Nanoporous Materials III : proceedings of the 3rd International Symposium on Nanoporous Materials, Ottawa, Ontario, Canada, June 12-15, 2002

Nanoporous Materials III contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 3rd Conference on Nanoporous Materials, which will be hosted in Ottawa, Canada, June 2002. The work covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves M41S and FSM16 and related materials including clays, carbon molecular sieves, colloidal crystal templated organic and inorganic materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic and separation processes as well as the development of nanotechnology. The contents of this title are based on topics to be discussed by invited lecturers, which deal with periodic mesoporous organosilicas, stability and catalytic activity of aluminosilicate mesostructures, electron microscopy studies of ordered materials, imprinted polymers and highly porous metal-organic frameworks. The other contributions deal with tailoring the surface and structural properties of nanoporous materials, giving a detailed characterization as well as demonstrating their usefulness for advanced adsorption and catalytic applications. Content: Preface Page v Abdel Sayari, Mietek Jaroniec Organizing Committee Page vii International Advisory Committee Page vii Recent developments in the synthesis and chemistry of periodic mesoporous organosilicas Original Research Article Pages 1-26 Tewodros Asefa, Geoffrey A. Ozin, Hiltrud Grondey, Michal Kruk, Mietek Jaroniec Porous materials: Looking through the electron microscope Original Research Article Pages 27-34 O. Terasaki, T. Ohsuna, Z. Liu, M. Kaneda, S. Kamiya, A. Carlsson, T. Tsubakiyama, Y. Sakamoto, S. Inagaki, S. Che, T. Tatsumi, M.A. Camblor, R. Ryoo, D. Zhao, G. Stucky, D. Shindo, K. Hiraga Molecular imprinting-a way to prepare effective mimics of natural antibodies and enzymes Original Research Article Pages 35-44 Günter Wulff Plugged hexagonal mesoporous templated silica: A unique micro- and mesoporous material with internal silica nanocapsules Original Research Article Pages 45-52 P. Van Der Voort, P.I. Ravikovitch, A.V. Neimark, M. Benjelloun, E. Van Bavel, K.P. De Jong, B.M. Weckhuysen, E.F. Vansant Imprinting of the surface of mesoporous silicates using organic structure directing agents Original Research Article Pages 53-60 Kaveri R. Sawant, Raul F. Lobo Synthesis and characterization of polymer-templated ordered silica with cage-like mesostructure Original Research Article Pages 61-68 Jivaldo R. Matos, Michal Kruk, Lucildes P. Mercuri, Mietek Jaroniec The modeling of wall structure of siliceous MCM-41 based on the formation process Original Research Article Pages 69-76 Yasunori Oumi, Kazuhiko Azuma, Takuji Ikeda, Shintaro Sasaki, Tsuneji Sano Pore size adjustment of bimodal mesoporous silica molecular sieves Original Research Article Pages 77-84 Xiaozhong Wang, Tao Dou, Dong Wu, Bing Zhong Alcothermal synthesis of large pore, high quality MCM-48 silica Original Research Article Pages 85-92 Jihong Sun, Marc-Olivier Coppens Studies of MCM-41 obtained from different sources of silica Original Research Article Pages 93-100 Icaro S. Paulino Synthesis and characterization of hexagonal mesoporous materials using hydrothermal restructuring method Original Research Article Pages 101-108 Kyoung-Ku Kang, Hyun-Ku Rhee Synthesis of highly ordered mesoporous compounds with control of morphology using a non-ionic surfactant as template Original Research Article Pages 109-116 A. Léonard, J.L. Blin, B.-L. Su Towards a better understanding on the mechanism of mesoporous formation via an assembly of C n (EO) m and TMOS Original Research Article Pages 117-125 J.L. Blin, A. Léonard, G. Herrier, G. Philippin, B.-L. Su Mesoporous silicas via organic-inorganic hydrids based on charged polymers Original Research Article Pages 127-132 Graham M Gray, John N Hay Mesoporous silicas of hierarchical structure by hydrothermal surfactant-templating under mild alkali conditions Original Research Article Pages 133-140 Zhong-Yong Yuan, Wuzong Zhou, Bao-Lian Su, Lian-Mao Peng Synthesis and characterisation of super-microporous aluminosilicates prepared via primary amine templating Original Research Article Pages 141-150 Ernesto Bastardo-Gonzalez, Robert Mokaya, William Jones Al-MCM-41 synthesis using Al-isopropoxide as Al source Original Research Article Pages 151-158 R. Bîrjega, R. Ganea, C. Nenu, Gr. Pop, A. Jitianu Mesoporous aluminosilicates from coal fly ash Original Research Article Pages 159-166 P. Kumar, N. Mal, Y. Oumi, T. Sano, K. Yamana New route for synthesis of highly ordered mesoporous silica with very high titanium content Original Research Article Pages 167-172 Xiang-Hai Tang, Xin Wen, Shi-Wei Sun, Hai-Yan Jiang Synthesis and characterization of Ti-containing mesoporous alumina molecular sieves Original Research Article Pages 173-182 Chun Yang, Xi Li Organizing one-dimensional molecular wires in ordered mesoporous silica Original Research Article Pages 183-188 Zongtao Zhang, Douglas A. Blom, Sheng Dai Synthesis and catalytic properties of organically modified Ti-HMS Original Research Article Pages 189-196 Yong Yang, Abdelhamid Sayari Synthesis and characterization of methyl- and vinyl-functionalized ordered mesoporous silicas with high organic content Original Research Article Pages 197-204 Michal Kruk, Tewodros Asefa, Mietek Jaroniec, Geoffrey A. Ozin Polyfunctionalized silica adsorbents obtained by using dodecylamine as template Original Research Article Pages 205-212 I.V. Mel'nyk (Seredyuk), Yu.L. Zub, A.A. Chuiko, M. Jaroniec, S. Mann Characterization of mesoporous thin films formed with added organophosphonate and organosilane Original Research Article Pages 213-220 Michael A. Markowitz, Eva M. Wong, Bruce P. Gaber Improving the hydro-stability of MCM-41 by post-synthesis treatment and hexamethyldisilazane coating Original Research Article Pages 221-228 Jing Yang, Antje Daehler, Michelle L. Gee, Geoffrey W. Stevens, Andrea J. O'Connor Adsorption of CO on Zn-Cu(I)/HMCM-41 Original Research Article Pages 229-234 Qihong Shi, Nongyue He, Fei Gao, Yibing Song, Yang Yu, Huilin Wan Design of transition metal oxide mesoporous thin films Original Research Article Pages 235-242 Eduardo L. Crepaldi, Galo J. de A.A. Soler-Illia, David Grosso, Pierre-Antoine Albouy, Heinz Amenitsch, Clément Sanchez Mesoporous alumina as a support for hydrodesulfurization catalysts Original Research Article Pages 243-250 Jiří Čejka, Naděžda silková, Luděk Kaluža, Miroslav Zdražil Preparation and XAFS spectroscopic characterization of mesoporous titania with surface area more than 1200 m 2 /g Original Research Article Pages 251-256 Hideaki Yoshitake, Tae Sugihara, Takashi Tatsumi Mesoporous zirconium oxides: an investigation of physico-chemical synthesis parameters Original Research Article Pages 257-264 J.L. Blin, L. Gigot, A. Léonard, B.L. Su Single crystal particles of mesoporous (Nb, Ta) 2 O 5 Original Research Article Pages 265-272 Junko N. Kondo, Tomohiro Yamashita, Tokumitsu Katou, Byongjin Lee, Daling Lu, Michikazu Hara, Kazunari Domen Preparation of exfoliated zeolites from layered precursors: The role of pH and nature of intercalating media Original Research Article Pages 273-279 Wieslaw J. Roth, James C. Vartuli Control of mesopore structure of smectite-type materials synthesized with a hydrothermal method Original Research Article Pages 281-288 Masayuki Shirai, Kuriko Aoki, Kazuo Torii, Masahiko Arai Synthesis, characterization and catalytic application of mesoporous sulfated zirconia Original Research Article Pages 289-296 Young-Woong Suh, Hyun-Ku Rhee Synthesis of mesoporous silicoaluminophosphates (SAPO) Original Research Article Pages 297-300 Erica C. de Oliveira, Heloise O. Pastore Synthesis and characterization of mesostructured vanadium-phosphorus-oxide phases Original Research Article Pages 301-308 Moises A. Carreon, Vadim V. Guliants Novel macroporous vanadium-phosphorus-oxides with three-dimensional arrays of spherical voids Original Research Article Pages 309-316 Moises A. Carreon, Vadim V. Guliants Engineering active sites in bifunctional nanopore and bimetallic nanoparticle catalysts for one-step, solvent-free processes Original Research Article Pages 317-328 Robert Raja, John Meurig Thomas Using Au nanoparticles-surfactant aqueous solution for a convenient preparation of mesoporous aluminosilicates containing Au-nanoparticles Original Research Article Pages 329-336 Yu-Shan Chi, Hong-Ping Lin, Chinn-Nan Lin, Chung-Yuan Mou, Ben-Zu Wan The use of templated mesoporous materials as templates for the development of ordered arrangements of nanowire and nanorods of electronically important materi Original Research Article Pages 337-344 J.D. Holmes, T.R. Spalding, K.M. Ryan, D. Lyons, T. Crowley, M.A. Morris Synthesis and adsorption properties of novel carbons of tailored porosity Original Research Article Pages 345-352 Zuojiang Li, Michal Kruk, Mietek Jaroniec Flexible metal-organic frameworks with isomerizing building units Original Research Article Pages 353-362 D.V. Soldatov, J.A. Ripmeester Dynamic porous frameworks of coordination polymers controlled by anions Original Research Article Pages 363-370 Shin-ichiro Noro, Susumu Kitagawa Mesoporous polymeric materials based on comb-coil supramolecules Original Research Article Pages 371-378 Sami Valkama, Riikka Mäki-Ontto, Manfred Stamm, Gerrit ten Brinke, Olli Ikkala Electron microscopic investigation of mesoporous SBA-2 Original Research Article Pages 379-386 Wuzong Zhou, Alfonso E. Garcia-Bennett, Hazel M.A. Hunter, Paul A. Wright A study of morphology of mesoporous silica SBA-15 Original Research Article Pages 387-394 Man-Chien Chao, Hong-Ping Lin, Hwo-Shuenn Sheu, Chung-Yuan Mou SBA-15 versus MCM-41: are they the same materials? Original Research Article Pages 395-402 Anne Galarneau, Hélène Cambon, Thierry Martin, Louis-Charles De Ménorval, Daniel Brunel, Francesco Di Renzo, François Fajula Comprehensive characterization of iron oxide containing mesoporous molecular sieve MCM-41 Original Research Article Pages 403-410 Z.Y. Yuan, W. Zhou, Z.L. Zhang, Q. Chen, B.-L. Su, L.-M. Peng Mesoporous molecular sieves of MCM-41 type modified with Cs, K and Mg-physico-chemical and catalytic properties Original Research Article Pages 411-416 Maria Ziolek, Aleksandra Michalska, Jolanta Kujawa, Anna Lewandowska Meso-ALPO prepared by thermal decomposition of the organic-inorganic composite: A FTIR study Original Research Article Pages 417-422 Enrica Gianotti, Erica C. Oliveira, Valeria Dellarocca, Salvatore Coluccia, Heloise O. Pastore, Leonardo Marchese Organic-inorganic phase interaction in AlSBA-15 mesoporous solids by double resonance NMR spectroscopy Original Research Article Pages 423-428 Elias Haddad, Jean-Baptiste d'Espinose, Andrei Nossov, Flavien Guenneau, Claude Mignon, Antoine Gédéon Adsorption of nitrogen on organized mesoporous alumina Original Research Article Pages 429-436 Jirí Cejka, Lenka Veselá, Jirí Rathouský, Arnošt Zukal The use of ordered mesoporous materials for improving the mesopore size analysis: Current state and future Original Research Article Pages 437-444 Mietek Jaroniec, Michal Kruk, Abdelhamid Sayari Sorption properties and hydrothermal stability of MCM-41 prepared by pH adjustment and salt addition Original Research Article Pages 445-452 Nawal Kishor Mal, Prashant Kumar, Masahiro Fujiwara Acidity characterization of MCM-41 materials using solid-state NMR spectroscopy Original Research Article Pages 453-458 Qi Zhao, Wen-Hua Chen, Shing-Jong Huang, Yu-Chih Wu, Huang-Kuei Lee, Shang-Bin Liu Acidity of calcined Al-, Fe- and La-containing MCM-41 mesoporous materials: An investigation of adsorption of pyridine Original Research Article Pages 459-466 Nong-Yue He, Chun Yang, Zu-Hong Lu Acid properties of ammonium exchanged AlMCM-41 with different Si/Al ratio Original Research Article Pages 467-472 Antonio S. Araujo, Cristiane D.R. Souza, Marcelo J.B. Souza, Valter J. Fernandes Jr, Luiz A.M. Pontes Kinetic evaluation of the pyrolysis of high density polyethylene over H-AlMCM-41 material Original Research Article Pages 473-478 Antonio S. Araújo, Valter J. Fernandes, Sulene A. Araujo, Massao Ionashiro Electrorheological response of mesoporous materials under applied electric fields Original Research Article Pages 479-486 Min S. Cho, Hyoung J. Choi, Wha-Seung Ahn, Myung S. Jhon Synthesis and characterization of TiO 2 loaded Cr-MCM-41 catalysts Original Research Article Pages 487-494 E.P. Reddy, Lev Davydov, Panagiotis G. Smirniotis Photocatalytic ethylene polymerization over chromium containing mesoporous molecular sieves Original Research Article Pages 495-502 Hiromi Yamashita, Katsuhiro Yoshizawa, Masao Ariyuki, Shinya Higashimoto, Masakazu Anpo Catalytic reduction of nitric oxide on Al-containing mesoporous molecular sieves Original Research Article Pages 503-510 W. Li, Y. Zhang, Y. Lin, X. Yang Catalytic oxidation of alpha-eicosanol to alpha-eicosanoic acid over Ti, Zr and Mn doped MCM-48 molecular sieves Original Research Article Pages 511-516 Changping Wei, Yining Huang, Qiang Cai, Wenqin Pang, Yingli Bi, Kaiji Zhen Preparation of Pd/Al-MCM-41 catalyst and its hydroisomerization properties for long chain alkane compounds Original Research Article Pages 517-524 Shui Lin, Han Ning, Sun Wan-Fu, Liu Wei-Min, Xue Qun-Ji Alkylation of phenol with methyl tert-butyl ether over mesoporous material catalysts Original Research Article Pages 525-530 Xiang-Hai Tang, Xin-Liang Fu, Hai-Yan Jiang Isopropanol dehydration over nanostructured sulfated MCM-41 Original Research Article Pages 531-536 Antonio S. Araujo, Joana.M.F.B. Aquino, Cristiane D.R. Souza, Marcelo J.B. Souza Effects of Si/Al ratio and pore size on cracking reaction over mesoporous MCM-41 Original Research Article Pages 537-542 Wen-Hua Chen, Qi Zhao, Hong-Ping Lin, Chung-Yuan Mou, Shang-Bin Liu Hydrogenation and mild hydrocracking of synthetic crude distillate by Pt-supported mesoporous material catalysts Original Research Article Pages 543-552 Hong Yang, Craig Fairbridge, Zbigniew Ring, Randall Hawkins, Josephine M. Hill Carbon-carbon bond forming reactions catalyzed by meso- and microporous silicate-quaternary ammonium composite Original Research Article Pages 553-560 Yoshihiro Kubota, Yusuke Nishizaki, Hisanori Ikeya, Junko Nagaya, Yoshihiro Sugi A selectivity of zeolite matrices in the Cu(II) reduction process Original Research Article Pages 561-568 Vitalii Petranovskii, Valerij Gurin, Nina Bogdanchikova, Miguel-Angel Hernandez, Miguel Avalos Reduction of binary silver-copper ion mixture in mordenite: an example of synergetic behavior Original Research Article Pages 569-574 Vitalii Petranovskii, Nina Bogdanchikova Preparation, characterization and catalytic properties of CuPC/Y nano-composite Original Research Article Pages 575-582 Huaixin Yang, Ruifeng Li, Kechang Xie Environmental applications of self-assembled monolayers on mesoporous supports (SAMMS) Original Research Article Pages 583-590 Glen E. Fryxell, Yuehe Lin, Hong Wu, Kenneth M. Kemner A possible use of modified mesoporous molecular sieves in water treatment processes Original Research Article Pages 591-598 Izabela Nowak, Barbara Kasprzyk, Maria Ziolek, Jacek Nawrocki Organized mesoporous titanium dioxide—A powerful photocatalyst for the removal of water pollutants Original Research Article Pages 599-606 Jiří Rathouský, Markéta Slabová, Kateřina Macounová, Arnošt Zukal Mesoporous materials for heavy metal ion adsorption synthesized by displacement of polymeric template Original Research Article Pages 607-614 V. Antochshuk, M. Jaroniec, S.H. Joo, R. Ryoo Organically-modified mesoporous silica spheres with MCM-41 architecture as sorbents for heavy metals Original Research Article Pages 615-622 M. Etienne, S. Sayen, B. Lebeau, A. Walcarius NO and NO 2 gas sensors based on surface photovoltage system fabricated by self-ordered mesoporous silicate film Original Research Article Pages 623-630 Hao-Shen Zhou, Takeo Yamada, Keisuke Asai, Itaru Honma, Hidekazu Uchida, Teruaki Katsube Polymerisations in mesoporous environments Original Research Article Pages 631-633 James Clark, Duncan Macquarrie, Valerie Sage, Katie Shorrock, Karen Wilson Incorporation of nano-sized zeolites into a mesoporous matrix, TUD-1 Original Research Article Pages 635-640 Z. Shan, W. Zhou, J.C. Jansen, C.Y. Yeh, J.H. Koegler, Th. Maschmeyer Formation and stabilization of gold nanoparticles in organo-functionalized MCM-41 mesoporous materials and their catalytic applications Original Research Article Pages 641-646 Chitta Ranjan Patra, Anirban Ghosh, Priyabrata Mukherjee, Murali Sastry, Rajiv Kumar Entrapment and stabilization of cadmium sulphide (CdS) nanoclusters formed inside propylthiol functionalized MCM-41 mesoporous materials Original Research Article Pages 647-652 Anirban Ghosh, Chitta Ranjan Patra, Priyabrata Mukherjee, Murali Sastry, Rajiv Kumar SnO 2 nanoparticles in the pores of non-structured SiO 2 and Si-MCM-41: Comparison of their properties in gas sensing Original Research Article Pages 653-660 Yücel Altindag, Andrei Jitianu, Michael Wark Spontaneous nitride formation in the reaction of mesoporous titanium oxide with bis(toluene) titanium in a nitrogen atmosphere Original Research Article Pages 661-668 M. Vettraino, X. He, Michel Trudeau, David Antonelli Isolation and characterization of amorphous solids from oil sands fine tailings Original Research Article Pages 669-674 Abdul Majid, Steve Argue, Irina Kargina, Victor Boyko, Gerry Pleizier, Jim Tunney Author index Pages 675-678 Subject index Pages 679-682 Nanoporous Materials III contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 3rd Conference on Nanoporous Materials, which will be hosted in Ottawa, Canada, June 2002. The work covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves M41S and FSM16 and related materials including clays, carbon molecular sieves, colloidal crystal templated organic and inorganic materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic and separation processes as well as the development of nanotechnology.

The contents of this title are based on topics to be discussed by invited lecturers, which deal with periodic mesoporous organosilicas, stability and catalytic activity of aluminosilicate mesostructures, electron microscopy studies of ordered materials, imprinted polymers and highly porous metal-organic frameworks. The other contributions deal with tailoring the surface and structural properties of nanoporous materials, giving a detailed characterization as well as demonstrating their usefulness for advanced adsorption and catalytic applications.
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