Interfaces in new materials : proceedings of the Workshop Interfaces in New Materials held in Louvain-la-Neuve, Belgium, 19-20 November, 1990, organised by the Institut Interfacultaire des Sciences Naturelles Appliquées and the Centre de Recherche des Ma

Thisbookreportstheproceedingsoftheworkshop Interfaces in New Materials organisedbytheMaterialsDivisionoftheInstitutInterfacultairedeSciencesNaturelles AppliqueesandtheCenterforAdvancedMaterialsoftheUniversiteCatholiquede Louvain,heldinNovember1990. Theobjectiveofthisworkshopwastobringtogetherscientistsfromdifferenthorizons whoseareasofresearcharethestudyandthecharacterisationofinterfaces. Three maintopicswereselected:thephysico-chemicalcharacterisation,theroleandthe modificationofinterfaces. Twoinvitedgenerallectures(Prof. M. vandeVoordefromtheJointResearchCentre, Petten,TheNetherlandsandDr. M. CourbierefromtheCentredeRecherchesde Voreppe,France)andtwenty-fourcommunicationsarereportedintheseproceedings. P. GRANGE B. DELMON VII Contents Preface v Understandinginterfaces. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 B. DELMON Developmentsinhightemperaturematerialsjoining. . . . . . . . . . . . . . . . . . . . . . . . . 12 M. VANDEVOORDE &M. G. NICHOLAS Metal-ceramicjoining,animportantkeytoceramicmaterialsdevelopment. . . . . . . . . 29 M. COURBlERE HightemperaturedeformationofAl203/Zr02matrixceramiccomposites: interfacecontrolledcreep 42 R. DUCLOS, R. MARTINEZ &1. CRAMPON FormationofLaA10thickfilmonAl0substrates. . . . . . . . . . . . . . . . . . . . . . . . . 52 3 Z 3 O. STRYCKMANS &P. R. DUVIGNEAUD Interphaseregionincompositesystems:analysis,characterisation andinfluenceonlongtermbehaviour. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 A. H. CARDON,W. P. DEWILDE,M. VERHEYDEN, D. VANHEMELRIJCK,L. SCHll. LEMANS &F. BOULPAEP Wettabilityofaglazeonaceramicsubstrateathightemperature applicationtotheglazingoftheporcelainofLimoges. . . . . . . . . . . . . . . . . . . . . . . 68 J. C. LABBE &V. PAULYOU Chemicalsensorsusinghetero-contactofceramics 76 M. MIYAYAMA,Y. NAKAMURA,H. YANAGIDA & K. KOUMOTO Surfacestudyofnewmicroporouspolymericmembranesusedas asubstratumforanimalcellculture. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 1. L. DEWEZ, A. DOREN,Y. -J. SCHNEIDER, R. LEGRAS &P. G. ROUXHET Influenceofcarbonfibresurfacecharacteristicsonthemicromechanical behaviourofthecarbon-epoxyinterface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95 M. DESAEGER &I. VERPOEST viii Colloidcoatingsandmaterials. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 P. G. ROUXHET Polycarbonate/polybutyleneterephthalateblends. Controlofthe phasediagrarnme. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 R. LEGRAS,J. DEVAUX&D. DELIMOY Ultrastructuralaspectsoffibre-matrixbondincellulosecementcomposites 129 B. DELHONEUX,E. BAES&T. AVELLA Roleoftheinterphases intherubberlbrassadhesion. . . . . . . . . . . . . . . . . . . . . . . . 139 F. DELAMARE & R. COMBARIEU Useofionicspectrometriesforthestudyofthemetal/polymerinterface 149 Y. DEPUYDT,P. PHUKU &P. BERTRAND Modificationofthestructureandtextureofinterfacesinthepreparation ofcatalystsandduringcatalysis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 T. MACHEJ,M. REMY,P. RUIZ &B. DELMON Pre-oxidizedcopperandaluminabonding. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 C. ESNOUF &D. TREHEUX Microscopicapproachofthemetalinsulatoradhesion 180 G. BORDIER &C. NOGUERA Diffusionbondingbetweeninconel600andalumina 190 B. TANGHE,O. EVRARD,J. P. MEYNCKENS& F. DELANNAY Electronmicroscopyofinterfacesinnewmaterials 200 G. VANTENDELOO,C. GOESSENS,D. SCHRYVERS, J. VANHAVENBERGH,A. DEVEIRMAN &J. VANLANDUYT Wettabilityandadhesionofmetallicliquidsonceramicsinnon-reactive andreactivesystems 210 D. CHATAIN,L. COUDURIER,A. STEINCHEN & N. EUSTATHOPOULOS Wettabilityofrealsurfacesinliquidmetal/monocrystallinealumina andcontactanglehysteresis 219 V. DEJONGHE &D. CHATAIN Interfacialreactionduringactivebrazingprocessonmetal-ceramic (SiC)joints " 229 B. BATFALSKY IX Interfacephenomena,morphologyandmicrostructureofthermallysprayed metalandceramiccomposites. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 239 H. -D. STEFFENS&J. DROZA CharacterizationofausteniticstainlesssteelAISI304surfacesby meansofglancingangleX-raydiffraction 253 C. QUAEYHAEGENS,L. M. STALS &M. VANSTAPPEN TheinterfacebetweenTiNcoatingsandAISI304steelsubstrates fordifferentdepositionconditions:Atransmissionelectron microscopystudy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 262 J. D'HAEN,L. DESCHEPPER,M. VANSTAPPEN &L. M. STALS ConcludingremarksontheworkshopInterfacesinNewMaterials. . . . . . . . . . . . . Front Matter....Pages i-ix Understanding Interfaces....Pages 1-11 Developements in High Temperature Materials Joining....Pages 12-28 Metal-Ceramic Joining, an Important Key to Ceramic Materials Development....Pages 29-41 High Temperature Deformation of Al2O3/ZrO2 Matrix Ceramic Composites: Interface Controlled Creep....Pages 42-51 Formation of LaAlO 3 thick film on Al 2 O 3 substrates....Pages 52-61 Interphase Region in Composite Systems: Analysis, Characterisation and Influence on Long Term Behaviour....Pages 62-67 Wettability of a Glaze on a Ceramic Substrate at High Temperature Application to the Glazing of the Porcelain of Limoges....Pages 68-75 Chemical Sensors Using Hetero-Contact of Ceramics....Pages 76-83 Surface Study of New Microporous Polymeric Membranes Used as a Substratum for Animal Cell Culture....Pages 84-94 Influence of carbon fibre surface characteristics on the micromechanical behaviour of the carbon-epoxy interface....Pages 95-106 Colloid Coatings and Materials....Pages 107-119 Polycarbonate/Polybutylene Terephthalate Blends. Control of the Phase Diagramme.....Pages 120-128 Ultrastructural Aspects of Fibre—Matrix Bond in Cellulose Cement Composites....Pages 129-138 Role of the Interphases in the Rubber/Brass Adhesion....Pages 139-148 Use of Ionic Spectrometries for the Study of the Metal/Polymer Interface....Pages 149-159 Modification of the Structure and Texture of Interfaces in the Preparation of Catalysts and During Catalysis....Pages 160-169 Pre-Oxidized Copper and Alumina Bonding....Pages 170-179 Microscopic Approach of the Metal Insulator Adhesion....Pages 180-189 Diffusion Bonding Between Inconel 600 and Alumina....Pages 190-199 Electron Microscopy of Interfaces in New Materials....Pages 200-209 Wettability and Adhesion of Metallic Liquids on Ceramics in Non-Reactive and Reactive Systems....Pages 210-218 Wettability of Real Surfaces in Liquid Metal/Monocrystalline Alumina and Contact Angle Hysteresis....Pages 219-228 Interfacial Reaction During Active Brazing Process on Metal-Ceramic (SiC) Joints....Pages 229-238 Interface Phenomena, Morphology and Microstructure of Thermally Sprayed Metal and Ceramic Composites....Pages 239-252 Characterization of Austenitic Stainless Steel AISI 304 Surfaces by Means of Glancing Angle X-Ray Diffraction....Pages 253-261 The Interface Between TiN Coatings and AISI 304 Steel Substrates for Different Deposition Conditions: A Transmission Electron Microscopy Study....Pages 262-269 Concluding Remarks on the Workshop Interfaces in New Materials....Pages 270-272 Back Matter....Pages 273-283