Inorganic Reactions and Methods, The Formation of Bonds to C, Si, Ge, Sn, Pb (Part 1) (Volume 9)

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.Content: Chapter 5.2.1 Introduction (pages 1–4): E. Hengge Chapter 5.2.3.1.2 By Other Methods (page 4): E. Hengge Chapter 5.2.3.1.3 Formation of High?Purity Silicon (pages 4–6): E. Hengge Chapter 5.2.3.1.4 Electrochemical Formation of Compounds with Si?Si Bonds (Including Elemental Silicon) (pages 6–7): E. Hengge Chapter 5.2.3.2 From Metal Silicides (pages 7–8): E. Hengge Chapter 5.2.3.2.2 Formation of Oligosilanes (pages 8–9): E. Hengge Chapter 5.2.3.2.3 Formation of Polymeric Compounds (pages 9–10): E. Hengge Chapter 5.2.3.3 From Silicon Hydrides and Organosilicon Hydrides (page 11): M. A. Ring Chapter 5.2.3.3.2 By Direct Photolysis (pages 11–13): M. A. Ring Chapter 5.2.3.3.3 By Sensitized Photolysis (pages 13–15): M. A. Ring Chapter 5.2.3.3.4 By Catalyzed Reactions (pages 15–16): M. A. Ring Chapter 5.2.3.3.5 By Reaction with Silylmetallic Compounds (page 17): M. A. Ring Chapter 5.2.3.4 From Silicon Halides and Organosilicon Halides (pages 17–18): M. A. Ring Chapter 5.2.3.4.2 By Halide Elimination with Active Metals (pages 18–20): M. A. Ring Chapter 5.2.3.4.3 By Reaction with Silylmetallics (pages 20–22): M. A. Ring Chapter 5.2.3.4.4 By Catalyzed Disproportionation (pages 22–23): M. A. Ring Chapter 5.2.3.4.5 By Reaction with Organomagnesium Halide Reagents (pages 23–24): M. A. Ring Chapter 5.2.3.4.6 By the Action of Silent Electric Discharge (page 24): M. A. Ring Chapter 5.2.3.4.7 By Mercury?Photosensitized Photolyses (pages 24–25): M. A. Ring Chapter 5.2.3.5 From Bissilylmercury Compounds (pages 25–26): M. A. Ring Chapter 5.2.3.5.2 By Photolysis (page 26): M. A. Ring Chapter 5.2.3.6 From Organosilanes and Silicon Halides by Hydrogenolysis (pages 26–27): M. A. Ring Chapter 5.2.3.7 From Silylenes (pages 28–29): M. A. Ring Chapter 5.2.3.7.2 By Insertions into Bonds of Silicon to Hydrogen, Oxygen and Silicon (pages 29–33): M. A. Ring Chapter 5.2.3.7.3 By Addition to SI=C (page 33): M. A. Ring Chapter 5.2.3.8 In the Direct Reaction of Methyl Chloride with Silicon?Copper (pages 33–34): M. A. Ring Chapter 5.2.4 Formation of the Germanium?Germanium Bond (pages 34–39): J. Satge and P. Riviere Chapter 5.2.4.1.2 From Sulfides (page 39): J. Satge and P. Riviere Chapter 5.2.4.1.3 By Other Syntheses (pages 39–43): J. Satge and P. Riviere Chapter 5.2.4.1.4 Formation of High?Purity Germanium (pages 43–45): J. Satge and P. Riviere Chapter 5.2.4.2 From Organogermanium Hydrides (pages 45–46): J. Satge and P. Riviere Chapter 5.2.4.2.2 By Hydrogermolysis Reaction (pages 46–48): J. Satge and P. Riviere Chapter 5.2.4.2.3 By Germanium Hydride Decomposition (page 48): J. Satge and P. Riviere Chapter 5.2.4.3 From Ge(IV) Halides and Organogermanium(IV) Halides (page 49): J. Satge and P. Riviere Chapter 5.2.4.3.2 By Electrochemical Reduction (pages 49–51): J. Satge and P. Riviere Chapter 5.2.4.3.3 By Halide Elimination with Active Metals (pages 52–55): J. Satge and P. Riviere Chapter 5.2.4.3.4 By Reaction with Germyl?Metal Reagents (pages 55–59): J. Satge and P. Riviere Chapter 5.2.4.3.5 By Reaction with Organometallic Reagents (pages 59–61): J. Satge and P. Riviere Chapter 5.2.4.4 From Germanium(II) Halides (pages 61–62): J. Satge and P. Riviere Chapter 5.2.4.4.2 By Reaction with Organometallic Reagents (pages 62–64): J. Satge and P. Riviere Chapter 5.2.4.5 From Germyl Compounds of Cadmium, Mercury, Thallium, Antimony and Bismuth (pages 64–66): J. Satge and P. Riviere Chapter 5.2.4.6 From Germylenes (pages 66–68): J. Satge and P. Riviere Chapter 5.2.4.6.2 By Insertions into Bonds of Germanium to Hydrogen, Halogen, Carbon, Oxygen, Sulfur, Nitrogen, Phosphorus and Germanium (pages 68–73): J. Satge and P. Riviere Chapter 5.2.5 The Formation of the Tin–Tin Bond (pages 73–75): B. Mathiasch Chapter 5.2.5.1.2 From Sulfides (page 75): B. Mathiasch Chapter 5.2.5.1.3 By Other Syntheses (pages 75–76): B. Mathiasch Chapter 5.2.5.1.4 Allotropy of Tin (pages 76–77): B. Mathiasch Chapter 5.2.5.2 From Organotin Hydrides (pages 77–79): B. Mathiasch Chapter 5.2.5.2.2 By Reaction with Organotin Halogen, Pseudohalogen, Chalcogen and Pnictogen Compounds (pages 79–82): B. Mathiasch Chapter 5.2.5.2.3 By Reaction with Organometallic Compounds (pages 82–83): B. Mathiasch Chapter 5.2.5.2.4 By Reaction with Reducible Organic Compounds (pages 83–84): B. Mathiasch Chapter 5.2.5.3 From Organotin Halides (pages 84–85): B. Mathiasch Chapter 5.2.5.3.2 By Halide Elimination with Active Metals (pages 85–86): B. Mathiasch Chapter 5.2.5.3.3 By Reaction with Stannyl Metal Reagents (pages 86–88): B. Mathiasch Chapter 5.2.5.3.4 By Reactions with Bulky Organometallic Reagents (pages 88–89): B. Mathiasch Chapter 5.2.5.4 From Tin(II) Halides by Reaction with Organometallic Reagents (pages 89–90): B. Mathiasch Chapter 5.2.5.5 From Bis(Stannyl) Compounds of Mercury (pages 90–92): B. Mathiasch Chapter 5.2.5.6 From Stannylenes (pages 93–94): B. Mathiasch Chapter 5.2.5.6.2 By Insertions into Bonds of Tin to Hydrogen, Carbon and Tin (pages 94–95): B. Mathiasch Chapter 5.2.5.7 From Sodium?Tin Alloys by Reaction with Organic and Organometallic Compounds (pages 95–96): B. Mathiasch Chapter 5.2.6 Formation of the Lead?Lead Bond (page 96): M. Drager and N. Kleiner Chapter 5.2.6.1 In Metallic Lead (pages 96–97): M. Drager and N. Kleiner Chapter 5.2.6.1.1 From Oxides (page 97): M. Drager and N. Kleiner Chapter 5.2.6.1.2 From Sulfides (pages 97–98): M. Drager and N. Kleiner Chapter 5.2.6.1.3 By Other Syntheses (pages 98–99): M. Drager and N. Kleiner Chapter 5.2.6.2 From Lead (II) and Lead(IV) Salts by Reaction with Organometallic Reagents (pages 99–101): M. Drager and N. Kleiner Chapter 5.2.6.3 From Organolead Hydrides (page 101): M. Drager and N. Kleiner Chapter 5.2.6.4 From Organolead Halides (pages 101–102): M. Drager and N. Kleiner Chapter 5.2.6.4.2 By Reaction with Plumbyl ? Metal Reagents (page 102): M. Drager and N. Kleiner Chapter 5.2.6.5 From Organolead Hydroxides by Electrolysis (pages 102–103): M. Drager and N. Kleiner Chapter 5.2.6.6 From Lead Alloys (page 103): M. Drager and N. Kleiner Chapter 5.2.6.6.2 By Reaction with Cryptate Reagents (page 103): M. Drager and N. Kleiner Chapter 5.2.6.7 By Other Syntheses (page 104): M. Drager and N. Kleiner Chapter 5.2.6.7.2 By Reductive Processes (pages 104–105): M. Drager and N. Kleiner Chapter 5.2.7 The Formation of the Carbon?Silicon Bond (pages 105–110): B. Kanner Chapter 5.2.7.2.2 By Reaction with Aryl Halides (pages 110–112): B. Kanner Chapter 5.2.7.2.3 By Reaction with Other Species (pages 112–113): B. Kanner Chapter 5.2.7.3 From Silicon Halides (pages 113–138): P. P. Gaspar Chapter 5.2.7.3.2 By Interaction with Organic Halides with Active Metals (pages 138–143): P. P. Gaspar Chapter 5.2.7.3.3 By Interaction with Unsaturated Organic Derivatives and Active Metals (pages 143–159): P. P. Gaspar Chapter 5.2.7.3.4 By Redistribution Reactions with Organosilanes (pages 159–161): P. P. Gaspar Chapter 5.2.7.3.5 By Reaction with Hydrocarbons (page 161): P. P. Gaspar Chapter 5.2.7.3.6 By Reaction with Diazoalkanes (pages 162–163): P. P. Gaspar Chapter 5.2.7.4 From Silicon Alkoxides, Silicon Carboxylates or Siloxanes (pages 163–170): P. P. Gaspar Chapter 5.2.7.4.2 By Interaction with Organic Halides and Active Metals (pages 170–173): P. P. Gaspar Chapter 5.2.7.4.3 By Interaction with Unsaturated Organic Compounds (pages 173–176): P. P. Gaspar Chapter 5.2.7.5 From Silicon Hydrides (pages 176–180): M. A. Ring Chapter 5.2.7.5.2 By Reaction with Diazoalkanes or Other Carbenoids (pages 180–182): M. A. Ring Chapter 5.2.7.5.3 By Reaction with Active Organometallics to Eliminate MH (pages 182–185): M. A. Ring Chapter 5.2.7.5.4 From the Pyrolysis of Organohydrosilanes (page 185): M. A. Ring Chapter 5.2.7.6 From Silylmetallics (pages 185–186): F. K. Cartledge and R. V. Piccione Chapter 5.2.7.6.1 By Reaction with Organic Halides to Eliminate MX (pages 186–195): F. K. Cartledge and R. V. Piccione Chapter 5.2.7.6.2 By Cleavage of Certain Ethers and Epoxides (pages 195–198): F. K. Cartledge and R. V. Piccione Chapter 5.2.7.6.3 By Addition to Carbonyl Groups of CO2 and Other Acyl Derivatives (pages 198–202): F. K. Cartledge and R. V. Piccione Chapter 5.2.7.6.4 By Addition to C—C Unsaturated Systems (pages 202–207): F. K. Cartledge and R. V. Piccione Chapter 5.2.7.7 From Other Organosilanes by Exchange with Active Organometallics (pages 207–212): F. K. Cartledge and R. V. Piccione Chapter 5.2.8 Formation of the Carbon?Germanium Bond (pages 212–215): B. Kanner Chapter 5.2.8.2.2 By Reaction with Aryl Halides (pages 215–216): B. Kanner Chapter 5.2.8.3 From Germanium Halides (DI? and Tetravalent) (page 216): J. Satge and P. Riviere Chapter 5.2.8.3.1 By Reaction with Active Organometallics (pages 217–224): J. Satge and P. Riviere Chapter 5.2.8.3.2 By Interaction with Organic Halides and Active Metals (pages 224–227): J. Satge and P. Riviere Chapter 5.2.8.3.3 By Addition of Organic Halide to Germanium (II) Halides and Organohalogermylenes (pages 227–228): J. Satge and P. Riviere Chapter 5.2.8.3.4 By Addition of Germylenes to Unsaturated Compounds (pages 228–232): J. Satge and P. Riviere Chapter 5.2.8.3.5 By Redistribution Reactions with Organogermanes (pages 232–234): J. Satge and P. Riviere Chapter 5.2.8.3.6 By Reaction with Diazoalkanes (pages 234–236): J. Satge and P. Riviere Chapter 5.2.8.4 From Germanium Alkoxides, Germanium Carboxylates or Germanium Oxides (pages 236–237): J. Satge and P. Riviere Chapter 5.2.8.4.1 By Reaction with Active Organometallics (pages 237–239): J. Satge and P. Riviere Chapter 5.2.8.4.2 By Reaction with Organic Halides and Active Metals (page 239): J. Satge and P. Riviere Chapter 5.2.8.5 From Germanium Hydrides (pages 240–251): J. Satge and P. Riviere Chapter 5.2.8.5.2 By Reaction with Diazoderivatives or Other Carbenoides (pages 252–253): J. Satge and P. Riviere Chapter 5.2.8.5.3 By Reaction with Active Organometallics to Eliminate MH (pages 254–256): J. Satge and P. Riviere Chapter 5.2.8.6 From Germyimetallics (pages 256–257): F. Glockling Chapter 5.2.8.6.1 By Reaction with Organic Halides to Eliminate HX (pages 257–261): F. Glockling Chapter 5.2.8.6.2 By Reaction with Ethers (pages 261–262): F. Glockling Chapter 5.2.8.6.3 By Addition to the Carbonyl Group of Co2 and Other Acyl Derivatives (pages 262–264): F. Glockling Chapter 5.2.8.6.4 By Addition to Alkenes and Alkynes (pages 264–266): F. Glockling Chapter 5.2.8.7 From Other Organogermanes by Exchange with Active Organometallics (pages 266–268): F. Glockling Chapter 5.2.9 Formation of the Carbon?Tin Bond (pages 268–269): R. C. Poller Chapter 5.2.9.2.1 By Reaction with Alkyl Halides (pages 269–272): R. C. Poller Chapter 5.2.9.2.2 By Reaction with Alkyl Halides Having Alkenyl or Aryl Substituents (pages 272–273): R. C. Poller Chapter 5.2.9.2.3 By Reaction with Alkyl Halides Having Other Substituents (pages 273–276): R. C. Poller Chapter 5.2.9.2.4 By Electrolysis at a Tin Anode (pages 276–277): R. C. Poller Chapter 5.2.9.2.5 By Electrolysis at a Tin Cathode (pages 277–278): R. C. Poller Chapter 5.2.9.3 From Tin Halides (Di? and Tetravalent) (pages 278–311): P. G. Harrison Chapter 5.2.9.3.2 Redistribution Reactions Involving Tetraorganostannanes and Tin(IV) Halides (pages 311–317): P. G. Harrison Chapter 5.2.9.3.3 From Tin(II) Halides (pages 317–322): P. G. Harrison Chapter 5.2.9.3.4 By Reaction with Diazoalkanes (pages 322–323): M. F. Lappert Chapter 5.2.9.3.5 By Reaction with Another Carbon?Centered Protic Compound (pages 323–324): M. F. Lappert Chapter 5.2.9.4 From Tin Alkoxides, Tin Carboxylates or Tin Oxides (pages 324–327): P. G. Harrison Chapter 5.2.9.4.2 By Reaction with Terminal Acetylenes (page 327): P. G. Harrison Chapter 5.2.9.4.3 By Decarboxylation of Organotin Carboxylates and Other Elimination Reactions (pages 328–329): P. G. Harrison Chapter 5.2.9.4.4 By Addition to Carbon?Carbon Multiple Bonds (pages 329–330): P. G. Harrison Chapter 5.2.9.4.5 By Transesterification (pages 331–332): P. G. Harrison Chapter 5.2.9.5 From Tin Hydrides (pages 332–333): P. G. Harrison Chapter 5.2.9.5.1 By Hydrostannation of Alkenes (pages 333–345): P. G. Harrison Chapter 5.2.9.5.2 By Hydrostannation of Alkynes (pages 345–349): P. G. Harrison Chapter 5.2.9.5.3 By Formation of Heterocyclic Compounds by Hydrostannation (pages 350–352): P. G. Harrison Chapter 5.2.9.5.4 By Reaction with Diazoalkanes (page 352): P. G. Harrison Chapter 5.2.9.6 From Organotin Amides (pages 353–354): M. F. Lappert Chapter 5.2.9.6.1 By Insertion (page 355): M. F. Lappert Chapter 5.2.9.6.2 By Reaction with a Terminal Acetylene (pages 356–357): M. F. Lappert Chapter 5.2.9.6.3 By Reaction with a Cyclopentadiene (page 357): M. F. Lappert Chapter 5.2.9.6.4 By Reaction with a Diazoalkane (pages 357–358): M. F. Lappert Chapter 5.2.9.6.5 By Reaction with Another Carbon?Centered Protic Compound (pages 358–359): M. F. Lappert Chapter 5.2.9.7 From Stannylmetallics (pages 359–360): F. Glockling Chapter 5.2.9.7.1 By Reaction with Organic Halides to Eliminate MX (pages 360–365): F. Glockling Chapter 5.2.9.7.2 By Addition to Alkenes and Alkynes (pages 365–366): F. Glockling Chapter 5.2.9.7.3 By Cleavage of Ethers and Epoxides (page 367): F. Glockling Chapter 5.2.9.8 From Other Organotins by Exchange with Active Organometallics (pages 367–369): F. Glockling Chapter 5.2.10 Formation of the Carbon?Lead Bond (pages 370–375): F. Huber Chapter 5.2.10.2.2 By Reaction with Aryl Halides (pages 375–376): F. Huber Chapter 5.2.10.2.3 By Reaction with Other Species (page 376): F. Huber Chapter 5.2.10.2.4 By Electrolysis of Sodium Tetraorganoaluminates at a Lead Anode (pages 377–379): F. Huber Chapter 5.2.10.2.5 By the Action of Aryldiazonium Salts on Pb Metal (page 379): F. Huber Chapter 5.2.10.3 From Lead Halides (Di? and Tetravalent) (pages 380–387): F. Huber Chapter 5.2.10.3.2 By Interaction of Lead (II) Salts with an Active Organometallic and an Organic Halide (pages 387–388): F. Huber Chapter 5.2.10.4 From Lead (II) Oxide, Lead Carboxylate or Plumbite Salts (page 389): B. Mauze Chapter 5.2.10.4.2 By Reaction with an Active Organometallic (pages 389–394): B. Mauze Chapter 5.2.10.5 From Organolead Hydrides (pages 394–396): P. G. Harrison Chapter 5.2.10.6 From Organolead Amides (page 396): M. F. Lappert Chapter 5.2.10.7 From Plumbylmetallics (page 397): F. Glockling Chapter 5.2.10.7.1 By Reaction with Organic Halides to Eliminate MX (pages 397–399): F. Glockling Chapter 5.2.10.7.2 By Addition to Alkenes and Alkynes (page 400): F. Glockling Chapter 5.2.10.7.3 By Cleavage of Epoxides and Lactones (page 400): F. Glockling Chapter 5.2.10.8 From Other Organoleads by Exchange with Active Organometallics (pages 400–404): F. Glockling Chapter 5.2.11 Formation of Mixed Group?IVB–Group?IVB Element Bonds (Except Carbon–Group?IVB Bonds) (pages 404–405): M. Drager Chapter 5.2.11.1 From the Elements (page 405): M. Drager Chapter 5.2.11.1.2 Insilicides (pages 405–406): M. Drager Chapter 5.2.11.1.3 In Germanides (page 406): M. Drager Chapter 5.2.11.1.4 In Hydrides (pages 406–407): M. Drager Chapter 5.2.11.2 From Group?IVB Halides (Di? and Tetravalent) (page 407): M. Drager Chapter 5.2.11.2.2 By Reaction with a Group?IVB Element–Active Metal Reagent (pages 407–408): M. Drager Chapter 5.2.11.3 From Group?IVB Hydrides (pages 408–409): M. Drager Chapter 5.2.11.3.2 By Reaction with a Group?IVB Element Amide (page 409): M. Drager Chapter 5.2.11.4 From Group?IVB Alkoxides and Carboxylates by Reaction with a Group?IVB Element?Active Metal Reagent (page 409): M. Drager Chapter 5.2.11.5 From Mixed Group?IVB Element Mercurials, By Photolysis (page 410): M. Drager Chapter 5.2.11.6 By Insertion of Silylenes, Germylenes, Stannylenes and Plumbylenes into Group?IVB–Hydrogen, –Halide and–Carbon Bonds (page 410): M. Drager