Inorganic Reactions and Methods, Electron-Transfer and Electrochemical Reactions; Photochemical and Other Energized Reactions (Volume 15)

How to Use this Book Preface to the Series Editorial Consultants to the Series Contributors to Volume 15 12. Electron-Transfer and Electrochemical Reactions 12.1. Introduction 12.2. Electron Transfer 12.3. Electrochemical Reactions 13. Photochemical and Other Energized Reactions 13.1. Introduction 13.2. Photosubstitution and Photoisomerization 13.3. Photoinduced Cleavage of Metal-Metal Bonds 13.4. Photoinduced Electron-Transfer Reactions 13.5. Pulse Radiolysis List of Abbreviations Author Index Compound Index Subject IndexContent: Chapter 12.2.1 Introduction (pages 1–5): J. J. Zuckerman, N. Sutin and R.G. Linck Chapter 12.2.2.1 Outer?Sphere Reactions (pages 5–7): R.G. Linck Chapter 12.2.2.1.2 Outer?Sphere Transition States (pages 7–9): R.G. Linck Chapter 12.2.2.2 Inner?Sphere Reactions (pages 9–11): R.G. Linck Chapter 12.2.2.2.2 Inner?Sphere Reactions: Scheme II (pages 11–12): R.G. Linck Chapter 12.2.2.2.3 Inner?Sphere Reactions: Scheme III (pages 12–14): R.G. Linck Chapter 12.2.2.2.4 Double?Ligand Bridging (page 14): R.G. Linck Chapter 12.2.2.3 Other Reaction Classes (page 14): R.G. Linck Chapter 12.2.2.3.2 Intramolecular Electron Transfer (pages 14–15): R.G. Linck Chapter 12.2.2.3.3 Two?Electron Transfers (page 16): R.G. Linck Chapter 12.2.3 Theory of Electron?Transfer Reactions (pages 16–17): N. Sutin Chapter 12.2.3.1 The Stability of the Precursor Complex (pages 17–19): N. Sutin Chapter 12.2.3.2 Potential?Energy Surfaces (page 20): N. Sutin Chapter 12.2.3.2.1 Of Zero Order (pages 20–22): N. Sutin Chapter 12.2.3.2.2 Of First Order (pages 22–23): N. Sutin Chapter 12.2.3.2.3 The Electronic Factor (pages 23–24): N. Sutin Chapter 12.2.3.3 Electron?Exchange Reactions (pages 24–26): N. Sutin Chapter 12.2.3.3.1 The Reorganization Energy (pages 26–29): N. Sutin Chapter 12.2.3.3.2 Nuclear Tunneling in Electron Exchange (pages 29–30): N. Sutin Chapter 12.2.3.3.3 Quantum?Mechanical Treatment (pages 30–31): N. Sutin Chapter 12.2.3.3.4 Comparison of Observed and Calculated Parameters for Electron Exchange (pages 32–37): N. Sutin Chapter 12.2.3.4 Electron Transfer Accompanied by a Net Chemical Change (pages 37–41): N. Sutin Chapter 12.2.3.4.2 Cross Reactions and Electron?Exchange Rates (pages 41–45): N. Sutin Chapter 12.2.3.4.3 Quantum?Mechanical Treatment (pages 45–46): N. Sutin Chapter 12.2.3.5 Conclusions (pages 46–49): C. Creutz and N. Sutin Chapter 12.2.4.1 The Inner?Shell Reorganization Energy: Exchange Rates of Aquo Ions (pages 49–53): C. Creutz and N. Sutin Chapter 12.2.4.2 Variations with Ligand: The Outer?Shell Reorganization Energy (pages 53–57): C. Creutz and N. Sutin Chapter 12.2.4.3 Electronic Factors: Nonadiabaticity (pages 58–59): C. Creutz and N. Sutin Chapter 12.2.4.4 Free?Energy Relations (pages 59–64): C. Creutz and N. Sutin Chapter 12.2.4.5 Inner?Sphere Versus Outer?Sphere Electron Transfer (pages 64–65): N. Sutin Chapter 12.2.4.6 Rate Saturation in Electron Transfer (pages 65–68): N. Sutin Chapter 12.2.5 Specific Reactivity Patterns in Electron?Transfer Reactions (pages 68–78): R.G. Linck Chapter 12.2.5.1.2 Two?Electron Reductants (page 78): R.G. Linck Chapter 12.2.5.2 Variation with the Oxidant (pages 78–81): R.G. Linck Chapter 12.2.5.2.2 Multiple?Electron Oxidants (pages 81–82): R.G. Linck Chapter 12.2.5.3 Oxidation and Reduction of Coordinated Ligands (page 82): R.G. Linck Chapter 12.2.5.4 Catalysis in Electron?Transfer Reactions (pages 83–84): R.G. Linck Chapter 12.2.5.4.2 Catalyzed Ligand Substitution (pages 84–85): R.G. Linck Chapter 12.2.5.5 Induced Electron?Transfer Reactions (pages 85–86): R.G. Linck Chapter 12.2.5.6 Photoinduced Electron?Transfer Reactions (pages 86–87): R.G. Linck Chapter 12.3.1 Introduction (page 88): W.E. Geiger Chapter 12.3.1.1 The Electrode Process (pages 88–90): W.E. Geiger Chapter 12.3.1.2.2 Chemical Reversibility (pages 90–100): W.E. Geiger Chapter 12.3.2.1.2 Pulse?Polarographic Methods (pages 100–106): W.E. Geiger Chapter 12.3.2.1.3 Alternating?Current Polarography (pages 107–110): W.E. Geiger Chapter 12.3.2.1.4 Cyclic Voltammetry (pages 110–116): W.E. Geiger Chapter 12.3.3 Evaluation of Formal Potentials (pages 116–117): W.E. Geiger Chapter 12.3.3.2 Involving Unstable Electrode Products (pages 118–123): W.E. Geiger Chapter 12.3.3.3 Involving Reactants Undergoing Multiple?Electrode Reactions (pages 123–128): W.E. Geiger Chapter 12.3.4 Chemical Reactions Accompanying Electrode Reactions (pages 128–129): W.E. Geiger Chapter 12.3.4.1.2 Fast?Reaction (I ? A) Limit (pages 130–133): W.E. Geiger Chapter 12.3.4.2 Reactions Following Electron Transfer (EC) (pages 133–135): W.E. Geiger Chapter 12.3.4.2.2 Giving Electroactive Products (ECE) (pages 135–141): W.E. Geiger Chapter 12.3.4.3 Other Coupled Chemical Reactions (pages 141–142): W.E. Geiger Chapter 12.3.5 Electrochemical Synthesis (page 142): W.E. Geiger Chapter 12.3.5.1 By Controlled?Potential Electrolysis (pages 142–145): W.E. Geiger Chapter 12.3.5.2 Involving Bulk Preparations (pages 145–146): W.E. Geiger Chapter 12.3.6 Thermodynamics of Simple Electrochemical Reactions (pages 147–150): M.J. Weaver Chapter 12.3.7 Kinetics of Electrochemical Reactions (pages 150–153): M.J. Weaver Chapter 12.3.7.2 Theory of Heterogeneous Electron?Transfer Reactions (pages 153–163): M.J. Weaver Chapter 12.3.7.3 Double?Layer Effects in Electrochemical Kinetics (pages 164–165): M.J. Weaver Chapter 12.3.7.4 Electrode?Reaction Mechanisms (pages 165–167): M.J. Weaver Chapter 12.3.7.5 Influence of the Electrode Material (pages 168–171): M.J. Weaver Chapter 12.3.7.6 Electrochemical Reactivity Patterns—Comparisons with Homogeneous Reactivities (pages 171–174): M.J. Weaver Chapter 13.2 Photosubstitution and Photoisomerization (pages 175–179): G.L. Geoffroy and P.C. Ford Chapter 13.2.1 With Group VIA Complexes (pages 179–183): P.C. Ford Chapter 13.2.1.2 Of Molybdenum and Tungsten (pages 183–184): P.C. Ford Chapter 13.2.2 With Group VIIA Complexes (page 184): P.C. Ford Chapter 13.2.3 With Group VIII Complexes (pages 184–186): P.C. Ford Chapter 13.2.3.2 Of Ruthenium (pages 186–190): P.C. Ford Chapter 13.2.3.3 Of Osmium (page 190): P.C. Ford Chapter 13.2.3.4 Of Cobalt (pages 190–194): P.C. Ford Chapter 13.2.3.5 Of Rhodium(III) and Iridium(III) (pages 195–198): P.C. Ford Chapter 13.2.3.6 Of Nickel(II) and Palladium(II) (pages 198–199): P.C. Ford Chapter 13.2.3.7 Of Platinum(II) (pages 199–202): P.C. Ford Chapter 13.2.3.8 Of Platinum(IV) (pages 202–204): P.C. Ford Chapter 13.2.4 With Metal Carbonyls (pages 204–205): H.B. Abrahamson Chapter 13.2.4.1.1 Of Titanium, Zirconium and Hafnium (pages 205–206): H.B. Abrahamson Chapter 13.2.4.1.2 Of Vanadium, Niobium and Tantalum (pages 206–209): H.B. Abrahamson Chapter 13.2.4.1.3 Of Chromium, Molybdenum and Tungsten (pages 209–217): H.B. Abrahamson Chapter 13.2.4.1.4 Of Manganese and Rhenium (pages 217–221): H.B. Abrahamson Chapter 13.2.4.1.5 Of Iron, Ruthenium and Osmium (pages 221–224): H.B. Abrahamson Chapter 13.2.4.1.6 Of Cobalt, Rhodium and Iridium (pages 225–226): H.B. Abrahamson Chapter 13.2.4.1.7 Of Nickel (page 226): H.B. Abrahamson Chapter 13.2.4.2 Involving Dinuclear Complexes (pages 226–229): H.B. Abrahamson Chapter 13.2.4.3 Involving Polynuclear Complexes (pages 229–230): H.B. Abrahamson Chapter 13.2.5 With Other Organometallic Complexes (pages 230–235): G.L. Geoffroy Chapter 13.2.5.2 Containing Isocyanides (pages 235–236): G.L. Geoffroy Chapter 13.2.5.3 Containing Olefins (pages 236–240): G.L. Geoffroy Chapter 13.2.5.4 Containing Arenes and Cyclopentadienyls (pages 240–242): G.L. Geoffroy Chapter 13.2.5.5 Containing Alkyls (pages 242–245): G.L. Geoffroy Chapter 13.3.1 In Dinuclear Complexes (pages 246–248): H.B. Abrahamson Chapter 13.3.1.1.2 And Contain Manganese, Technetium and Rhenium (pages 248–252): H.B. Abrahamson Chapter 13.3.1.1.3 And Contain Iron and Ruthenium (pages 252–254): H.B. Abrahamson Chapter 13.3.1.1.4 And Contain Cobalt (pages 254–255): H.B. Abrahamson Chapter 13.3.1.1.5 And Contain Nickel, Palladium and Platinum (pages 255–256): H.B. Abrahamson Chapter 13.3.1.2 That are Heteronuclear (pages 256–257): H.B. Abrahamson Chapter 13.3.2 In Polynuclear Complexes (pages 257–259): H.B. Abrahamson Chapter 13.4 Photoinduced Electron?Transfer Reactions (page 260): N. Sutin Chapter 13.4.1 Excited?State Assignments (pages 260–262): N. Sutin Chapter 13.4.2 Excited?State Electron Exchange (pages 262–265): N. Sutin Chapter 13.4.3 Quenching and Back Reactions (pages 265–268): N. Sutin Chapter 13.4.4 Free?Energy Relations (pages 269–271): N. Sutin Chapter 13.5.1 Introduction (pages 272–273): M.Z. Hoffman Chapter 13.5.3 Techniques (pages 273–274): M.Z. Hoffman Chapter 13.5.4.1 Of Hydrated Electrons (page 274): M.Z. Hoffman Chapter 13.5.4.2 Of Hydroxyl Radicals (pages 274–275): M.Z. Hoffman Chapter 13.5.4.3 Of Hydrogen Atoms (page 275): M.Z. Hoffman Chapter 13.5.4.4 Of Secondary Radicals (pages 275–276): M.Z. Hoffman Chapter 13.5.5 Of Metal Complexes (pages 276–277): M.Z. Hoffman Chapter 13.5.5.1 Involving Groups IA and IIA (page 277): M.Z. Hoffman Chapter 13.5.5.2 Involving Group IIIA (page 277): M.Z. Hoffman Chapter 13.5.5.3 Involving Group IVA (page 277): M.Z. Hoffman Chapter 13.5.5.4 Involving Group VA (pages 277–278): M.Z. Hoffman Chapter 13.5.5.5 Involving Group VIA (pages 278–279): M.Z. Hoffman Chapter 13.5.5.5.2 With Molybdenum and Tungsten (page 279): M.Z. Hoffman Chapter 13.5.5.6 Involving Group VIIA (page 280): M.Z. Hoffman Chapter 13.5.5.6.2 With Technetium (pages 280–281): M.Z. Hoffman Chapter 13.5.5.7 Involving Group VIIIA (pages 281–282): M.Z. Hoffman Chapter 13.5.5.7.2 With Ruthenium (pages 282–284): M.Z. Hoffman Chapter 13.5.5.7.3 With Osmium (page 284): M.Z. Hoffman Chapter 13.5.5.7.4 With Cobalt (pages 284–288): M.Z. Hoffman Chapter 13.5.5.7.5 With Rhodium (pages 288–289): M.Z. Hoffman Chapter 13.5.5.7.6 With Iridium (page 289): M.Z. Hoffman Chapter 13.5.5.7.7 With Nickel (pages 289–290): M.Z. Hoffman Chapter 13.5.5.7.8 With Palladium and Platinum (pages 290–291): M.Z. Hoffman Chapter 13.5.5.8 Involving Group IB (pages 291–292): M.Z. Hoffman Chapter 13.5.5.8.2 With Silver (pages 292–293): M.Z. Hoffman Chapter 13.5.5.8.3 With Gold (page 293): M.Z. Hoffman Chapter 13.5.5.9 Involving Group IIB (pages 293–294): M.Z. Hoffman Chapter 13.5.5.9.2 With Cadmium (page 294): M.Z. Hoffman Chapter 13.5.5.9.3 With Mercury (pages 294–295): M.Z. Hoffman Chapter 13.5.5.10 Involving Group NIB (page 295): M.Z. Hoffman Chapter 13.5.5.10.2 With Indium (page 295): M.Z. Hoffman Chapter 13.5.5.10.3 With Thallium (page 295): M.Z. Hoffman Chapter 13.5.5.11 Involving Group IVB (page 296): M.Z. Hoffman Chapter 13.5.5.11.2 With Lead (page 296): M.Z. Hoffman Chapter 13.5.5.12 Involving Lanthanides (page 296): M.Z. Hoffman Chapter 13.5.5.13 Involving Actinides (page 297): M.Z. Hoffman Inorganic Reactions and Methods systemizes the discipline of modern inorganic chemistry according to a plan constructed by a council of editorial advisors and consults that include three Nobel laureates (E.O. Fischer, H. Taube, and G. Wilkinson). Rather than producing a collection of unrelated review articles, this series creates a framework that reflects the creative potential of this scientific discipline. In a clear, concise, and highly organized manner, it provides an in-depth treatment of bond formation reactions categorized by element type. The series covers all areas of inorganic chemistry including chemistry of the elements, coordination compounds, donor-acceptor adducts, organometallic, polymer and solid-state material, and compounds relevant to bioinorganic chemistry. A unique index system provides users with several fast options for accessing information on forming any bond type, compound, or reaction. Coverage of both classical chemistry and the frontiers of today's research make this series a valuable reference for years to come.