Molecular Recognition and Inclusion : Proceedings of the Ninth International Symposium on Molecular Recognition and Inclusion, Held at Lyon, 7–12 September 1996

This volume contains the Proceedings of the Ninth International Symposium on Molecular Recognition and Inclusion, ISMRI 9 which was held in Lyon, France during 7 to 12 September 1996. The articles reflect the over 50 oral presentations and 140 posters which were presnted at ISMRI 9, both in the range of topics and also in the layout of the volume which comprises five sections, Plenary, Invited, Oral and Emerging Lectures and the four poster sessions. Some words should be said about the Emerging lectures, these were a means of allowing young scientists, often doctoral students to present short 15 minute talks on their work and were one of the great scientific successes ofISMRI 9. I would again like to thank the presenters ofthese lectures for their contributions. The scientific content of ISMRI 9 reflected the logo of the conference showing the symbiotic interactions between Chemistry, Physics and Biology which contribute so strongly to the inter-and pluridisciplinary nature of Supramolecular Science. The topics ranged from Glycobiology through Membrane Systems through Synthetic Organic and Inorganic Chemistry to the construction of Complex Edifices in solution and the Solid-State to arrive at the Physics of Molecular Interactions via the understanding of Water and Gas-Clathrates. Once more to all the speakers who us the breadth of the subjects, thank you. Front Matter....Pages i-xv Biological Importance of Glycosylation....Pages 1-6 Hydration Interactions: Their Role in Recognition and Bioassembly Phenomena....Pages 7-18 Tris(Macrocycles) as Models for Transmembrane, Cation-Conducting Channels....Pages 19-29 Construction of the Interfaces Possessing Both Functionalities of Molecular Recognition and Electron Transfer....Pages 31-38 Electrical Sieves for Molecule Recognition....Pages 39-58 Supramolecular Complexation of Fullerenes and 1,2-Dicarbadodeca-Borane(12)....Pages 59-66 Molecular Switches Based on Molecular Inclusion....Pages 67-75 Fluorescent Cyclodextrins as Chemosensors for Molecular Recognition....Pages 77-84 Tetrathiafulvalenes in Macrocyclic and Supramolecular Chemistry: Self Assembly with Tetrathiafulvalenes....Pages 85-95 Anion Selective Recognition and Sensing by Novel Transition Metal Receptor Systems....Pages 97-102 Macrocyclic Sugar Thioureas: Cyclooligosaccharides Mimicking Cyclopeptides....Pages 103-108 Molecular Clefts Derived from Kagan’s Ether. Synthesis and Solid State Inclusion Complexes of a Chiral Molecular Tweezer....Pages 109-116 Molecular Tectonics: An Approach to Organic Networks....Pages 117-122 New Macrocyclization Reaction Based on Tris(2-Aminoethyl) Amine....Pages 123-128 Signal Transmission by Artificial Receptors Embedded in Bilayer Membranes....Pages 129-134 Inclusion Compounds: Kinetics and Selectivity....Pages 135-152 Kinetics of Intercalation in Lamellar Hosts Using Time-Resolved X-Ray Diffraction....Pages 153-158 Control of Permeation of Ions Across Vesicles and Chemical Differentiation of Their Bilayer Membrane....Pages 159-166 Molecular Recognition and Artificial Ion Channel with Amphiphilic Macrocycles....Pages 167-172 Calix[4]- bis -Crowns: From Nuclear Waste Treatment to Molecular Machines....Pages 173-178 Tripodal Coordination Complexes as Scaffolds for Molecular Recognition and Catalysis....Pages 179-184 Photochromic Molecular Recognition of Cyclodextrins Bearing Spiropyran Moiety for Organic Guests....Pages 185-190 Interactions of Porphyrins with Cyclodextrins. Porphyrins as Probes for Studying Inclusion Phenomena....Pages 191-196 Synthesis and Evaluation of New Ionoselective Materials....Pages 197-202 Concave Reagents and Catalysts: from Lamps to Selectivity....Pages 203-208 Order-Disorder Phenomena in Inclusion Compounds: A Solid State NMR Study....Pages 209-214 One Class of Azocalixarene, Different Types of Assemblies in Solid State....Pages 215-220 The Simple Synthesis of Chiral Diazacoronands Derived from D-Mannitol and L-Tartaric Acid....Pages 221-226 Biomimetic Oxidation of Aromatic Aldehydes Catalyzed by a Bis(Coenzyme)-Cyclophane....Pages 227-232 Some New Calix[4]Arene-Based Complexing Agents....Pages 233-238 Development of Ruthenium Probes Designed to Bind Enantio- and Stereospecifically to DNA....Pages 239-244 Affinity for Both 5-HT 1A - and D 1 -Receptors and Anxiolytic Activity of N-(Arylpiperazinylalkyl) Phthalimides....Pages 245-249 Physico Chemical Studies of the Adsorption Process Between Aminated Silica Wafers and Oligonucleotides.....Pages 251-254 How Can X-Ray Structures Be Helpful for Design of Ionophores for Ion-Selective Membrane Electrodes?....Pages 255-258 The Synthesis and Conformational Analyses of Some Dibenzo[3n+2]Crown-n Ethers....Pages 259-262 Calix[4]Resorcinarene Derivatives as Ionophores for Cations Studied in Polymeric (PVC) Membrane....Pages 263-266 Synthesis of Isoflavone Derivatives of Crown Ethers....Pages 267-269 The Synthesis of Some Coumestan and Related Chromogenic Derivatives of Crown Ethers, Part II....Pages 271-274 The Associaton Constants of Macrocyclic Ether-Cation Interactions in Dioxane / Water mixtures, Part II....Pages 275-278 Binuclear Copper(II) Complexes of Cyclo-Bis Intercaland Receptors. Effect of the Ligand on the Crystal Structure and Complexation Properties....Pages 279-282 Specific Interaction of β-Casomorphin (Human) with Cu(II) Ion....Pages 283-290 The Structure and Properties of the New Ligand for the 5-HT 1A Receptors....Pages 291-295 Phase Transitions of Cyclophosphazene Adducts Directly Followed by Solid State NMR....Pages 297-300 Molecular Recognition in Solid Inclusion Compounds of Novel Roof-Shaped Diol Hosts....Pages 301-304 Success Rate in a Chiral Separation: Towards a Better Separation Machinery....Pages 305-308 NMR Study of Per(3,6-Anhydro) α Cyclodextrin as a Potential Agent for the Biological Decontamination of Lead as Evidenced by NMR Spectroscopy....Pages 309-312 Thioureido β-Cyclodextrins as Molecular Carriers for the Anticancer Drug Taxotère®....Pages 313-316 Continuity and Discontinuity in the Thermodynamic Properties of Solid β-Cyclodextrin Versus Hydration. A Comparative Study....Pages 317-320 Phosphorylated Cavitands: Encapsulation of Hard Cationic Guests....Pages 321-324 The Cation Complexation Properties of Per-3,6-Anhydro-α and β-Cyclodextrins Studied by Thin Layer Chromatography and 1 H NMR....Pages 325-328 Caesium-Selective Imprinted Phenolic Resins....Pages 329-332 Supramolecular Synthesis with Carboxyl-Substituted Secondary Dialkylammonium Salts and Macrocyclic Polyethers....Pages 333-336 Cation Binding of Benzo Crown Ethers in acetonitrile using Fluorescence Spectroscopy, Part II....Pages 337-340 Crystal Engineering with Novel Aminoborates. Hydrogen-Bonded Cyclic Motifs Containing Tetrahedral Boron and Nitrogen....Pages 341-344 Novel Bis(phenoxyalkyl)sulfane Podands — Synthesis and Complex Formation with Thiophilic Metals Ions....Pages 345-348 Design of Coordination Arrays as Potential Molecular Memory Units and Switches....Pages 349-352 Synthesis of a Functionalized Chiral Molecular Tweezer....Pages 353-356 Optimal Polymer Architecture for Adsorption at the Solid-Liquid Interface: Dendrimers Versus Linear Polymers....Pages 357-360 Organizations of Two-Dimensional DNA-Mimetics at the Air-Water Interface....Pages 361-364 Metal-Induced “Aggregation-Deaggregation” and “Colour Change” in Fullerene Derivatives....Pages 365-368 Allosteric Regulation in the Catalytic Activity of Cyclodextrin Dimer as an Artificial Hydrolase....Pages 369-372 Conformational Studies on Anthryl(Alkylamino)-β-Cyclodextrin Complexes and Their Abilities as DNA Intercalators....Pages 373-376 Host-Guest Complexation of Phosphorus Contained Calixarenes with Aromatic Molecules in RP HPLC Conditions. The Stability Constants Determination....Pages 377-380 Synthesis of Cyclodextrins Derivatives Carrying Bio-Recognisable Saccharide Antennae....Pages 381-384 X-Ray and Atomic Force Microscopy Structures of Short Chain Amphiphilic Cyclodextrins....Pages 385-389 Study of Inclusion of Cobalt(II) in Per-6-O-(Ter-Butyl Dimetylsilyl β-CD Using Pyrene as a Fluorescence Probe....Pages 391-394 β-Cyclodextrin Complexes of Polymers Containing Aromatic Groups....Pages 395-398 Inclusion of Neutral Guests in a Self-Assembling Superstructure....Pages 399-402 Recognition and Transport of Nucleoside Monophosphates with Synthetic Receptors....Pages 403-406 Structure and Dynamics of Guest Molecules in Cyclophosphazene Inclusion Compounds....Pages 407-410 Towards Rotaxane-Based Metal-Ion Sensors....Pages 411-414 Microcalorimetric Studies of Ligand-Induced Vancomycin Dimerisation and Molecular Recognition....Pages 415-418 Self-Assembled Hydrogen Bonded Dimers of Calix[4]arenes....Pages 419-422 Crystal Growth of Macrocycles in Gel....Pages 423-426 Chiral Calixarenes Functionalized with Camphorsulfonyl Groups. Synthesis, Structure and Inclusion Properties....Pages 427-430 Synthesis of Water Soluble Resorcinarenes Application in Nanofiltration-Complexation....Pages 431-434 Crystal Engineering in Solid-State Metal Salt Complexes of Cyclodextrins....Pages 435-438 Glycolipid Hydrolase Models D, L-Stereorecognition of Amino Acids ....Pages 439-442 Anthracene Crown Ethers: Synthesis and Complexation of Selected Cations....Pages 443-446 Cyclo Bis-Intercaland Receptors: Structure of Two Intercalative Inclusion Complexes. Stability of the Hydration Network Facing Two Different Substrates....Pages 447-450 Zeolites as Catalysts: Porosity or Acidity? Alkylation of Benzene....Pages 451-454 Quantification of Specific Immunological Reactions by Atomic Force Microscopy....Pages 455-458 Transport Studies of Inorganic and Organic Cations Across Liqued Membranes Containing Mannich-Base Calix[4]Resorcinarenes....Pages 459-462 Chiral Recognition Studies of Amino Acids by Chiral Calix[4]Resorcinarenes in Langmuir Films....Pages 463-466 Preorganized Macrocyclic Dicarboxylic Receptors....Pages 467-470 New endo -Functional Cryptophanes as Selective Complexants....Pages 471-474 In Search of New Tyrosinase Mimetics: Acyclic Polyaminic Ligands of Benzo[g]Phthalazine Able to Form Dinuclear Complexes with Cu(II)....Pages 475-478 Models Systems for Flavoenzyme Activity. Redox-Induced Modulation of Flavin-Receptor Hydrogen Bonding....Pages 479-482 Selectivity in Thermodynamic Cyclisations of Cinchona Alkaloid Derivatives....Pages 483-486 A New Bi-Functional Receptor for Acetylamino- Fluorene Modified Guanosine....Pages 487-490 Macrocyclic Polyethers as Ditopic Co-Receptors for Dual-Centred Secondary Dialkylammonium Guests: from Double-Stranded to Single-Stranded Pseudorotaxanes....Pages 491-494 Synthesis of a 20-Crown-6 from D-Glucose and First Study of its Alkali Metal Cations Affinity by MALDI-FTMS....Pages 495-498 2 H NMR Investigations of the Cyclohexane/Tri- o -Thymotide Inclusion Compound....Pages 499-502 Inclusion Complexes of Siliconhydrofluoric Acid Transformation Products with the Crown Ethers....Pages 503-506 Study of the Interaction of the Host: Guest Type Between SnF 2 : β-Cyclodextrin....Pages 507-510 13 C CP/MAS Studies of Rhodium (II) 3-Fluorobenzoate and their Inclusion Compound in β-Cyclodextrin....Pages 511-514 Anion Recognition Using Boronate-Ureas....Pages 515-518 Synthesis and Self-Organisation of New Cyclodextrin Amphiphile....Pages 519-522 Molecular Recognition of Anionic Species: Hydrogenbonding Properties of Sulfate Andthiocyanate....Pages 523-525 Synthesis and Characterization of Na + and Ba 2+ Complexes With Some Lipophilic Diaza-18-Crown-6 Derivatives....Pages 527-530 The Effect of Macrocycles on the Reaction Rate....Pages 531-534 Stereocontrol and Rate Enhancement of a Diels Alder Reaction Within an Unsymmetrical Porphyrin Host....Pages 535-538 Preorganization of Linear Polyamines in the Solid State....Pages 539-542 Vibrational Spectroscopic Studies on the Inclusional Complexation by β-Cyclodextrin....Pages 543-546 This volume contains the proceedings of ISMRI 9, held in Lyon, France, in 1996. It presents articles on the developing field of molecular interactions, molecular recognition, crystal engineering and structural determination of complex molecular systems. The approaches described are interdisciplinary in nature, reflecting the concept of the ISMRI series of symposia. Audience: This work will be of interest to researchers in chemistry, biology and physics, whose work involves molecular recognition, molecular interactions, supramolecular chemistry and inclusion systems.