Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2

Volume II/26 supplements the previous compilations II/l, II/9 and II/17 of the magnetic properties of free radicals which were published in 1965, 1977–1980 and 1986–90. Due to the still rapid growth of the field and the necessary inclusion of new subjects the volume is divided into subvolumes which will appear in fast succession. Together with the earlier publications volume II/26 offers an up-to-date and comprehensive survey and collection of structures and data on the important chemical intermediates, namely radicals, polyradicals and related species such as carbenes, nitrenes, etc. As before the species have been grouped according to chemical aspects. The contents of the individual subvolumes are indicated on the inside of the front covers. For each group of substances the literature has been compiled and extracted by experts in the fields. A small overlap between the chapters is intentional and allows a maximum of coherence and comprehensiveness of the display. We wish to thank all the authors for their careful and experienced work and the most agreeable cooperation, the Landolt-Börnstein office, especially Mrs. A. Endemann, for the layouts and the untiring and careful checking of manuscripts and galley proofs, and Springer-Verlag for the customary care in the preparation of the volume which is published without external financial support. Zürich, December 2003 The Editor Table of contents Magnetic Properties of Free Radicals Subvolume E: Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions Part 2 I Introduction I General introduction [H. Fischer]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 A Definition and substances . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Front Matter....Pages i-ix I General introduction....Pages 1-6 III General symbols and abbreviations....Pages 7-11 16.1 Introduction....Pages 12-12 16.2.1.1 Monosubstituted 1,2-benzosemiquinones....Pages 13-18 16.2.1.2 3,4-Disubstituted 1,2-benzosemiquinones....Pages 19-21 16.2.1.3 3,5-Disubstituted 1,2-benzosemiquinones....Pages 22-46 16.2.1.4 3,6-Disubstituted 1,2-benzosemiquinones....Pages 47-64 16.2.1.5 4,5-Disubstituted 1,2-benzosemiquinones....Pages 65-67 16.2.1.6 Trisubstituted 1,2-benzosemiquinones....Pages 68-92 16.2.1.7 Tetrasubstituted 1,2-benzosemiquinones....Pages 93-107 16.2.1.8 Imino-1,2-benzosemiquinones....Pages 108-113 16.2.2.1 Unsubstituted 1,4-benzosemiquinones....Pages 114-115 16.2.2.2 Monosubstituted 1,4-benzosemiquinones....Pages 116-122 16.2.2.3 Disubstituted 1,4-benzosemiquinones....Pages 123-127 16.2.2.4 Trisubstituted 1,4-benzosemiquinones....Pages 128-131 16.2.2.5 Tetrasubstituted 1,4-benzosemiquinones....Pages 132-140 16.3 1,4-Naphthosemiquinones....Pages 141-152 16.4 9,10-Phenanthrosemiquinones....Pages 153-161 16.5 9,10-Anthrosemiquinones....Pages 162-185 16.6 Other semiquinones....Pages 186-197 17.1 Introduction....Pages 198-205 17.2 Radical cations of alkanes....Pages 206-214 17.3.1 Radical cations of cyclohexanes....Pages 215-222 17.3.2 Radical cations of other cycloalkanes....Pages 223-236 17.4.1 Radical cations of acyclic monoenes....Pages 237-261 17.4.2 Radical cations of acyclic di- and higher-enes....Pages 262-270 17.4.3 Radical cations of cyclic monoenes....Pages 271-280 17.4.4 Radical cations of cyclic di- and higher-enes....Pages 281-298 17.5 Radical cations of alkynes....Pages 299-301 17.6.1 Benzene hydrocarbons....Pages 302-310 17.6.2 Radical cations of bi-, tri-, and tetra-phenylenes....Pages 311-314 17.6.3 Radical cations of biphenyls and higher biaryls....Pages 315-323 17.6.4 Radical cations of azulenes....Pages 324-330 17.6.5 Radical cations of polycyclic aromatic hydrocarbons....Pages 331-341 17.7 Radical cations of cyclophanes....Pages 342-350 17.8.1 Radical cations of aliphatic alcohols and ethers....Pages 351-370 17.8.2 Radical cations of furans....Pages 371-377 17.8.3 Radical cations of carbonyl compounds....Pages 378-381 17.8.4 Radical cations of phenols and aromatic ethers....Pages 382-399 17.9.1 Radical cations of aliphatic amines and derivatives....Pages 400-414 17.9.2 Radical cations of imines....Pages 415-420 17.9.3 Radical cations of diazo compounds....Pages 421-424 17.9.4 Radical cations of azo compounds....Pages 425-434 17.9.5 Radical cations of hydrazines....Pages 435-440 17.9.6 Radical cations of aromatic amines....Pages 441-454 17.9.7 Radical cations of nitroso and related compounds....Pages 455-460 17.9.8 Radical cations of pyrroles....Pages 461-467 17.9.9 Heteroaromatic compounds containing 1 or 2 nitrogen atoms....Pages 468-484 17.9.10 Heteroaromatic compounds containing 3 or 4 nitrogen atoms....Pages 485-490 17.9.11 Radical cations of heteroaromatic compounds containing both nitrogen and sulphur....Pages 491-500 17.10.1 Radical cation of sulfides....Pages 501-513 17.10.2 Radical cations of thiophenes....Pages 514-535 17.10.3 Radical cations of thiofulvalenes....Pages 536-551 17.10.4 Radical cations of aromatic and heterocyclic sulphur compounds....Pages 552-559 17.10.5 Radical cations of other compounds of sulfur, selenium, and tellurium....Pages 560-565 17.11.1 Radical cations of alkyl halides....Pages 566-568 17.11.2 Radical cations of aryl fluorides....Pages 569-572 17.12 Radical cations of compounds of phosphorus....Pages 573-587 17.13.1 Radical cations of organosilanes....Pages 588-598 17.13.2 Radical cations of organomercury compounds....Pages 599-610 17.13.3 Radical cations of other organometallic compounds....Pages 611-614