Magnetic Properties · Magnetic Properties of Free Radicals · Nitroxide Radicals. Part 1

Volume II/17d1 is the first part of the fourth subvolume of a supplement to the previous compilations II/1 and II/9a-d on magnetic properties of free radicals, published in 1965 and 1977 - 1980, which covered the literature up to 1975. Due to the continuing rapid development of the field and the inclusion of new subjects, the supplement covering the period 1975 - 1985 had to be split into subvolumes which appear in fast succession. Together with earlier volumes, II/17 offers an up-to-date and comprehensive survey and a collection of data on important chemical intermediates. The series started with subvolume II/17a, which treats inorganic radicals and radical ions as well as radicals in metal complexes. Subvolume II/17b deals with nonconjugated carbon radicals. Subvolume II/17c covers conjugated carbon-centered and nitrogen radicals. Subvolumes II/17e and II/17f, which appeared at the end of 1987, are concerned with radicals centered on heteroatoms with Z > 7 and selected anion radicals. Subvolumes II/17d1 (presented herewith) and II/17d2 (early in 1989) treat nitroxide radicals. General introduction....Pages 1-4 6.1 Introduction....Pages 5-7 6.2.1.1.1 Primary alkyl radicals with a carbonyl substituent....Pages 8-12 6.2.1.1.2 Primary alkyl radicals with an amino substituent....Pages 12-15 6.2.1.1.3 Primary alkyl radicals with neither carbonyl nor amino substituent....Pages 15-21 6.2.1.1.4 Secondary alkyl radicals with a carbonyl and an amino substituent....Pages 21-24 Part 1....Pages 25-34 Part 2....Pages 35-43 Part 1....Pages 44-53 Part 2....Pages 54-62 6.2.1.1.7 Seconary alkyl radicals with neither carbonyl nor amino substituents....Pages 63-67 6.2.1.1.8 Tertiary alkyl radicals with a carbonyl and an amino substituent....Pages 67-71 6.2.1.1.9 Tertiary alkyl radicals with an amino substituent....Pages 71-72 6.2.1.1.10 Tertiary alkyl radicals with neither a carbonyl nor an amino substituent....Pages 72-74 6.2.1.1.11 Aminyl radicals....Pages 74-74 6.2.1.1.12 Thiyl radicals....Pages 75-75 6.2.1.2.1 Prirnary alkyl radicals....Pages 76-80 6.2.1.2.2 Secondary alkyl radicals....Pages 80-93 6.2.1.2.3 Tertiary alkyl radicals....Pages 94-100 6.2.1.2.5 Aminyl, arnidyl and imidyl radicals....Pages 100-103 6.2.1.3 Radicals derived from carbohydrates and their derivatives....Pages 104-110 6.2.1.4 Hydrogen atorns....Pages 110-111 6.2.1.5.1 Primary alkyl radicals with a beta-trigonal carbon substituent....Pages 111-123 6.2.1.5.2 Primary alkyl radicals with a beta-vinyl substituent....Pages 123-124 6.2.1.5.3 Primary alkyl radicals with a beta-aryl substituent....Pages 124-125 6.2.1.5.4 Primary alkyl radicals with a beta-carbonyl substituent....Pages 126-127 6.2.1.5.5 Primary alkyl radicals with a beta-amino substituent....Pages 127-130 6.2.1.5.6 Primary alkyl radicals with a beta-oxy or other substituent....Pages 130-132 6.2.1.6.1 Secondary alkyl radicals with a beta-trigonal carbon substituent....Pages 132-139 6.2.1.6.2 Secondary alkyl radicals with one or more beta-carbonyl substituents....Pages 140-145 6.2.1.6.3 Secondary alkyl radicals with a beta-amino substituent....Pages 145-148 6.2.1.6.4 Secondary alkyl radicals with a beta-oxy substituent....Pages 148-151 6.2.1.6.5 Secondary alkyl radicals with other beta-substituents....Pages 151-153 6.2.1.7 Tertiary alkyl radicals....Pages 154-162 6.2.1.8 Polyhaloalkyl radicals....Pages 162-165 6.2.1.9 Substituted vinyl radicals....Pages 165-168 6.2.1.10 Aryl radicals....Pages 168-175 6.2.1.11 Imidoyl radicals....Pages 175-176 6.2.1.13 Acyl radicals....Pages 177-182 6.2.1.14 Aminyl radicals....Pages 182-183 6.2.1.15 Oxyl radicals....Pages 184-190 6.2.1.16 Thiyl radicals....Pages 190-194 6.2.1.17 Sulfonyl and related radicals....Pages 194-197 6.2.1.18 Boron-centred radicals....Pages 198-200 6.2.1.19 Phosphorus-centred radicals....Pages 200-201 6.2.1.21 Silyl radicals....Pages 201-201 6.2.1.24 Iron-centred radicals....Pages 202-202 6.2.2 Methyl-nitrosobutanone....Pages 203-204 6.2.3 Nitrosotryptycene....Pages 204-206 6.2.4 Trifluoronitrosomethane....Pages 206-212 6.3.1.1 Primary alkyl radicals....Pages 212-216 6.3.1.2 Secondary alkyl radicals....Pages 216-221 6.3.1.3 Tertiary alkyl radicals....Pages 221-223 6.3.1.4 Vinyl radicals....Pages 223-224 6.3.1.5 Aryl radicals....Pages 224-226 6.3.1.6 Imidoyl radicals....Pages 226-227 6.3.1.7 Acyl radicals....Pages 227-228 6.3.1.8 Aminyl and iminyl radicals....Pages 228-230 6.3.1.9 Alkoxyl radicals....Pages 230-231 6.3.1.11 Sulfonyl radicals....Pages 232-233 6.3.2 2,6-Dichloronitrosobenzene....Pages 233-237 6.3.3 2,4,6-Trichloronitrosobenzene....Pages 238-251 6.3.4 2,4,6-Tribromonitrosobenzene....Pages 251-255 6.3.5 2,6-Dibromobenzene-sulfonate....Pages 255-261 6.3.6 2,4,6-Trimethylnitrosobenzene and 2,4,6-trimethylnitrobenzene....Pages 262-268 6.3.7.1 Hydrogen and parent radical ions....Pages 268-269 6.3.7.2 Primary alkyl radicals....Pages 269-283 Part 1....Pages 284-292 Part 2....Pages 293-301 6.3.7.4 Tertiary alkyl radicals....Pages 301-306 6.3.7.5 Polyhaloalkyl radicals....Pages 307-310 6.3.7.6 Aryl radicals....Pages 310-315 6.3.7.7 Acyl radicals....Pages 315-317 6.3.7.8 Aminyl and other N-centred radicals....Pages 317-318 6.3.7.9 Alkoxyl radicals....Pages 318-320 6.3.7.10 Thiyl and sulfonyl radicals....Pages 320-321 6.3.7.11 Other non-metal-centred radicals....Pages 321-322 6.3.7.12 Metal-centred radicals....Pages 323-325 6.3.8 3,5-Di-t-butylnitrosobenzene....Pages 325-327 6.3.9.1 Hydrogen and radical ions....Pages 328-329 6.3.9.2 Primary alkyl radicals....Pages 329-336 6.3.9.3 Secondary alkyl radicals....Pages 337-340 6.3.9.4 Tertiary alkyl and aryl radicals....Pages 341-341 6.3.9.7 Alkoxyl radicals....Pages 342-344 6.3.9.8 Thiyl radicals....Pages 344-344 6.3.9.10 Phosphorus-centred radicals....Pages 345-346 6.3.9.11 Metal-centred radicals....Pages 346-347 6.3.10 Sodium 2,6-di(trideuteromethyl)-4,5-dideuteronitrosobenzene-3-sulfonate....Pages 347-351 6.3.11 Pentafluoronitrosobenzene....Pages 351-352 6.3.12 Pentamethoxynitrosobenzene....Pages 352-356 6.3.13 Pentamethylnitrosobenzene....Pages 356-360 6.3.14 3,5-Diphenyl-1-methyl-4-nitrosopyrazole....Pages 360-363 6.3.15 Sodium (3’,5’-diphenyl-4’-nitrosopyrazol-1’-yl)propane-1-sulfonate....Pages 364-365 6.3.16 Nitrosopyridine 1-oxide....Pages 365-366 6.3.17 Dimethyl-nitrosopyridine 1-oxide....Pages 366-368 6.3.18 Other nitrosoarenes....Pages 368-377 6.3.19 Other nitroarenes....Pages 377-389 References for 6.2 and 6.3....Pages 390-401 General symbols and abbreviations....Pages 402-403