Nanoporous Materials IV: Proceedings of the 4th International Symposium on Nanoporous Materials, Niagara Falls, Ontario, Canada June 7-10, 2005 ... in Surface Science and Catalysis, Volume 156)

Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology. This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up. * Unique contributions brings readers up-to-date on new research and application developments * Figures and tables supplement comprehensive topics * Extensive author and subject index. Read more... Content: Preface Page v Abdel Sayari, Mietek Jaroniec Organizing Committee Page vii International Advisory Committee Page vii An overview of mesostructured forms of alumina with crystalline framework walls Review Article Pages 1-10 Thomas J. Pinnavaia, Zhaorong Zhang, Randall W. Hicks Studies of anionic surfactant templated mesoporous structures by electron microscopy Original Research Article Pages 11-18 Alfonso E. Garcia-Bennett, Shunai Che, Keiichi Miyasaka, Yasuhiro Sakamoto, Tetsu Ohsuna, Zheng Liu, Osamu Terasaki Design of functional nano-structured inorganic and hybrid materials Original Research Article Pages 19-36 C. Sanchez, C. Boissière, A. Coupé, F. Goettmann, D. Grosso, B. Julián, M. Llusar, L. Nicole Organic zeolites Original Research Article Pages 37-54 D.V. Soldatov, J.A. Ripmeester Optimization of silica/surfactant ratio in MCM-41 synthesis Original Research Article Pages 55-62 Michal Kruk, Mietek Jaroniec, Hyun June Shin, Ryong Ryoo Synthesis of MCM-41 under ultrasonic conditions Original Research Article Pages 63-68 Yongmei Liu, Yingyue Qin, Yongkang Lv, Weiren Bao, Tao Dou, Kechang Xie In-situ studies of the formation mechanism of SBA-15 Original Research Article Pages 69-74 Viveka Alfredsson, Heinz Amenitsch, Katarina Flodström, Mika Lindén, Cilâine V. Teixeira, Hkan Wennerström Optimization of synthesis time for SBA-15 materials Original Research Article Pages 75-82 Pasquale F. Fulvio, Mietek Jaroniec Tuning the morphology of SBA-15 by stirring in the presence of phosphoric acid: films, cakes, fibers and bundles of threads Original Research Article Pages 83-88 Raghuraman Pitchumani, Wenjiang Li, Marc-Olivier Coppens Acid-Free synthesis of mesostructured silica materials in a triblock copolymer-based system Original Research Article Pages 89-96 Shih-Yuan Chen, Soofin Cheng Preparation of mesostructured silica using a nonionic fluorinated surfactant: Relation between mesoporous characteristics and surfactant phase behavior Original Research Article Pages 97-104 J.L. Blin, M.J. Stébé Influence of synthesis time on adsorption properties of FDU1 materials Original Research Article Pages 105-112 Rafal M. Grudzien, Mietek Jaroniec Synthesis and characterization of nanoscale aluminosilicate mesoporous materials by microwave irradiation Original Research Article Pages 113-118 C.-F. Cheng, H.-H. Cheng, L.-L. Wu, B.-W. Cheng Synthesis and characterization of mesoporous aluminosilicates from zeolitic precursors and TEOS Original Research Article Pages 119-124 J.L. Zheng, S.R. Zhai, D. Wu, Y.H. Sun Mesostructured aluminosilica oxynitrides: solid acid-base materials prepared via post-synthesis grafting routes Original Research Article Pages 125-132 Yongde Xia, Robert Mokaya Synthesis and characterization of gallosilicate mesoporous molecular sieves SBA-15 Original Research Article Pages 133-138 C.-F. Cheng, H.-H. Cheng Direct synthesis of Cu-modified MCM-41 functional materials Original Research Article Pages 139-146 Z.Y. Wu, Y.M. Wang, J.H. Zhu Behaviour of NiO and Ni o pohases at high loadings, in SBA-15 and SBA-16 mesoporous silica matrices Original Research Article Pages 147-154 D. Kantorovich, L. Haviv, L. Vradman, M.V. Landau A novel mixed cationic-nonionic surfactant templating approach for the synthesis of mesoporous niobium containing silica-a promising epoxidation catalyst Original Research Article Pages 155-162 I. Nowak, M. Ziolek Synthesis of niobium molecular sieves with a new Nb source and catalytic oxidation of cyclohexene Original Research Article Pages 163-170 Eliezer Ladeia Gomes, Dilson Cardoso Physicochemical properties of FSM-16 modified by fluoride and HPA Original Research Article Pages 171-176 P. Pérez-Romo, M.L. Guzmán-Castillo, H. Armendáriz-Herrera, R. Flores-Rodríguez, J. Navarrete-Bolaños, J.A. Montoya de la Fuente, J.J. Fripiat Immobilization of tungstophosphoric acid in mesoporous silica Original Research Article Pages 177-182 Nongyue He, Chun Yang, Chang-Soo Woo, Ho-In Lee Morphological change of PMO and SBA-15 by metamorphic reconstruction Original Research Article Pages 183-190 S.S. Park, S.J. Kim, Y.-K. Seo, D.H. Park Synthesis and characterization of vinyl-functionalized SBA-15 by a direct synthesis grafting method Original Research Article Pages 191-196 Byeong-Gyu Park, Jin-Woo Park, Sung Soo Park, Il Kim, Chang-Sik Ha Synthesis and adsorption properties of periodic mesoporous organosilicas with large heterocyclic bridging groups Original Research Article Pages 197-204 Oksana Olkhovyk, Mietek Jaroniec Functionalized mesoporous SBA-15 silica with propylsulfonic groups as catalysts for esterification of salicylic acid with dimethyl carbonate Original Research Article Pages 205-212 Yan Zheng, Xiaowei Su, Xuehong Zhang, Wei Wei, Yuhan Sun Preparation of hydrothermally stable mercapto-functionalized mesoporous silicas via assembly of nanoclustered zeolite Y seeds and 3-mercaptopropyltrimethoxysilane Original Research Article Pages 213-220 Ningya Yu, Junlin Zheng, Qunli Tang, Dong Wu, Yuhan Sun, Wei Hu, Wuyang Liu, Feng Deng Functionalization of mesoporous silica by condensation of tetramethoxysilane and alkyl peptidoamine monomers in the presence of a non-ionic fluorinated surfactant Original Research Article Pages 221-228 J.L. Blin, C. Gérardin, L. Rodehüser, C. Selve, M.J. Stébé Functionalization of HMS mesoporous molecular sieves and their base-catalytic performance Original Research Article Pages 229-236 Chun Yang Grafting of [CpMo(CO) 3 ] − Na + on 3,6-dichloro-pyridazine modified mesoporous MCM-41 and MCM-48 molecular sieves Original Research Article Pages 237-242 Ayyamperumal Sakthivel, Jin Zhao, Fritz E. Kühn The generation of mesoporous CeO 2 with crystalline pore walls using novel block copolymer templates Original Research Article Pages 243-248 T. Brezesinski, B. Smarsly, M. Groenewolt, M. Antonietti, D. Grosso, C. Boissière, C. Sanchez Preparation of tailored pore size mesoporous zirconia with enhanced thermal stability via controlled sol-gel process Original Research Article Pages 249-256 Yachun Liu, Jiangang Chen, Yuhan Sun Hydrotalcites (HTs) and mesoporous mixed oxides obtained from HTs, basic solid catalysts for cyclohexanone condensation Original Research Article Pages 257-264 E. Angelescu, R. Bîrjega, O.D. Pavel, M. Che, G. Costentin, S. Popoiu Doping of rare earth elements into microporous and mesoporous aluminophosphate Original Research Article Pages 265-272 Wenfu Yan, Zongtao Zhang, Jun Xu, Shannon M. Mahurin, Sheng Dai Colloidal crystals as templates for zinc sulfide inverse opal via solvothermal approach Original Research Article Pages 273-278 J.-M. Cao, X. Chang, M.-B. Zheng, H.-B. Huang, Y.-L. Cao, X.-F. Ke Preparation of nanostructured boron nitride with borazinic precursor Original Research Article Pages 279-286 P. Dibandjo, L. Bois, F. Chassagneux, B. Toury, D. Cornu, F. Babonneau, P. Miele Mesostructured and mesoporous pure and substituted barium hexaferrite phases Original Research Article Pages 287-294 Eugenia E. Macias, Vadim V. Guliants, Moises A. Carreon Porosity analysis of spin-on mesoporous silica films Original Research Article Pages 295-302 Chih-Yuan Ting, Hwo-Shuenn Sheu, Ben-Zu Wan Controlling morphological, orientational and material properties of mesoporous aluminosilicate films: enabling supercritical fluid deposition of perpendicularly ordered nanowire arrays Original Research Article Pages 303-314 Kevin M. Ryan, Daniel M. Lyons, Justin D. Holmes, R. Farrell, E. Brennan, M.A. Morris Electrochemically self-assembled mesoporous dye-modified zinc oxide thin films Original Research Article Pages 315-320 J. Rathousky, T. Loewenstein, K. Nonomura, T. Yoshida, M. Wark, D. Schlettwein Preparation of crack-free, transparent, nanoporous niobium oxide film with crystalline structure by evaporation-induced self-assembly (EISA) process Original Research Article Pages 321-326 Kiyotaka Nakajima, Nao Shirokura, Byongjin Lee, Junko N. Kondo, Michikazu Hara, Kazunari Domen Ordered mesoporous organosilica films Original Research Article Pages 327-334 M. Matheron, T. Gacoin, J.-P. Boilot, A. Bourgeois, A. Brunet-Bruneau, J. Rivory, A. Jimenez, J. Biteau Effect of exchangeable cation and hydration layer on the swelling property of 2:1 dioctahedral smectite clay—a periodic density functional study Original Research Article Pages 335-342 Abhijit Chatterjee, Fujio Mizukami, Akira Miyamoto Isolation, characterization and modification of clay solids from oil sand wastes Original Research Article Pages 343-348 Abdul Majid, Steve Argue, Jim Margeson New modifications of layered MCM-36 molecular sieve pillared with various mixed oxides: facts and perspectives Original Research Article Pages 349-356 J. Kornatowski, J.-O. Barth, J.A. Lercher New nanoparticle/LDH composite materials as precursors of supported metal catalysts Original Research Article Pages 357-362 C. Gérardin, D. Kostadinova, N. Sanson, D. Francova, N. Tanchoux, D. Tichit, B. Coq Synthesis and catalytic application of tantalum and silica pillared porous materials from layered silicate ilerite Original Research Article Pages 363-370 Sun Jin Kim, Min Jo Park, Hun Jung, Kwang-Deog Jung, Oh-Shim Joo Optimal design of hierarchically structured nanoporous catalysts Original Research Article Pages 371-378 Marc-Olivier Coppens, Stefan Gheorghiu, Peter Pfeifer Synthesis of hierarchically structured MCM-41 with high hydrothermal stability and its application in environmental catalysis Original Research Article Pages 379-384 Su Liu, Lingdong Kong, Xuewu Yan, Quanzhi Li, Adi He Effect of nanoporous ZrO 2 crystal size on the surface sulphur capacity and performance of sulfated zirconia as an acidic catalytic material Original Research Article Pages 385-392 M.V. Landau, L. Titelman, A.M. Shapira-Tchelet, P. Wilson, D. Tavor, L. Vradman, A. Wolfson A dry gel synthesis route to mesoporous ZSM-5 catalysts Original Research Article Pages 393-400 C. Chou, C.S. Cundy, A.A. Garforth Role of intrinsic zeolite properties on mesopore formation by desilication of MFI structures Original Research Article Pages 401-408 J.C. Groen, L.A.A. Peffer, J.A. Moulijn, J. Pérez-Ramírez Selective introduction of solid acid sites into the mesopore surface of non-acidic USY zeolite by aluminum insertion Original Research Article Pages 409-416 Hiromichi Shimada, Kosaku Honna, Yasuhiro Araki, Yoichi Nishimura Influence of zirconium on the crystallisation kinetics of ETS-4 molecular sieves Original Research Article Pages 417-422 D. Vuono, C.C. Pavel, P. De Luca, J.B. Nagy, A. Nastro Synthesis of silver nanoparticles within ordered CMK-3 mesoporous carbon Original Research Article Pages 423-426 J.M. Cao, Y.L. Cao, X. Chang, M.B. Zheng, J.S. Liu, H.M. Ji Supercritical carbon dioxide as medium for the formation of gold nanoparticles into MCM-41 and its catalytic activity Original Research Article Pages 427-432 M. Chatterjee, Y. Ikushima 3D design of self-assembled nanoporous colloids Original Research Article Pages 433-442 I. Sokolov, Y. Kievsky Fabrication and porosity control of mesoporous polycarbosilane from SBA-15 templated polymethylsilane Original Research Article Pages 443-450 J.H. Cheon, S.J. Kim, Y.-K. Seo, D.H. Park Structuration of organo-minerals: nanohybrid materials resulting from the incorporation of alcohols in the tunnels of palygorskite Original Research Article Pages 451-456 W. Kuang, C. Detellier Synthesis and characterization of mesostructured alloys with controlled compositions Original Research Article Pages 457-464 Y. Yamauchi, S. Sadasivan Nair, T. Yokoshima, T. Momma, T. Osaka, K. Kuroda One-pot synthesis and characterization of high surface area perovskite-type BaTiO 3 with mesoporous texture Original Research Article Pages 465-472 Bo Hou, Zhijie Li, Yao Xu, Dong Wu, Yuhan Sun Novel non-surfactant pathway to controllable micro/mesoporous bimodal xerogels Original Research Article Pages 473-480 D.-J. Yang, S.-R. Zhai, Y. Xu, J.-L. Zheng, D. Wu, Y.-H. Sun, F. Deng An ultrafiltration membrane, prepared with MSU-type mesoporous silica: preparation and specific filtration behavior Original Research Article Pages 481-488 Eric Prouzet, André Larbot, Cédric Boissière, Marco U. Martines Synthesis and adsorption properties of FDU-1 silica with carbon deposited in mesopores Original Research Article Pages 489-496 Ewa B. Celer, Mietek Jaroniec Flexible coordination polymers as novel porous materials Original Research Article Pages 497-504 Tapas Kumar Maji, Ryotoro Matsuda, Susumu Kitagawa Conducting polymer and carbon mesoporous structures by electrochemical syntheses Original Research Article Pages 505-516 L.T. Qu, L.C. Li, V. Bajpai, G.Q. Shi, L. Dai Preparation and electrorheological property of conducting copolyaniline/MCM-41 nanocomposite Original Research Article Pages 517-522 Il Sang Lee, Min Seong Cho, Cheng Hai Hong, Hyoung Jin Choi, Sang Soon Yoon, Wha-Seung Ahn Synthesis and characterization of intercalated mesostructured PANI/V 2 O 5 Original Research Article Pages 523-528 Li Li, Zi-Feng Yan Synthesis, characterization and application of poly (butyl acrylate -co-methyl methacrylate)/clay nanocomposites via emulsion polymerization Original Research Article Pages 529-534 Zhiyi Zhang, Ning Zhao, Wei Wei, Dong Wu, Yuhan Sun Mesoporous carbon prepared by nanocasting of MCM-41 and MCM-48 nanospheres Original Research Article Pages 535-542 M. Wallau, L. Dimitrov, E.A. Urquieta-González SBA-15 templated-ordered mesoporous carbon: effect of SBA-15 microporosity Original Research Article Pages 543-550 Yong Yang, Abdelhamid Sayari Well-ordered cubic mesoporous carbon with Im3m symmetry Original Research Article Pages 551-556 Wanping Guo, George X.S. Zhao Carbonization of sucrose in the presence of zeolite: control over pore structure and morphology Original Research Article Pages 557-564 Fabing Su, Lu Lv, (George) X.S. Zhao Synthesis of hollow spherical mesoporous N-doped carbon materials with graphitic framework Original Research Article Pages 565-572 Yongde Xia, Zhuxian Yang, Robert Mokaya Porous N-doped carbon with various hollow-cored morphologies nanocast using zeolite templates via chemical vapour deposition Original Research Article Pages 573-580 Zhuxian Yang, Yongde Xia, Robert Mokaya Pitch-based carbons synthesized by using silica colloids and ordered mesoporous silica particles as templates Original Research Article Pages 581-588 Kamil P. Gierszal, Mietek Jaroniec Electrical double-layer capacitive properties of colloidal crystaltemplated nanoporous carbons Original Research Article Pages 589-594 I. Moriguchi, F. Nakawara, H. Yamada, T. Kudo Generating selective adsorptive sites on activated carbon Original Research Article Pages 595-602 Y. Cao, L.Y. Shi, C.F. Zhou, T.T. Zhuang, Y. Wang, J.H. Zhu Synthesis, characterization and hydrogen storage on ordered carbon adsorbents Original Research Article Pages 603-608 Louis C Chen, Ranjeet K Singh, Paul A Webley Monitoring the preparation of spherical activated carbon from sulfonated styrene-divinylbenzene copolymer Original Research Article Pages 609-616 S.B. de Oliveira, D. Rabelo, M.C. Rangel The sorption of butanes over carbon nanotubes Original Research Article Pages 617-624 Zs. Ötvös, Gy. Onyestyák, J. Valyon, I. Kiricsi, L.V.C. Rees Adsorption of benzene on MCM-41-type material: A QM/MM study Original Research Article Pages 625-630 Bavornpon Jansang, Jumras Limtrakul Adsorption of amino acid on mesoporous molecular sieves Original Research Article Pages 631-636 A. Vinu, K.Z. Hossain, G. Satish Kumar, V. Sivamurugan, K. Ariga Adsorption of lysozyme over mesoporous carbons with various pore diameters Original Research Article Pages 637-642 A. Vinu, M. Miyahara, K.Z. Hossain, T. Nakanishi, K. Ariga Competition between organics adsorbed in mesoporous MCM-41 materials: predictions for heterogeneous catalysis Original Research Article Pages 643-648 Philippe Trens, Nathalie Tanchoux, Daniel Maldonado, Francesco Di Renzo, François Fajula Famotidine drug adsorption on carboxylic acid functionalized ordered SBA-15 mesoporous silica Original Research Article Pages 649-656 Qunli Tang, Ningya Yu, Zhijie Li, Dong Wu, Yuhan Sun Acidity and sorption properties of nano-sized mesoporous aluminosilicate materials Original Research Article Pages 657-662 Wen-Hua Chen, Shing-Jong Huang, Hui-Hsin Ko, An-Ya Lo, Huang-Kuei Lee, Li-Li Wu, Chi-Feng Cheng, Shang-Bin Liu Pore size characterization of mesoporous materials by a thermodynamic approach: A curvature-dependent solid-fluid potential Original Research Article Pages 663-672 E.A. Ustinov, D.D. Do, M. Jaroniec Characterization of pore structure of copolymer-templated periodic mesoporous organosilicas Original Research Article Pages 673-682 Oksana Olkhovyk, Michal Kruk, Rebecca Sutton, Mietek Jaroniec Influence of the wall heterogeneity on the layering transition in cylindrical pores Original Research Article Pages 683-688 B. Kuchta, L. Firlej Melting of krypton monolayers adsorbed on carbon nanopores Original Research Article Pages 689-694 L. Firlej, B. Kuchta Determination of cardiac troponin I by anodic stripping voltammetry at SBA-15 modified carbon paste electrode Original Research Article Pages 695-702 Hui-Shi Guo, Nong-Yue He, Shu-Xun Ge, Di Yang, Ji-Nan Zhang Spectroscopic characterization and catalytic performances of Iron substituted three dimensional cubic SBA-1 and KIT-5 mesoporous molecular sieves Original Research Article Pages 703-710 A. Vinu, G. Chandrasekar, M. Hartmann, K. Ariga Photoluminescence property of [Eu(bpy) 2 ] 3+ dispersed in mesoporous materials SBA-15 Original Research Article Pages 711-716 Shuxun Ge, Nongyue He, Chun Yang, Jieming Cao, Hong Chen, Min Gu Microemulsion templated mesoporous silica: characterisation via small angle x-ray scattering and stability in aqueous buffers Original Research Article Pages 717-724 S. Boskovic, C.F. Maitland, J. Connolly, C.E. Buckley, T.W. Turney, M.L. Lee, G.W. Stevens, A.J. O'Connor Dynamics of guests in microporous coordination polymers studied by solid state NMR and X-ray analysis Original Research Article Pages 725-732 Satoshi Horike, Ryotaro Matsuda, Susumu Kitagawa Molecular designed vanadia–titania supported SBA-15 for the oxidative dehydrogenation of isobutane and propane Original Research Article Pages 733-740 Yolanda Segura, Johan S. Paul, Kevin Huyghe, Walter Vermandel, Pegie Cool, Etienne F. Vansant, Bert F. Sels, Pierre A. Jacobs Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology.

This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up.

* Unique contributions brings readers up-to-date on new research and application developments
* Figures and tables supplement comprehensive topics
* Extensive author and subject index