Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers : A Selection of Papers From the 9th International Symposium, Paris, France, 27 June - 1 July 2005

Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers contains a selection of papers presented at PASSIVITY-9, the 9th International Symposium on the Passivation of Metals and Semiconductors and the Properties of Thin Oxide Layers, which was held in Paris, 27 June - 1 July, 2005. One hundred and twelve peer-reviewed manuscripts have been included. The book covers all the fundamental and applied aspects of passivity and provides a relevant and updated view of the advances and new trends in the field. It is structured in ten sections: & bull; Growth, (Nano)structure and Composition of Passive Films & bull; Passivity of Semiconductors & bull; Electronic Properties of Passive Films & bull; Passivity Issues in Biological Systems & bull; Passivity in High-Temperature Water & bull; Mechanical Properties of Passive Films, & bull; Passivity Issues in Stress Corrosion Cracking and Tribocorrosion & bull; Passivity Breakdown and Localized Corrosion & bull; Modeling and Simulation & bull; Surface Modifications and Inhibitors (for Improved Corrosion Resistance and/or Adhesion). Read more... Content: Preface , Page v Electrochemical Properties of Fe-Cr-Mo Alloys and Fe 2 O 3 -Cr 2 O 3 -MoO 2 Artificial Passivation Films in 1 M HCl , Pages 3-8 , Katsuhisa Sugimoto, Mamoru Saito, Noboru Akao, Nobuyoshi Hara Formation and growth processes of electrochemical passive layers (borate medium: pH 9.2) and electron stimulated oxidized films (5.10 −6 Pa O 2 ) formed on Fe-Cr alloys , Pages 9-14 , M. Bouttemy, M. Bertoglio, G. Lorang Development and Composition of the High Temperature Oxide Film Grown on Fe-15Cr during Annealing , Pages 15-21 , Eungyeul Park, Michael Spiegel Passivity of Nickel-Containing Stainless Steels in Concentrated Sulphuric Acid , Pages 23-28 , M.B. Ives, Y. Li, K.S. Coley An insight on the role of Nickel in the passive films generated on different stainless steels , Pages 29-34 , C.M. Abreu, M.J. Cristóbal, R. Losada, X.R. Nóvoa, G. Pena, M.C. Pérez Passivity of Nitrogen-Bearing Stainless Steel in Acidic Solution , Pages 35-40 , Sanja Martinez, Mirjana Metikoš-Huković, Nushe Lajci Passive behaviour of stainless steels and nickel in LiBr solution at different temperatures , Pages 41-46 , A. Igual Muñoz, J. García Antón, J.L. Guiñón Segura, V. Pérez Herranz The effect of the Cerium ion implantation in the passive films properties of a duplex stainless steel , Pages 47-52 , C.M. Abreu, M.J. Cristóbal, X.R. Nóvoa, G. Pena, M.C. Pérez, C. Serra Use of Alloy 22 as Long-Term Radioactive Waste Containment Material , Pages 53-57 , Osvaldo Pensado, Roberto Pabalan, Darrell Dunn, Kuang-Tsan Chiang Effect of temperature and melt composition on the passivity of a Ni-10%Cr alloy in a molten electrolyte , Pages 59-64 , Martin Bojinov, Petia Gencheva, Tzvety Tzvetkoff Spontaneous passivation of amorphous bulk Ni-Cr-Mo-Ta-Nb-P alloys in concentrated HCl , Pages 65-70 , Koji Hashimoto, Hiroyuki Shinomiya, Akito Nakazawa, Katsuhiko Asami Passivity of Fe90V10 and Fe75Cr15V10 in Alkaline Media , Pages 71-76 , Andreas Drexler, Hans-Henning Strehblow Effect of anodic passivation on the corrosion behaviour of Fe-Mn-Al steels in 3.5%NaCl , Pages 77-82 , A.S. Hamada, L.P. Karjalainen, M.A. El-Zeky Surface Characterization of 1018 Carbon Steel in Borate Medium by in-situ Electrochemical Scanning Tunneling Microscopy , Pages 83-88 , Ignacio González, Román Cabrera-Sierra, Nikola Batina Iron passivation studied by in situ Raman spectroscopy on Fe/Au(111) epitaxial films , Pages 89-94 , S. Joiret, P. Allongue Atomic-Structure Characterization of Passive Film of Fe by Grazing Incidence X-ray Scattering at SPring-8 , Pages 95-100 , Masugu Sato, Masao Kimura, Masato Yamashita, Hiroyuki Konishi, Shinji Fujimoto, Yasunori Tabira, Takashi Doi, Masayasu Nagoshi, Shigeru Suzuki, Takayuki Kamimura, Takenori Nakayama, Toshiaki Ohtsuka Electrochemical aspects of the behavior of perchlorate ions in the presence of iron group metals , Pages 101-106 , G.G. Láng, T.A. Rokob, M. Ujvari, G. Horányi The effect of Al 3+ in the passivity of iron in alkaline media containing chlorides , Pages 107-112 , C.M. Abreu, M.J. Cristóbal, L. Freire, X.R. Nóvoa, G. Pena, M.C. Pérez Nanoscale modifications of a Ni(111) surface during nucleation and growth of the passive film , Pages 113-118 , A. Seyeux, V. Maurice, L.H. Klein, P. Marcus Simultaneous Anodic Dissolution and Passivation of Nickel in Moderate Acid Medium , Pages 119-124 , Joan Gregori, José Juan García-Jareño, David Giménez-Romero, Francisco Vicente Copper Passivity in Carbonate Base Solutions and its Application in Chemical Mechanical Planarization (CMP) , Pages 125-130 , E. Abelev, D. Starosvetsky, M. Auinat, Y. Ein-Eli Analysis of Cu corrosion product in aqueous lithium bromide concentrated solutions , Pages 131-136 , M.J. Muñoz-Portero, J. García-Antón, J.L. Guiñón, V. Pérez-Herranz Passivity of Tin and CuSn Alloys in Alkaline Media studied by X-ray Photoelectron Spectroscopy , Pages 137-142 , Petra Keller, Hans-Henning Strehblow Surface Analytical Characterization of Chromium Passivation on Tinplate , Pages 143-148 , Roelf Sandenbergh, Marius Biermann, Thomas von Moltke To Passivate or not to Passivate, that is the Question: The Case of Barium Tin(II) Chloride Fluorides , Pages 149-154 , Georges Dénès, Abdualhafed Muntasar A Thin Passivating Tin(IV) Oxide Layer on Tin(II)-Containing Fluoride Particles, or not? The M 1−x Sn x F 2 Solid Solutions , Pages 155-160 , Georges Dénès, Eva Laou, M. Cecilia Madamba, Abdualhafed Muntasar, Zhimeng Zhu Electrochemical Data About Disruption of Passivating Films. The Pb/PbSO 4 /H 2 SO 4 System , Pages 161-166 , C.V. D'Alkaine, P.M.P. Pratta Morphology, composition and structure of anodic films on binary Al-Cu alloys , Pages 167-172 , Jonathan Idrac, Peter Skeldon, Yanwen Liu, Teruo Hashimoto, Georges Mankowski, George Thompson, Christine Blanc Repassivation of aluminium during the AC-graining process by aluminium hydroxide formation , Pages 173-178 , Thanasis Dimogerontakis, Herman Terryn, Paola Campestrini Anodization of Ti: Formation of Self-Organized Titanium Oxide Nanotube-Layers , Pages 179-186 , P. Schmuki, H. Tsuchiya, L. Taveira, K. Sirotna, J.M. Macak Self-Organized Nanoporous Valve Metal Oxide Layers , Pages 187-192 , Hiroaki Tsuchiya, Jan Macak, Irina Sieber, Luciano Taveira, Patrik Schmuki Studies on transition of titanium from active into passive state in phosphoric acid solutions , Pages 193-198 , Elzbieta Krasicka-Cydzik The Influence of Temperature on the Passive Film Properties of ASTM Grade-7 Titanium , Pages 199-204 , J.J. Noël, L. Yan, D. Ofori, P. Jakupi, D.W. Shoesmith Chromatic properties of anodised titanium obtained with two techniques , Pages 205-210 , MariaPia Pedeferri, Barbara Del Curto, Pietro Pedeferri Amorphous-to-Crystalline Transition of Anodic Niobia , Pages 211-216 , H. Habazaki, T. Ogasawara, H. Konno, K. Shimizu, K. Asami, S. Nagata, P. Skeldon, G.E. Thompson Ellipsometric Analysis of Growth Process of Oxidation Films on Magnesium and its Alloys in Neutral Aqueous Solutions , Pages 217-223 , Nobuyoshi Hara, Daisuke Kagaya, Noboru Akao Corrosion Protection of Magnesium Alloys by Ce, Zr and Nb oxide layers , Pages 225-230 , Hélène Ardelean, Isabelle Frateur, Philippe Marcus Passivation of (100) and (111) Silicon in KOH Solution , Pages 233-238 , Harold G.G. Philipsen, John J. Kelly On the nature of oscillations of Open Circuit Potential of silicon immersed in CuSO 4 /HF solution , Pages 239-244 , Vitali Parkhutik, Yuri Makushok, Yukio Ogata Passivation and Local Corrosion of p-Silicon in Anhydrous Organic Solutions of Chlorides , Pages 245-250 , U. Lelek-Borkowska, J. Banaś Silicon Texturing Under Negative Potential Dissolution (NPD) Conditions , Pages 251-255 , Y. Ein-Eli, N. Gordon, D. Starosvetsky Fermi Level Pinning at n-GaAs(110) Electrodes , Pages 257-262 , Valentina Lazarescu, Mariuca Gartner, Rares Scurtu, Mihai Anastasescu, Adrian Ghita, Mihail F. Lazarescu, Wolfgang Schmickler Composition and Growth of Thermal and Anodic Oxides on InAlP , Pages 263-270 , S. Kleber, M.J. Graham, S. Moisa, G.I. Sproule, X. Wu, D. Landheer, A.J. SpringThorpe, P.J. Barrios, P. Schmuki High-k gate oxide formed by anodic oxidation for organic field effect transistors , Pages 271-276 , M. Erouel, A. Gagnaire, A.L. Deman, J. Tardy, N. Jaffrezic-Renault, Z. Sassi, J.C. Bureau, M.A. Maaref Photoelectrochemical analysis of the passive film formed on Fe-Cr-Ni alloys in pH 8.5 buffer solution , Pages 279-284 , HeeJin Jang, HyukSang Kwon Photoelectrochemical Response and Corrosion Property of Passive Films on Fe-18Cr Alloy , Pages 285-290 , Shinji Fujimoto Effects of EDTA on the Electronic Properties of Passive Film on Fe-20Cr in pH 8.5 Buffer Solution , Pages 291-297 , EunAe Cho, SeJin Ahn, HyukSang Kwon Electrochemical and Mott-Schottky Behaviour of the Oxide Films on I625 Exposed to Gamma Radiation , Pages 299-304 , James F. Dante, Darrell S. Dunn, Kendra T. Price Oxygen Reduction on Passive Steel and Cr Rich Alloys for Concrete Reinforcement , Pages 305-310 , Alberto A. Sagüés, Sannakaisa Virtanen, Patrik Schmuk Diffusivity of point defects in the passive film on Fe , Pages 311-316 , SeJin Ahn, HyukSang Kwon Electrochemical impedance of thin rust film fabricated artificially , Pages 317-323 , M. Itagaki, H. Araki, K. Watanabe, H. Katayama, K. Noda A new approach to describe the passivity of nickel and titanium oxides , Pages 325-330 , Román Cabrera-Sierra, Ignacio González, Jorge Ávalos-Martínez, Gerardo Vázquez, Máximo A. Pech-Canul Relation of the photocurrents to the corrosion rates of pure aluminum having various oxides , Pages 331-336 , Maia C. Romanes, Kathleen A. Donovan, T. David Burleigh Growth and characterization of anodic films on Al-Nb alloys , Pages 337-342 , M. Santamaria, F. Di Quarto, M. Gentile, P. Skeldon, G.E. Thompson Amorphous semiconducting passive film-electrolyte junctions revisited. The influence of a non homogeneous density of state on the differential admittance behaviour of anodic a-Nb 2 O 5 , Pages 343-348 , F. La Mantia, M. Santamaria, F. Di Quarto Influence of Protein Adsorption on the Passivation of Dental Amalgams , Pages 351-356 , Christopher M.A. Brett, Elsa Jorge, Carla Gouveia-Caridade, Humberto Dias BSA adsorption on Fe-17Cr in acid solution: Electrochemical behaviour and surface composition , Pages 357-363 , Luis Lartundo-Rojas, Isabelle Frateur, Anouk Galtayries, Philippe Marcus XPS characterisation of BSA adsorption on stainless steel , Pages 365-370 , Sandrine Zanna, Chantal Compère, Philippe Marcus Study of corrosion behaviour of Ti-coated AISI 316L stainless steel in a simulated body fluid solution , Pages 371-376 , F. Hellal, F. Atmani, B. Malki, H. Sedjal, M. Kerkar, F. Dalard Effect of Al on the passivity of Ti base implant alloys , Pages 377-381 , Sannakaisa Virtanen, Helga Hildebrand, Mariana Ruczickova Improved adhesion of titanium oxide film to titanium-base alloy by Ti/O compositional gradient using reactive sputter-deposition , Pages 383-388 , Tsutomu Sonoda, Akira Watazu, Kiyotaka Katou, Tadashi Asahina Liquid crystal behavior in solutions, electrode passivation, and impedance loci in four quadrants , Pages 389-394 , C.V. Krishnan, Merrill Garnett Passive film growth and oxide layer restructuring on stainless steel in a high-temperature borate electrolyte , Pages 397-402 , Martin Bojinov, Petri Kinnunen, Klas Lundgren, Gunnar Wikmark Kinetics of passivation of nickel-base alloys (Alloy 600 and Alloy 690) in high temperature water , Pages 403-409 , A. Galtayries, A. Machet, P. Jolivet, P. Scott, M. Foucault, P. Combrade, P. Marcus Behaviour of oxide films in boric acid — lithium hydroxide solutions , Pages 411-416 , V. Ignatova, M. Vankeerberghen, S. Gavrilov, R.-W. Bosch, S. Van Dyck, S. Van den Berghe The Effect of CO 2 and H 2 S on the Passivation of Chromium and Stainless Steels in Aqueous Solutions at Elevated Temperature and under High Pressure , Pages 417-423 , J. Banaś, B. Mazurkiewicz, U. Lelek-Borkowska, H. Krawiec, W. Solarski, K. Kowalski Effect of Lead on Passivation of Alloy 600 Surface , Pages 425-430 , Zhongquan Zhou, Jangyul Park, J. Ernesto. Indacochea, Roger. W. Staehle, Seong S. Hwang, Nancy Finnegan, Rick Haasch Interaction of Oxide Layers on Structural Materials with Light Water Reactor Coolants - its influence on the mechanism of oxide growth and restructuring , Pages 431-436 , Martin Bojinov, Björn Beverskog Differences in Mechanical Properties of the Passive Metal Surfaces Obtained in Solution and Air , Pages 439-449 , Masahiro Seo, Daisuke Kawamata, Makoto Chiba Current Transients of Passive Iron during Micro-indentation in Solution , Pages 451-456 , Koji Fushimi, Ken-ichi Takase, Masahiro Seo Mechanical Properties of Single-Crystal Tantalum (100) Surface Covered with Anodic Oxide Film , Pages 457-462 , Daisuke Kawamata, Masahiro Seo Study of the mechanical effects on passivity breakdown by local probe techniques , Pages 463-468 , V. Vignal, N. Mary, R. Oltra Mechanical properties of metastable r.f magnetron sputter-deposited Al 1−x Cu x thin films , Pages 469-473 , Mohamed Draissia, Mohamed Y. Debili Passivity Issues in Tribocorrosion , Pages 477-487 , D. Landolt Wear in nuclear power plants, a tribocorrosion approach , Pages 489-494 , A. Beaudouin, P. Combrade, D. Kaczorowski, J-P. Vernot Comparison between tribocorrosion mechanisms of Stellite 6 and Zircaloy 4 in LiOH-H 3 BO 3 solutions , Pages 495-500 , Viorel-Eugen Iordache, François Wenger, Pierre Ponthiaux, Antoine Ambard, Jean Peybernès, Joëlle Vallory Detrimental effect of lead on the passivity of UNS N06690 alloy , Pages 501-506 , B.T. Lu, J.L. Luo, Y.C. Lu The role of Borides in the Passivity and SCC of Alloy 600 , Pages 507-512 , Yongsun Yi, Hongpyo Kim, Joungsoo Kim Effect of Nickel and Tungsten on Repassivation Rate of Stainless Steels in Chloride Solution by Potential Step Chronoamperometry , Pages 513-518 , Sung-Yu Kim, Heesan Kim, Hyuk-Sang Kwon Dislocations effect on kinetic of passivation of polycrystalline nickel in H 2 SO 4 medium , Pages 519-524 , Mohamed Sahal, Catherine Savall, Juan Creus, R. Sabot, Xavier Feaugas Electrochemical potential oscillations during galvanostatic passivation of copper in NaNO 2 solution and their role in TGSCC mechanism , Pages 525-530 , Y. Yagodzinskyy, P. Aaltonen, H. Hänninen Effects of straining on oxide films and passivity of copper in nitrite solution at ambient temperature , Pages 531-536 , P. Aaltonen, Y. Yagodzinskyy, H. Hänninen Repassivation Kinetics of Al-Alloys for Aircraft Structures , Pages 537-542 , Joachim Wloka, Theo Hack, Sannakaisa Virtanen Localized Corrosion Growth Kinetics in AA7178 , Pages 545-554 , G.S. Frankel, Tsai-Shang Huang, Xinyan Zhao An in situ AFM study of the first steps of localised corrosion on a stressed 304L stainless steel in chloride media , Pages 555-560 , Frantz Martin, Sophie Fréchard, Christian Bataillon, Jacques Cousty Initial stage of localized corrosion in artificial pit formed on zinc coated steels by photon rupture , Pages 561-566 , Sakairi Masatoshi, Uchida Yoshiyuki, Takahashi Hideaki Influence of the chemical dissolution of MnS inclusions on the composition of passive films and the local electrochemical behaviour of stainless steels , Pages 567-572 , H. Krawiec, V. Vignal, R. Oltra, O. Heintz Electrochemical characterization of corrosion resistant alloys in chloride solutions , Pages 573-578 , Fabio Bolzoni, Patrizia Fassina, Gabriele Fumagalli, Sara Goidanich Effect of HCl on Pickling of 304 Stainless Steel in Iron Chloride-Based Electrolytes , Pages 579-584 , Lian-Fu Li, Mathieu Daerden, Peter Caenen, Jean-Pierre Celis Influence of thermal oxides on pitting corrosion of austenitic and duplex steels , Pages 585-590 , Vesna Alar, Vera Rede, Ivan Juraga, B. Runje Modifications in the electrochemical behaviour of SAF 2205 in alkaline media induced by Cl − ions , Pages 591-596 , C.M. Abreu, M.J. Cristóbal, R. Losada, X.R. Nóvoa, G. Pena, M.C. Pérez In-situ Raman spectroscopy study of iron and carbon steel corrosion in mineral water , Pages 597-602 , Lise Lanarde, Suzanne Joiret, Xavier Campaignolle, Michel Meyer Effect of Noble Element Alloying on Passivity and Passivity Breakdown of Ni , Pages 603-608 , Yeong Ho Kim, G.S. Frankel, J.C. Lippold Analysis of Electrochemical Noise of Pure Aluminium in Sulphate and Molybdate Ion-Containing 0.1 M NaCl Solution , Pages 609-614 , Su-Il Pyun, Kyung-Hwan Na Localized corrosion of 2024 alloy: Structure and composition of oxide films grown on model alloys representative of the different metallurgical phases , Pages 615-620 , Christine Blanc, Georges Mankowski, Corinne Dufaure, Claude Mijoule, Yolande Kihn Passivity Breakdown of Aluminum Alloys by Trace Element Lead , Pages 621-626 , Kemal Nişancıoğlu, Øystein S˦vik, Yingda Yu Passivity Breakdown of Aluminum Alloys by Surface Enrichment of Group IIIA – VA Trace Elements , Pages 627-632 , Brit Graver, Øystein S˦vik, Yingda Yu, Kemal Nisancioglu Electrochemical behaviour of Al and some of its alloys in chloride solutions , Pages 633-638 , Sherif Zein El Abedin, Frank Endres Cooperative Spreading of Pit Sites as a New Explanation for Critical Threshold Potentials , Pages 641-650 , J.R. Scully, N.D. Budiansky, L. Organ, A.S. Mikhailov, J.L. Hudson Atomistic simulation of the passivation of iron-chromium alloys using calculated local diffusion activation barriers , Pages 651-657 , Boubakar Diawara, Yves-Alain Beh, Philippe Marcus DFT study of the interactions of Cl − with passivated Nickel surfaces: Energetic and structural aspects , Pages 659-665 , B. Diawara, A. Bouzoubaa, N. Pineau, C. Minot, V. Maurice, P. Marcus Simulation of corrosion processes with anodic and cathodic reactions separated in space , Pages 667-672 , Janusz Stafiej, Abdelhafed Taleb, Chrisitine Vautrin-Ul, Annie Chaussé, Jean Pierre Badiali On the Interaction of Organic Molecules with Metal Oxide Surfaces , Pages 675-683 , H. Terryn, O. Blajev, S. Van Gils, J. van den Brand, A. Ithurbide, E. Vandeweert, J. Snauwaert, A. Hubin, C. Van Haesendonck Formation of Al-Si Composite Oxide Films on Aluminum by Electrophoretic Sol-Gel Coating / Anodizing , Pages 685-690 , H. Takahashi, M. Sunada, T. Kikuchi, M. Sakairi, S. Hirai In-situ Raman Spectroscopy and Spectroscopic Ellipsometry study of the iron/Polypyrrole interface , Pages 691-696 , T. Van Schaftinghen, S. Joiret, C. Deslouis, H. Terryn Spontaneous grafting of iron surfaces by reduction of aryldiazonium salts in acidic water. Applications to the inhibition of iron corrosion , Pages 697-702 , Fetah I. Podvorica, Catherine Combellas, Michel Delamar, Frédéric Kanoufi, Jean Pinson Conversion coating of zinc heptanoate in aqueous media on electrogalvanized steel , Pages 703-708 , S. Jacques, E. Rocca, M-J. Stébé, H. Derule, N. Genet, J. Steinmetz Study of carbon steel corrosion inhibition in alkaline solution by means of EIS , Pages 709-714 , Gianni Rondelli, Luciano Lazzari, Marco Ormellese, Ramon Novoa, Elmer Pérez Nitrided/nitrocarburized and oxidized steel: Corrosion data in dependence on the N- and C-content of the ɛ-phase under the oxide layer , Pages 715-720 , U. Ebersbach Passivation treatments on Zn and Zn alloys substrates involving Mo and W compounds , Pages 721-727 , L. Anicai, A. Petica, M. Buda, T. Visan Electrochemical Properties and Applications of Sputtered Iridium Oxide Thin Films , Pages 729-735 , Evelina P. Slavcheva, Uwe Schnakenberg, Wilfried Mokwa Study of DSA® deactivation , Pages 737-742 , E. Herrera Calderon, R. Wüthrich, H. Bleuler, Ch. Comninellis Index , Pages 743-747 Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers contains a selection of papers presented at PASSIVITY-9, the 9th International Symposium on the Passivation of Metals and Semiconductors and the Properties of Thin Oxide Layers, which was held in Paris, 27 June - 1 July, 2005. One hundred and twelve peer-reviewed manuscripts have been included.

The book covers all the fundamental and applied aspects of passivity and provides a relevant and updated view of the advances and new trends in the field. It is structured in ten sections:

• Growth, (Nano)structure and Composition of Passive Films
• Passivity of Semiconductors
• Electronic Properties of Passive Films
• Passivity Issues in Biological Systems
• Passivity in High-Temperature Water
• Mechanical Properties of Passive Films,
• Passivity Issues in Stress Corrosion Cracking and Tribocorrosion
• Passivity Breakdown and Localized Corrosion
• Modeling and Simulation
• Surface Modifications and Inhibitors (for Improved Corrosion Resistance and/or Adhesion)