Femtochemistry

Wiley, 2001. — 447 p. Фемтохимия - за работы в этой области А. Зивэйл получил Нобелевскую премию по химии 1999 г.: «за исследования химических реакций в реальном масштабе времени с помощью фемтосекундной спектроскопии». Главный результат работ состоит в том, что появилась возможность наблюдать за протеканием элементарных химических реакций "в реальном масштабе времени" и тем самым создан новый раздел химии – фемто-химия, который изучает химические процессы в фемтосекундном временном диапазоне (10^-15 – 10^-12 секунды). Изучением элементарных реакций занимается специальный раздел химии – химическая динамика. Основная задача химической динамики – определить структуру переходного состояния и проследить динамику его образования и распада в реальном времени. Contents Femtochemistry: Atomic-Scale Dynamics of the Chemical Bond Using Ultrafast Lasers (Nobel Lecture) Transition State Theory and Reaction Dynamics - An Overview Organic Femtochemistry: Diradicals, theory and Experiments The Coulomb Explosion Imaging Method and excited-State Proton-Transfer Reactions Femtosecond Dynamics at Conical Intersections Femtosecond Spectroscopy of Molecular Caging: Quantum and Classical Approaches Ultrafast Geometrical Relaxation in Polydiacetylene Induced by Sub-5-fs-Pulses Ultrafast Probing and Control of Molecular Dynamics: Beyond the Pump-Probe Method Quantum Control of Ultrafast Laser-Driven isomerization Reactions: Proton Transfer and Selective Preparation of Enantiomers Controlling the Vibration and Dissociation Dynamics in Small Moleculesand Clusters Two-Dimensional Optical Nonlinear Spectroscopy in Liquids Femtosecond Diffuse Reflectance Spectroscopy and Photochemistry of Organic Molecules Impurity Rydberg States as Probes of Local Dynamics in the Condensed Phase Photoelectron Spectroscopy as a Probe for Investigating Chemical Dynamics Femtochemistry in Nanocavities Energy- and Angle-Resolved Femtosecond Photoelectron Spectra from Rotating Molecules Femtosecond Time-resolved Fluorescence and Anisotropy Decay Spectroscopy of a Dendrimer with Eight Chromophores at the Rim Excited-State Dynamics of Conjugated Polymers and Oligomers Excited-State Intramolecular Proton Transfer (ESIPT) and Energy Relaxation Processes in Hydroxyphenylbenzotriazole Derivatives: A Femtosecond Laser Study Direct Detection of the Charge-Shift Reaction in Aromatic Vinyl Polymers by means of Transient Absorption and Dichroism Measurements Femtosecond Chemical Events of Intramolecular Charge Transfer and Intermolecular Hydrogen Bond Breaking after Electronic Excitation: Structural Dynamics in the Condensed Phase Vibrational Coherence in Electron Donor-Acceptor Complexes: Assignment of the Oscillatory Mode Femtosecond Studies of the Initial Events in the Photocycle of Photozctive Yellow Protein (PYP) Elementary Reactions in the Condensed Phase: Bond Breaking, Isomerization, and Electron Transfer Primary Processes in Photosynthesis by Femtosecond Nonlinear Spectroscopy Femtosecond Studies of Intramolecular Bond Twisting in Solution