High Resolution NMR in Solids Selective Averaging. Supplement to Advances in Magnetic Resonance

High Resolution NMR in Solids: Selective Averaging presents the principles and applications of the four approaches to high resolution NMR in solids — magic-angle sample spinning, multiple-pulse, proton-enhanced nuclear induction, and indirect detection methods. Divided into six chapters, this book initially describes the tensorial properties of nuclear spin interactions in both ordinary and spin spaces. It then deals with the manifestations of nuclear magnetic shielding in NMR spectra of both single-crystal and powder samples, and then discusses the techniques for analyzing spectra and rotation patterns in terms of shielding tensors. A wide range of NMR phenomena that are result of intentional or natural, selective or unselective averaging processes and the average Hamiltonian theory that yields the inclusion of correction are covered. This book also provides a detailed discussion on multiple-pulse sequences intended for high resolution NMR in solids. The concluding chapter examines the applications of multiple-pulse techniques, with particular emphasis on measurements of 19F and 1H shielding tensors. Discussions on rotations of angular momentum operators; time ordering and the Magnus expansion; off-resonance averaging of the second-order dipolar Hamiltonian; and phase transients are covered in the supplemental texts. Content: Advances in MAGNETIC RESONANCE , Page ii Front Matter , Page iii Copyright , Page iv Dedication , Page v Foreword , Page ix Preface , Pages xi-xiii I - Introduction , Pages 1-4 II - Nuclear Spin Hamiltonian , Pages 5-15 III - Manifestations of Nuclear Magnetic Shielding in NMR Spectra of Solids , Pages 17-35 IV - Averaging in Ordinary Coordinate and Spin Spaces , Pages 37-89 V - Detailed Discussion of Multiple-Pulse Sequences Intended for High-Resolution NMR in Solids , Pages 91-136 VI - Applications of Multiple-Pulse Techniques , Pages 137-170 Appendix A - Rotations of Angular Momentum Operators , Pages 171-172 Appendix B - Time Ordering and the Magnus Expansion , Pages 173-180 Appendix C - Off-Resonance Averaging of the Second-Order Dipolar Hamiltonian , Pages 181-182 Appendix D - Phase Transients , Pages 183-186 Subject Index , Pages 187-190 Ulrich Haeberlen. Includes Bibliographical References And Index.