Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents (Volume 41) (Comprehensive Chemical Kinetics, Volume 41)

Content: Section 1. The practice and theory of kinetics (v.1-3). Section 2. Homogeneous decomposition and isomerisation reactions (v.4-5) Section 3. Inorganic reactions (v.6-7) Section 4. Organic reactions (v.8-13) Section 5. Polymerisation reactions (v.14-15) Section 6. Oxidation and combustion reactions (v.16-17) Section 7. Selected elementary reactions (v.18) Section 8. Heterogeneous reactions (v.19-22) Section 10. Modern methods, theory, and data (v.24-41) -- Section 11? Modeling of chemical reactions (v.42) The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented.
This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry.

* First book devoted to oxoacids and oxobases
* Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena
* The perfect handbook for beginners looking for preliminary knowledge about methods of investigation The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry. * First book devoted to oxoacids and oxobases * Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena * The perfect handbook for beginners looking for preliminary knowledge about methods of investigation Content: Editorial Board Page V List of symbols Pages VIII-IX Introduction Pages XI-XV VictorL. Cherginets Chapter 1 Homogeneous acid–base equilibria and acidity scales in ionic melts Pages 1-128 Chapter 2 Oxygen electrodes in ionic melts. Oxide ion donors Pages 129-228 Chapter 3 Equilibria in “Solid oxide–ionic melt” systems Pages 229-345 Afterword Pages 347-350 References Pages 351-372 Formula index Pages 373-377 Subject index Pages 379-382 The Arrhenius definition, known as the theory of electrolytic dissociation (TED) appropriate for the description of aqueous solutions, was historically the first definition of this kind.