شیمی رزین اپوکسی II: بر اساس سمپوزیومی که توسط بخش پوشش‌های آلی و شیمی پلاستیک‌های ACS در جلسه 183 انجمن شیمی آمریکا، لاس‌وگاس، نوادا، 28 مارس تا 2 آوریل 1982 برگزار شد

Content: Elastomer-modified epoxy resins in coatings applications / R.S. Drake, D.R. Egan, and W.T. Murphy -- Elastomeric polysiloxane modifiers for epoxy networks : synthesis of functional oligomers and network formation studies / J.S. Riffle, I. Yilgor, C. Tran, G.L. Wilkes, J.E. McGrath, and A.K. Banthia -- Synthesis and analysis of saturated, reactive n-butyl acrylate polymers for use in epoxy resin toughening / S. Gazit and James P. Bell -- Impact performance of epoxy resins with poly(n-butyl acrylate) as the reactive liquid rubber modifier / S. Gazit and James P. Bell -- Synthesis, morphology, and thermal stability of elastomer-modified epoxy resins / William A. Romanchick, John E. Sohn, and Jon F. Geibel -- Polyfunctional chelating agents for improved durability of epoxy adhesion to steel / Anthony J. Denicola, Jr. and James P. Bell -- High performance tris(hydroxyphenyl)methane-based epoxy resins / K.L. Hawthorne and F.C. Henson -- Fast curing epoxy-episulfide resin for uses at room temperature / Wenhsiung Ku and James P. Bell -- Influence of physical aging on the time-dependent properties of network epoxies and epoxy-matrix composites / Eric S.W. Kong -- Effects of impurities on hydrolytic stability and curing behavior / Gary L. Hagnauer and Peter J. Pearce -- Structure-property relations of polyethertriamine-cured bisphenol-A-diglycidyl ether epoxies / Fung-Ming Kong, Connie M. Walkup, and Roger J. Morgan -- Isothermal cure kinetics of an epoxy resin prepreg / Gary L. Hagnauer, Bernard R. Laliberte, and David A. Dunn -- Branching of high molecular weight polyhydroxyethers based on bisphenol-A / S.A. Zahir and S. Bantle -- Characterization and moldability analysis of epoxy reaction injection molding resins / J.S. Osinski and L.T. Manzione -- Water dispersible epoxy-g-acrylic copolymer for container coating / James T.K. Woo, Vincent Ting, James Evans, Carlos Ortiz, Gary Carlson, and Richard Marcinko Title Page......Page 1 Half Title Page......Page 3 Copyright......Page 4 ACS Symposium Series......Page 5 FOREWORD......Page 6 PdftkEmptyString......Page 0 PREFACE......Page 7 1 Elastomer-Modified Epoxy Resins in Coatings Applications......Page 9 Elastomer-Modified Epoxy Resin Preparation......Page 10 Elastomer-Modified Epoxy Resin Applications......Page 16 Elastomer-Modified Epoxy Resins - Coatings Background......Page 17 Elastomer Modification......Page 19 Impact Strength......Page 20 Summary......Page 24 Literature Cited......Page 26 2 Elastomeric Polysiloxane Modifiers for Epoxy Networks Synthesis of Functional Oligomers and Network Formation Studies......Page 29 Preparation of the Siloxanolate Equilibration Catalyst......Page 32 Equilibration of Aminopropyl Terminated Disiloxanes......Page 33 Synthesis of Piperazine Terminated Disiloxanes from the Reaction of Carboxy Functional Disiloxane and Aminoethyl Piperazine (AEP)......Page 34 Synthesis of the Modified Epoxy Networks......Page 35 Gel Permeation Chromatography (GPC)......Page 36 ATR-FTIR Investigations......Page 37 Synthesis of Functional Polydimethylsiloxane Oligomers......Page 38 Network Formation Studies......Page 48 ESCA......Page 53 Synthesis of Linear Copolymers......Page 60 Literature Cited......Page 61 3 Synthesis and Analysis of Saturated, Reactive n-Butyl Acrylate Polymers for Use in Epoxy Resin Toughening......Page 63 Background Calculations......Page 65 Results and Discussion......Page 67 Appendix A......Page 72 Appendix C......Page 73 Literature Cited......Page 75 4 Impact Performance of Epoxy Resins with Poly(n-butyl acrylate) as the Reactive Liquid Rubber Modifier......Page 76 Experimental......Page 78 Results and Discussion......Page 79 Conclusions......Page 89 Literature Cited......Page 90 Synthesis......Page 91 Proposed Mechanisms......Page 92 Morphology......Page 95 Thermal Stability......Page 103 Literature Cited......Page 123 6 Polyfunctional Chelating Agents for Improved Durability of Epoxy Adhesion to Steel......Page 125 Coupling Agents......Page 128 Literature Cited......Page 140 7 High Performance Tris(hydroxyphenyl)methane-Based Epoxy Resins......Page 141 Experimental......Page 142 8 Fast Curing Epoxy-Episulfide Resin for Uses at Room Temperature......Page 158 Experimental......Page 159 Results and Discussion......Page 165 Literature Cited......Page 173 Experimental......Page 175 Results and Discussion......Page 178 Conclusion......Page 188 Synopsis......Page 193 Literature Cited......Page 194 10 Effects of Impurities on Hydrolytic Stability and Curing Behavior......Page 196 Experimental......Page 197 Results and Discussion......Page 198 Literature Cited......Page 212 11 Structure—Property Relations of Polyethertriamine-Cured Bisphenol-A-diglycidyl Ether Epoxies......Page 213 Experimental......Page 215 Results and Discussion......Page 217 Conclusions......Page 227 Literature Cited......Page 228 12 Isothermal Cure Kinetics of an Epoxy Resin Prepreg......Page 230 Experimental......Page 231 Results......Page 233 Conclusions......Page 242 Literature Cited......Page 245 13 Branching of High Molecular Weight Polyhydroxyethers Based on Bisphenol-A......Page 246 Experimental......Page 251 Results......Page 253 Discussion......Page 256 Literature Cited......Page 262 14 Characterization and Moldability Analysis of Epoxy Reaction Injection Molding Resins......Page 263 Resin Characterization......Page 266 Resin Moldability......Page 274 List of Symbols......Page 280 Literature Cited......Page 281 15 Water Dispersible Epoxy-g-Acrylic Copolymer for Container Coating......Page 283 Particle Size Data......Page 287 MECHANISM OF GRAFTING......Page 289 Emulsion polymerization using the Epoxy-g-(methacrylic acid-styrene) copolymer as emulsifier.......Page 295 Literature Cited......Page 298 B......Page 301 C......Page 302 E......Page 303 F......Page 304 K......Page 305 P......Page 306 S......Page 308 W......Page 309 X......Page 310