Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations (Structure and Bonding, Volume 97)

The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations. Active Iron-oxo And Iron-peroxo Species In Cytochromes P450 And Peroxidases ; Oxo-hydroxo Tautomerism With Water-soluble Metalloporphyrins / B. Meunier, J. Bernadou -- Nucleophilicity Of Iron-peroxo Porphyrin Complexes / D.l. Wertz, J.s. Valentine -- Characterization Of High-valent Oxo-metalloporphyrins / Y. Watanabe, H. Fujii -- Characterization, Orbital Description, And Reactivity Patterns Of Transition-metal Oxo Species In The Gas Phase / D. Schröder, H. Schwarz, S. Shaik -- Quantum Chemical Studies On Metal-oxo Species Related To The Mechanisms Of Methane Monooxygenase And Photosynthetic Oxygen Evolution / P.e.m. Siegbahn, R.h. Crabtree -- Characterization And Properties Of Non-heme Iron Peroxo Complexes / J.-j. Girerd, F. Banse, A.j. Simaan -- Copper-dioxygen And Copper-oxo Species Relevant To Copper Oxygenases And Oxidases / A.g. Blackman, W.b. Tolman -- Rhenium-oxo And Rhenium-peroxo Complexes In Catalytic Oxidations / F.e. Kühn, W.a. Herrmann -- Structure, Reactivity, And Selectivity Of Metal-peroxo Complexes Versus Dioxiranes / W. Adam ... [et Al.] -- Nature Of Activated Bleomycin / R.m. Burger. Volume Editor, B. Meunier; With Contributions By W. Adam ... [et Al.]. Includes Bibliographical References And Index. Cover......Page 1 Structure and Bonding 97......Page 2 Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations......Page 4 ISBN 3-540-66943-4......Page 5 Editors......Page 6 Preface......Page 7 Contents......Page 9 001-035......Page 11 037-060......Page 46 061-089......Page 70 091-123......Page 99 125-144......Page 132 145-177......Page 152 179-211......Page 185 213-236......Page 218 237-285......Page 242 287-303......Page 291 Author Index Volumes 1-97......Page 308