Lanthanide and Actinide Chemistry (Inorganic Chemistry: A Textbook Series)

Cotton S. / Коттон С. Henderson W. / Хендерсон У. Komiya S. / Комия С. Lawrence G.A. / Лоренц Дж.А. Muller U. / Мюллер У. Rehder D. / Редер Д. Описание: Список книг: Amouri, H. / Амури, Х. - Chirality in Transition Metal Chemistry. Molecules, Supramolecular Assemblies and Materials (Inorganic Chemistry - A Textbook Series) / Хиральность в химии переходных металлов. Молекулы, супрамолекулярные ансамбли и материалы (Неорганическая химия: серия учебников Wiley) Cotton S. / Коттон С. - Lanthanide and Actinide Chemistry (Inorganic Chemistry - A Textbook Series) / Химия лантаноидов и актиноидов (Неорганическая химия: серия учебников Wiley) Henderson W. / Хендерсон У. - Mass Spectrometry of Inorganic, Coordination and Organometallic Compounds - Tools-Techniques-Tips (Inorganic Chemistry - A Textbook series) / Масс-спектрометрия неорганических, координационных и металлорганических соединений (Неорганическая химия: серия учебников Wiley) Komiya S. / Комия С. - Synthesis of Organometallic Compounds - A Practical Guide (Inorganic Chemistry - A Textbook Series) / Синтез металлорганических соединений (Неорганическая химия: серия учебников Wiley) Lawrence G.A. / Лоренц Дж.А. - Introduction to Coordination Chemistry (Inorganic Chemistry - A Textbook Series) / Введение в координационную химию (Неорганическая химия: серия учебников Wiley) Muller U. / Мюллер У. - Inorganic Structural Chemistry (Inorganic Chemistry - A Textbook Series) / Структурная неорганическая химия (Неорганическая химия: серия учебников Wiley) Rehder D. / Редер Д. - Bioinorganic Vanadium Chemistry (Inorganic Chemistry - A Textbook Series) / Бионеорганическая химия ванадия (Неорганическая химия: серия учебников Wiley) Title Page......Page 2 ISBN 0470010053......Page 6 Contents......Page 10 Preface......Page 16 1.1 Introduction......Page 18 1.3 The Occurrence and Abundance of the Lanthanides......Page 19 1.5.1 Extraction......Page 20 1.5.2 Separating the Lanthanides......Page 21 1.6 The Position of the Lanthanides in the Periodic Table......Page 23 1.7 The Lanthanide Contraction......Page 24 2.1 Electron Configurations of the Lanthanides and f Orbitals......Page 26 2.3 How f Orbitals affect Properties of the Lanthanides......Page 27 2.4 The Lanthanide Contraction......Page 28 2.6 Patterns in Ionization Energies......Page 29 2.8 Patterns in Hydration Energies (Enthalpies) for the Lanthanide Ions......Page 31 2.9.1 Stability of Tetrahalides......Page 32 2.9.2 Stability of Dihalides......Page 34 2.9.3 Stability of Aqua Ions......Page 35 2.10 Patterns in Redox Potentials......Page 36 3.2.1 Properties......Page 40 3.2.2 Synthesis......Page 41 3.3.1 Trihalides......Page 42 3.3.2 Tetrahalides......Page 44 3.3.3 Dihalides......Page 45 3.3.4 Oxides......Page 46 3.7 Hydrides......Page 48 3.8 Sulfides......Page 49 4.2 Stability of Complexes......Page 52 4.3.2 Hydrated Salts......Page 54 4.3.3 Other O-Donors......Page 55 4.3.4 Complexes of B-Diketonates......Page 56 4.3.7 Crown Ether Complexes......Page 58 4.3.8 Complexes of EDTA and Related Ligands......Page 59 4.3.9 Complexes of N-Donors......Page 60 4.3.10 Complexes of Porphyrins and Related Systems......Page 61 4.3.12 Complexes of S-Donors......Page 63 4.4.1 Alkylamides......Page 64 4.4.2 Alkoxides......Page 65 4.5.1 General Principles......Page 67 4.5.2 Examples of the Coordination Numbers......Page 68 4.5.3 The Lanthanide Contraction and Coordination Numbers......Page 70 4.6 The Coordination Chemistry of the +2 and +4 States......Page 71 4.6.1 The ( +2) State......Page 72 4.6.2 The ( +4) State......Page 73 5.1 Magnetic and Spectroscopic Properties of the Ln3+ Ions......Page 78 5.2 Magnetic Properties of the Ln3+ Ions......Page 79 5.2.1 Adiabatic Demagnetization......Page 81 5.3.1 Electronic Spectra......Page 82 5.3.2 Hypersensitive Transitions......Page 85 5.4 Luminescence Spectra......Page 86 5.4.2 Antenna Effects......Page 90 5.4.3 Applications of Luminescence to Sensory Probes......Page 91 5.4.4 Fluorescence and TV......Page 92 5.4.6 Lasers......Page 93 5.5.1 B-Diketonates as NMR Shift Reagents......Page 94 5.5.2 Magnetic Resonance Imaging (MRI)......Page 95 5.5.3 What Makes a Good MRI Agent?......Page 96 5.5.4 Texaphyrins......Page 98 5.6 Electron Paramagnetic Resonance Spectroscopy......Page 99 5.7 Lanthanides as Probes in Biological Systems......Page 100 6.2.1 Alkyls......Page 106 6.2.2 Aryls......Page 107 6.3.1 Compounds of the Unsubstituted Cyclopentadienyl Ligand (C5H5 =Cp; C5Me5 =Cp*)......Page 108 6.3.2 Compounds [LnCp*3] (Cp* =Pentamethylcyclopentadienyl)......Page 111 6.3.3 Bis(cyclopentadienyl) Alkyls and Aryls LnCp2R......Page 112 6.3.4 Bis(pentamethylcyclopentadienyl) Alkyls......Page 113 6.4 Cyclooctatetraene Dianion Complexes......Page 115 6.5.1 Alkyls and Aryls......Page 116 6.5.3 Other Compounds......Page 117 6.7 Metal–Arene Complexes......Page 118 6.8 Carbonyls......Page 119 7.2 Scandium......Page 124 7.3.1 The Aqua Ion and Hydrated Salts......Page 125 7.3.2 Other Complexes......Page 126 7.3.3 Alkoxides and Alkylamides......Page 128 7.3.4 Patterns in Coordination Number......Page 129 7.5 Yttrium......Page 131 7.6 Promethium......Page 132 8.2.1 Oxidation of Aromatics......Page 138 8.2.3 Oxidation of Alcohols......Page 140 8.3.3 Reductions of Carbonyl Groups......Page 141 8.3.4 Barbier Reactions......Page 143 8.4 Lanthanide B-Diketonates as Diels–Alder Catalysts......Page 144 8.5 Cerium(III) Chloride and Organocerium Compounds......Page 145 8.6 Cerium(III) Chloride and Metal Hydrides......Page 147 8.7.1 Friedel–Crafts Reactions......Page 148 8.7.3 Mannich Reactions......Page 149 8.7.4 Imino-Diels–Alder Reactions......Page 150 8.8 Alkoxides and Aryloxides......Page 151 8.9 Lanthanide Metals......Page 152 8.10 Organometallics and Catalysis......Page 153 9.2 Synthesis......Page 162 9.3.1 Extraction of Thorium......Page 164 9.4.2 Gas Centrifuge......Page 165 9.5 Characteristics of the Actinides......Page 166 9.6 Reduction Potentials of the Actinides......Page 167 9.7 Relativistic Effects......Page 169 10.2 Halides......Page 172 10.2.1 Syntheses......Page 173 10.2.2 Structure Types......Page 175 10.3 Thorium Halides......Page 176 10.4 Uranium Halides......Page 177 10.4.3 Uranium (IV) Compounds......Page 178 10.4.5 Uranium Hexafluoride and Isotope Separation......Page 180 10.5.2 Protactinium......Page 182 10.5.4 Plutonium......Page 183 10.5.5 Americium......Page 184 10.6.3 Einsteinium(III) Chloride......Page 185 10.7.2 Uranium Oxides......Page 186 10.9 Oxyhalides......Page 187 11.2 General Patterns in the Coordination Chemistry of the Actinides......Page 190 11.4 Types of Complex Formed......Page 191 11.5.1 Uranyl Complexes......Page 192 11.5.2 Coordination Numbers and Geometries in Uranyl Complexes......Page 194 11.5.3 Some Other Complexes......Page 195 11.5.5 Nuclear Waste Processing......Page 196 11.6.2 Uranium(IV) Nitrate Complexes......Page 197 11.6.3 Complexes of the Actinide(IV) Halides......Page 198 11.7 Thiocyanates......Page 200 11.8.1 Amide Chemistry......Page 201 11.8.2 Alkoxides and Aryloxides......Page 202 11.9 Chemistry of Actinium......Page 203 11.10 Chemistry of Protactinium......Page 204 11.11.1 Complexes of Neptunium......Page 205 11.12.1 Aqueous Chemistry......Page 206 11.12.2 The Stability of the Oxidation States of Plutonium......Page 207 11.12.3 Coordination Chemistry of Plutonium......Page 208 11.12.4 Plutonium in the Environment......Page 210 11.13.1 Potentials......Page 212 11.14 Chemistry of the Later Actinides......Page 213 12.1 Introduction......Page 218 12.2.1 Uranium(VI)–UO2 2 +–f 0......Page 219 12.2.2 Uranium(V)–f 1......Page 220 12.2.3 Uranium(IV)–f 2......Page 221 12.2.4 Spectra of the Later Actinides......Page 223 12.3 Magnetic Properties......Page 224 13.2 Simple 0-Bonded Organometallics......Page 226 13.3.3 Oxidation State (IV)......Page 228 13.3.4 Oxidation State (III)......Page 231 13.4.1 Oxidation State(IV)......Page 232 13.4.2 Cationic Species and Catalysts......Page 233 13.4.3 Hydrides......Page 234 13.4.4 Oxidation State (III)......Page 235 13.7 Cyclooctatetraene Dianion Compounds......Page 236 13.8 Arene Complexes......Page 238 13.9 Carbonyls......Page 239 14.1 Introduction......Page 242 14.3 Synthesis of the Transactinides......Page 243 14.4 Naming the Transactinides......Page 246 14.6 Identifying the Elements......Page 247 14.7 Predicting Chemistry of the Transactinides......Page 250 14.8.3 Element 106......Page 251 14.8.5 Element 108......Page 252 14.9 And the Future?......Page 253 Bibliography......Page 254 Index......Page 270 The only introduction into the exciting chemistry of Lanthanides and Actinides. The book is based on a number of courses on "f elements" The author has a long experience in teaching this field of chemistry Lanthanides have become very common elements in research and technology applications; this book offers the basic knowledge The book offers insights into a vast range of applications, from lasers to synthesis The Inorganic Chemistry: A Textbook series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry. Lanthanide and Actinide Chemistry is a one-volume account of the Lanthanides (including scandium and yttrium), the Actinides and the Transactinide elements, intended as an introductory treatment for undergraduate and postgraduate students. The principal features of these elements are set out in detail, enabling clear comparison and contrast with the Transition Elements and Main Group metals. The book covers the extraction of the elements from their ores and their purification, as well as the synthesis of the man-made elements; the properties of the elements and principal binary compounds; detailed accounts of their coordination chemistry and organometallic chemistry, from both preparative and structural viewpoints, with a clear explanation of the factors responsible for the adoption of particular coordination numbers; spectroscopy and magnetism, especially for the lanthanides, with case studies and accounts of applications in areas like magnetic resonance imaging, lasers and luminescence; nuclear separations and problems in waste disposal for the radioactive elements, particularly in the context of plutonium. Latest developments are covered in areas like the synthesis of the latest man-made elements, whilst there is a whole chapter on the application of lanthanide compounds in synthetic organic chemistry. End-of-chapter questions suitable for tutorial discussions are provided, whilst there is a very comprehensive bibliography providing ready access to further reading on all topics. This Series Reflects The Pivotal Role Of Modern Inorganic And Physical Chemistry In A Range Of Emerging Areas And In This Text, The Main Features Of The Lanthanides, Actinides And The Transactinide Elements Are Described, Enabling Clear Comparison And Contrast With The Transition Elements And Main Group Metals. 1. Introduction To The Lanthanides -- 2. The Lanthanides -- Principles And Energetics -- 3. The Lanthanide Elements And Simple Binary Compounds -- 4. Coordination Chemistry Of The Lanthanides -- 5. Electronic And Magnetic Properties Of The Lanthanides -- 6. Organometallic Chemistry Of The Lanthanides -- 7. The Misfits : Scandium, Yttrium, And Promethium -- 8. The Lanthanides And Scandium In Organic Chemistry -- 9. Introduction To The Actinides -- 10. Binary Compounds Of The Actinides -- 11. Coordination Chemistry Of The Actinides -- 12. Electronic And Magnetic Properties Of The Actinides -- 13. Organometallic Chemistry Of The Actinides -- 14. Synthesis Of The Transactinides And Their Chemistry. Simon Cotton. Errata Slip Inserted. Includes Bibliographical References (p. [237]-251) And Index.