Numerical data and functional relationships in science and technology new series Subvol. a Gruppe 4: Makroskopische und technische Eigenschaften der Materie = Group 4: Macroscopic and technical properties of matter. Bd. 8. Thermodynamic properties of orga

The temperatures and the enthalpies of both solid-solid and solid-liquid phase transition were collected from the origi- nal literature published from the end of last century to early 1995. All the values were critically evaluated to pro- vide recommended values in the cases where several experi- mental values were reported for the same phase transition. The accuracies of both the original and recommended values were determined and information was given regarding the sam- ple purity and method of measurement. This volume will be useful to a wide community of researchers, specialists and engineers working in the field of physical and organic chem- istry, chemical engineering, electronics, material science, chemical aspects of energy technology, and those developing computerized predictive packages, and for universities. Basic Concepts of Enthalpies of Fusion and Transition 7 Definitions 7 Thermodynamic Principles of Phase Transitions 10 Type of Phases 12 Temperature Dependence of Enthalpies of Fusion and Transition 14 Application of Enthalpies of Fusion and Transition in Chemical Engineering and Thermodynamics 15 References 15 Determination of Enthalpies of Fusion and Transition 17 Adiabatic Calorimeter 17 Isoperibol Calorimeter 18 Isothermal Calorimeter 19 Heat Conduction Calorimeter 19 Drop Method 20 Differential Thermal Analysis 20 Differential Scanning Calorimeter 21 Cryoscopic Method 22 Difference between Enthalpies of Sublimation and Vaporization from Vapor Pressure Measurements 22 Difference of Enthalpies of Solution between Two Phases 22 References 23 Critical Compilation of Enthalpies of Fusion and Transition of Organic Compounds 25 Scope and Literature Search 25 Temperature Correction 25 Procedures for Evaluation, Processing and Selection of Data 25 Description of the Tabulated Data 26 References sections 3.1 to 3.4 29 References 431 Title, Authors, Preface....Pages 1-6 Introduction....Pages 1-23 Organic Compounds, C1 to C3....Pages 29-68 Organic Compounds, C4 to C5....Pages 73-114 Organic Compounds, C6....Pages 119-155 Organic Compounds, C7 to C8....Pages 159-208 Organic Compounds, C9 to C10....Pages 213-259 Organic Compounds, C11 to C12....Pages 263-295 Organic Compounds, C13 to C14....Pages 299-325 Organic Compounds, C15 to C17....Pages 329-354 Organic Compounds, C18 to C22....Pages 359-399 Organic Compounds, C23 to C96....Pages 403-451 References....Pages 455-484