Lanthanides: Chemistry and Use in Organic Synthesis (Topics in Organometallic Chemistry (2))

The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of Topics in Organometallic Chemistry is designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis. Principles In Organolanthanide Chemistry / R. Anwander -- Lanthanide Triflate-catalyzed Carbon-carbon Bond-forming Reactions In Organic Synthesis / S. Kobayashi -- Lanthanide- And Group 3 Metallocene Catalysis In Small Molecule Synthesis / G. Molander, E.c. Dowdy -- Influence Of Solvents Or Additives On The Organic Chemistry Mediated By Diiodosamarium / H. Kagan, J.l. Namy. Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifunctional Catalysts For The Asymmetric Formation Of C-c, C-o And C-p Bonds / M. Shibasaki, H. Gröger -- Reactions Of Ketones With Low-valent Lanthanides: Isolation And Reactivity Of Lanthanide Ketyl And Ketone Dianion Complexes / Z. Hou, Y. Wakatsuki -- Organo Rare Earth Metal Catalysis For The Living Polymerizations Of Polar And Nonpolar Monomers / H. Yasuda -- Polymer-supported Rare Earth Catalysts Used In Organic Synthesis / S. Kobayashi. Volume Editor, S. Kobayashi ; With Contributions By R. Anwander ... [et Al.]. Includes Bibliographical References. preface......Page 1 p1......Page 2 p119......Page 63 p155......Page 99 p199......Page 143 p233......Page 177 p255......Page 198 p285......Page 227 p63......Page 248 The rare earth elements constitute an integral part of modern organic synthesis [1].