2 as a SUPPORT: OXIDATION of CO on CrO x /ZrO 2 Original Research Article Pages 567-574 T. Yamaguchi, M. Tan-No, K. Tanabe Methane oxidative coupling by definite compounds (e.g. perovskite, cubic or monoclinic structure,...) obtained by low temperature processes Original Research Article Pages 575-582 J.L. Rehspringer, P. Poix, A. Kaddouri, A. Kiennemann Preparation of Strong Alumina Supports for Fluidized Bed Catalysts Original Research Article Pages 583-590 M.N. Shepeleva, R.A. Shkrabina, Z.R. Ismagilov, V.B. Fenelonov Synthesis and Regeneration of Raney Catalysts by Mechanochemical Methods Original Research Article Pages 591-600 A.B. Fasman, S.D. Mikhailenko, O.T. Kalinina, E.Yu. Ivanov, G.V. Golubkova Controlled Preparation of Raney Ni Catalysts from Ni 2 Al 3 Base Alloys - Structure and Properties. Original Research Article Pages 601-610 S. Hamar-Thibault, J. Gros, J.C. Joud, J. Masson, J.P. Damon, J.M. Bonnier Novel Type of Hydrotreating Catalysts Prepared through Precipitation from Homogeneous Solution (Pfhs) Method Original Research Article Pages 611-616 Kaza Somasekhara Rao + , V.V.D.N. Prasad, K.V.R. Chary, P. Kanta Rao Preparation of Manganese Oxide Catalysts Using Novel NH 4 MnO 4 and Manganese Hydroxide Precursors. Comparison of Unsupported and Alumina Supported Catalysts Original Research Article Pages 617-626 A.K.H. Nohman, D. Duprez, C. Kappenstein, S.A.A. Mansour, M.I. Zaki Influence of Surface OH Groups and Traces of Water Vapor During the Preparation of TiO 2 -SiO 2 Samples Original Research Article Pages 627-636 A. Muñoz-Paez, G. Munuera Catalysts and Preparation of New Titanates Original Research Article Pages 637-646 R.G. Anthony, R.G. Dosch New Methods of Synthesis of Highly Dispersed Silver Catalysts Original Research Article Pages 647-652 N.E. Bogdanchikova, V.V. Tretyakov Preparation of High-Surface-Area V-Si-P Oxide Catalysts Original Research Article Pages 653-660 M. Ai Preparation of Fine Particles of Ruthenium-Alumina Composite by Mist Reduction Method Original Research Article Pages 661-668 H. Imai, J. Sekiguchi Designed Catalysts for Hydrodechlorination, Reduction and Reductive Amination Reactions Original Research Article Pages 669-678 J.L. Margitfalvi, S. Göbölös, E. Táas, M. Hegedüs Preparation of High Surface Area Hydrogen Molybdenum Bronze Catalysts Original Research Article Pages 679-686 C. Hoang-Van, O. Zegaoui, B. Pommier, P. Pichat New Preparation of Supported Metals. Hydrogenation of Nitriles Original Research Article Pages 687-693 M. Blanchard, J. Barrault, A. Derouault Preparation of Highly Dispersed Gold on Titanium and Magnesium Oxide Original Research Article Pages 695-704 Susumu Tsubota, Masatake Haruta, Tetsuhiko Kobayashi, Atsushi Ueda, Yoshiko Nakahara Preparation of Monodisperse Colloidal Pt-Reo 2 Particles using Microemulsions Original Research Article Pages 705-716 A. Claerbout, J.B. Nagy New Organometallic Active Sites Obtained by Controlled Surface Reaction of Organometallic Complexes with Supported Metal Particles Original Research Article Pages 717-728 B. Didillon, A. El Mansour, J.P. Candy, J.M. Basset, F. Le Peltier, J.P. Bournonville Conversion Coatings on Stainless Steel as Multipurpose Catalysts Original Research Article Pages 729-739 L. Aries, A. Komla, J.P. Traverse Author Index Pages 741-744 Studies in Surface Science and Catalysis Pages 745-748