Landolt-Börnstein numerical data and functional relationships in science and technology. Group 2, Atomic and molecular physics. Vol. 13, Radical reaction rates in liquids. Subvolume c, Radicals centered on N, S, P and other heteroatoms ; Nitroxyls

Reaction Radical generation Ref./ Method Solvent TCKI Rate data add. ref. 5.1 Aminyl radicals, RR'N -5.1.1 Bimolecular self-reactions and radicaldimer equilibria 5.1.1.1 Monoalkylaminyls (R=alkyl, R'=H) 2(CH,),CNH + products ns-phot. of benzophenone IlInbl/ KAS C6H6 RT 2k,=2.107M-'s-l ') 79Gril 5.1.1.2 Acyclic dialkylaminyls (R, R'=alkyl) 2(CH,),N ---) products Phot. of (CH,),COOC(CH,), with the aminodiethylphosphine 73Robl KESR i-C,H,, 193 2k,=2(1)+109M-'s-l 2 (C,H,),fi + products Phot. of (C,H,),NN = NN(C,H,), 71Robl/ KESR n-V4 2 183 2k,=7(3).109M-'s-l 73Robl Phot. of (CH,),COOC(CH,), with theaminodiethylphosphine 73Robl KESR n-w, 2 183 2k,=1.0(5).109M-'s-l 2 [(CH,),CH],h --f [(CHJ,CH],NH + (CH,),CHN = C(CH,), Phot. of trans-[(CH,),CH],NN=NN[CH(CH,),], 71Robl/ KESR n-C?1 2 5.1 Aminyl radicals [Ref. p. 160 General introduction....Pages 1-4 5.0 Introduction....Pages 5-6 5.1.1 Bimolecular self-reactions and radical-dimer equilibria....Pages 6-14 5.1.2 Reactions with a different radical....Pages 14-14 5.1.3 Unimolecular reactions....Pages 15-19 5.1.4 Intermolecular hydrogen atom abstractions from carbon....Pages 20-25 5.1.5 Intermolecular hydrogen atom abstractions from oxygen....Pages 25-28 5.1.7 Intermolecular hydrogen atom abstractions from sulfur....Pages 28-29 5.1.8 Intermolecular reactions other than hydrogen atom abstraction....Pages 29-36 5.2.1 Bimolecular self-reactions and radical-dimer equilibria....Pages 36-44 5.2.3 Unimolecular reactions....Pages 45-51 5.2.4.1 Aminium....Pages 52-53 5.2.4.2 Monoalkylaminiums....Pages 53-53 5.2.4.3 Acyclic dialkylaminiums....Pages 54-67 5.2.4.4 Secondary cyclic aminiums....Pages 67-72 5.2.4.5 Acyclic trialkylaminiums....Pages 72-73 5.2.4.6 Tertiary cyclic aminiums....Pages 73-74 5.2.5 Intermolecular reactions other than hydrogen atom abstraction....Pages 74-79 5.3 Carboxamidyl radicals, R’CONR....Pages 79-89 5.4 Sulfinamidyl radicals, RR’SON, and sulfonamidyl radicals, RR’SO{2}N....Pages 89-92 5.5 Imidyl radicals, RCOR’CON....Pages 93-98 5.6 Iminyl radicals, RR’C=N....Pages 98-101 5.7 Alkoxyaminyl radicals, RR’ON....Pages 102-104 5.8 Thioaminyl radicals, RR’SN....Pages 104-108 5.9 Dithioaminyl radicals, RSR’SN....Pages 108-109 5.10.1 Bimolecular self-reactions and radical-dimer equilibria....Pages 110-119 5.10.2 Reactions with a different radical....Pages 120-120 5.10.3 Unimolecular reactions....Pages 121-122 5.10.5 Intermolecular hydrogen atom abstractions by DPPH from amines....Pages 123-126 Part 1....Pages 126-133 Part 2....Pages 134-142 5.10.7 Intermolecular hydrogen atom abstractions by DPPH from thiols....Pages 142-145 5.10.8 Intermolecular hydrogen atom abstractions by DPPH from ethers....Pages 145-145 5.10.9 Intermolecular hydrogen atom abstractions by DPPH from acids, alcohols, anhydrides and other compounds....Pages 146-146 5.11 Hydrazyl radical cations, (R’R”NNR{2}){+}, and related species....Pages 147-150 5.12 Verdazyl and related radicals....Pages 151-154 5.13 Diazirinyl radicals....Pages 154-154 5.14 Diazenyl radicals, RN=N....Pages 155-156 5.15 Azidyl radical, N{3}....Pages 156-157 5.16 Triazenyl radicals, R{2}N{3} and diazaallyl radicals, (RN){2}CR’; bimolecular self-reactions....Pages 157-158 5.17 Benzolnitrile radical anions, ArCM{-}; unimolecular reactions....Pages 158-159 References for 5.1 - 5.17....Pages 160-165 6.0 Introduction....Pages 166-166 6.1.1 Bimolecular self-reactions and radical-dimer equilibria....Pages 167-181 6.1.2.1 Acyclic dialkylaminoxyls....Pages 181-182 6.1.2.2 Cyclic aminoxyls....Pages 182-199 6.1.2.3 Acyclic alkarylaminoxyls, with carbon-centered radicals....Pages 199-199 6.1.2.4 Acyclic diarylaminoxyls....Pages 200-200 6.1.3 Unimolecular reactions....Pages 201-215 6.1.4 Intermolecular hydrogen atom abstractions from carbon....Pages 216-222 6.1.5 Intermolecular hydrogen atom abstractions from oxygen....Pages 222-227 6.1.6 Intermolecular hydrogen atom abstractions from nitrogen; cyclic aminoxyls....Pages 228-230 6.1.7.1 Acyclic dialkylaminoxyls....Pages 231-236 6.1.7.2 Cyclic aminoxyls....Pages 236-246 6.1.7.3 Aminoxyl biradicals....Pages 246-248 6.1.8 Other intermolecular reactions....Pages 249-256 6.2 Iminoxyl radicals, RR’C=NO....Pages 257-265 6.3 Aminothiyl radicals, RRNS, iminothiyl radicals, RR’C=NS, and related species....Pages 265-267 References for 6.1 - 6.3....Pages 267-270 7.0 Introduction....Pages 271-272 7.2 Silicon-centered radicals....Pages 272-287 7.3.1 Absolute rate constants....Pages 287-304 7.3.2 Relative rate constants, fragmentation or rearrangement....Pages 304-307 7.4 Sulfur-centered radicals....Pages 308-321 7.5 Germanium-centered radicals....Pages 321-322 7.6 Arsenic-centered radicals....Pages 322-322 7.7 Tin-centered radicals....Pages 323-337 7.8 Mercury-centered radicals....Pages 337-337 References for 7.1 - 7.8....Pages 338-339