راهنمای نمک‌های مذاب

Front Cover......Page 1 Title Page ......Page 4 Copyright Page......Page 5 Table of Contents......Page 8 PREFACE......Page 6 ACKNOWLEDGMENT......Page 7 CHAPTER I. PHYSICAL PROPERTIES ......Page 14 I.A. ATOMIC AND IONIC RADII, MELTING POINTS, AND BOILING POINTS OF SINGLE SALTS AND EUTECTICS ......Page 16 I.Β. DENSITY ......Page 54 I.C. VISCOSITY......Page 67 I.D. VAPOR PRESSURE......Page 78 I.E. SURFACE TENSION......Page 95 I.F. REFRACTIVE INDEX......Page 104 I.G. CRITICAL DATA......Page 108 CHAPTER II. THERMODYNAMIC PROPERTIES ......Page 112 II.A. LIQUID-LIQUID IMMISCIBILITY ......Page 114 II.Β. METAL-MOLTEN SALT SYSTEMS ......Page 119 II.C. METAL OXIDE-MOLTEN SALT SYSTEMS ......Page 133 II.D. SILVER SALTS-MOLTEN SALT SYSTEMS ......Page 135 II.Ε. PHASE-RULE STUDIES ......Page 146 II.F. SOLUBILITY ......Page 193 II.G. THERMAL DATA ......Page 201 II. Η. CRYOSCOPY AND RELATED THERMODYNAMIC STUDIES......Page 229 II.I. EXPANSIVITY, COMPRESSIBILITY, ULTRASONIC, AND HIGH PRESSURE STUDIES ......Page 265 CHAPTER III. ELECTROCHEMICAL PROPERTIES ......Page 282 IIΙ.A. REFERENCE ELECTRODES AND EMF SERIES ......Page 284 III.Β. ELECTRICAL CONDUCTANCE......Page 306 III.C. POLAROGRAPHY, CHRONOPOTENTIOMETRY, AND DOUBLE LAYER CAPACITY STUDIES......Page 337 IIΙ.D. ELECTROMIGRATION: TRANSPORT NUMBERS AND DIFFUSION......Page 361 III.Ε. DIELECTRIC AND THERMOELECTRIC PROPERTIES......Page 375 CHAPTER IV. SPECTROSCOPY AND STRUCTURE ......Page 378 IV.A. VIBRATIONAL SPECTROSCOPY......Page 380 IV.Β. VISIBLE AND U. V. SPECTROSCOPY......Page 387 IV.C. NUCLEAR MAGNETIC AND ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY ......Page 394 IV.D. X-RAY AND NEUTRON DIFFRACTION ......Page 397 IV.Ε. FUSED SALT ELECTROLYTES ......Page 401 CHAPTER V. PRACTICAL FEATURES ......Page 404 V.A. MELT PREPARATION AND PURIFICATION ......Page 406 V.Β. CONTAINMENT AND CORROSION ......Page 411 V.C. CHROMATOGRAPHIC ANALYSIS ......Page 429 V.D. ELECTROLYSIS ......Page 434 V.Ε. CHEMICAL PROCESSES ......Page 480 V.F. FUEL CELLS, BATTERIES, NUCLEAR TECHNOLOGY ......Page 487 CHAPTER VI. EXPERIMENTAL TECHNIQUES ......Page 522 VI.A. ILLUSTRATIONS OF EXPERIMENTAL ASSEMBLIES ......Page 524 VI.B. Additional References and Data Sources......Page 538 CHEMICAL FORMULA INDEX......Page 560