Electrochemical Methods; Fundamentals and Applications (2nd Ed.) - Wiley
معرفی کتاب «Electrochemical Methods; Fundamentals and Applications (2nd Ed.) - Wiley» نوشتهٔ Allen J. Bard و Larry R. Faulkner، منتشرشده توسط نشر A.J. Bard and L.R. Faulkner. John Wiley & Sons در سال 2001. این کتاب در فرمت pdf، زبان انگلیسی ارائه شده است. «Electrochemical Methods; Fundamentals and Applications (2nd Ed.) - Wiley» در دستهٔ شیمی قرار دارد.
This edition is fully revised to reflect the current state off the field.
* Significant additions include ultramicroelectrodes, modified electrodes, and scanning probe methods.
* Many chapters have been modified and improved, including electrode kinetics, voltammetric methods, and mechanisms of coupled chemical reactions. Cover PREFACE CONTENTS MAJOR SYMBOLS Chapter 1 Introduction and overview of electrode processes 1.1 Introduction 1.2 Nonfaradaic Processes And The Nature Of The Electrode-Solution Interface 1.5 Semiempirical Treatment Of Nernstian Reactions With Coupled Chemical Reactions 1.6 The Literature Of Electrochemistry 1.7 References 1.8 Problems Chapter 2 Potentials And Thermodynamics Of Cells 2.1 Basic Electrochemical Thermodynamics 2.2 A More Detailed View Of Interfacial Potential Differences 2.3 Liquid Junction Potentials 2.4 Selective Electrodes 2.5 References 2.6 Problems Chapter 3 Kinetics Of Electrode Reactions 3.1 Review Of Homogeneous Kinetics 3.2 Essentials Of Electrode Reactions 3.3 Butler-Volmer Model Of Electrode Kinetics 3.4 Implications Of The Butler-Volmer Model For The One-Step, One-Electron Process 3.5 Multistep Mechanisms 3.6 Microscopic Theories Of Charge Transfer 3.7 References 3.8 Problems Chapter 4 Mass Transfer By Migration And Diffusion 4.1 Derivation Of A General Mass Transfer Equation 4.2 Migration 4.3 Mixed Migration And Diffusion Near An Active Electrode 4.4 Diffusion 4.5 References 4.6 Problems Chapter 5 Basic Potential Step Methods 5.1 Overview Of Step Experiments 5.2 Potential Step Under Diffusion Control 5.3 Diffusion-Controlled Currents At Ultramicroelectrodes 5.4 Sampled-Current Voltammetry For Reversible Electrode Reactions 5.5 Sampled-Current Voltammetry For Quasireversible And Irreversible Electrode Reactions 5.6 Multicomponent Systems And Multistep Charge Transfers 5.7 Chronoamperometric Reversal Techniques 5.8 Chronocoulometry 5.9 Special Applications Of Ultramicroelectrodes 5.10 References 5.11 Problems Chapter 6 Potential Sweep Methods 6.1 Introduction 6.2 Nernstian (Reversible) Systems 6.3 Totally Irreversible Systems 6.4 Quasireversible Systems 6.5 Cyclic Voltammetry 6.6 Multicomponent Systems And Multistep Charge Transfers 6.7 Convolutive Or Semi-Integral Techniques 6.8 Cyclic Voltammetry Of The Liquid-Liquid Interface 6.9 REFERENCES 6.10 Problems Chapter 7 Polarography And Pulse Voltammetry 7.1 Behavior At Polarographic Electrodes 7.2 Polarographic Waves 7.3 Pulse Voltammetry 7.3.1 Tast Polarography and Staircase Voltammetry 7.3.2 Normal Pulse Voltammetry 7.3.3 Reverse Pulse Voltammetry 7.3.4 Differential Pulse Voltammetry 7.3.5 Square Wave Voltammetry 7.3.6 Analysis by Pulse Voltammetry 7.4 References 7.5 Problems Chapter 8 Controlled-Current Techniques 8.1 Introduction 8.2 General Theory Of Controlledcurrent Methods 8.3 Potential-Time Curves In Constantcurrent Electrolysis 8.4 Reversal Techniques 8.5 Multicomponent Systems And Multistep Reactions 8.6 The Galvanostatic Double Pulse Method 8.7 Charge Step (Coulostatic) Methods 8.8 References 8.9 Problems Chapter 9 Methods Involving Forced Convection-Hydrodynamic Methods 9.1 Introduction 9.2 Theoretical Treatment Of Convective Systems 9.3 Rotating Disk Electrode 9.4 Rotating Ring And Ring-Disk Electrodes 9.5 Transients At The RDE And RRDE 9.6 Modulated Rde 9.7 Convection At UMEs 9.8 Electrohydrodynamics And Related Phenomena 9.9 References 9.10 Problems Chapter 10 Techniques Based On Concepts Of Impedance 10.1 Introduction 10.2 Interpretation Of The Faradaic Impedance 10.3 Kinetic Parameters From Impedance Measurements 10.4 Electrochemical Impedance Spectroscopy 10.5 Ac Voltammetry 10.6 Higher Harmonics 10.7 Chemical Analysis By Ac Voltammetry 10.8 Instrumentation For Electrochemical Impedance Spectroscopy 10.9 Analysis Of Data In The Laplace Plane 10.10 References 10.11 Problems Chapter 11 Bulk Electrolysis Methods 11.1 Classification Of Techniques 11.2 General Considerations In Bulk Electrolysis 11.3 Controlled-Potential Methods 11.4 Controlled-Current Methods 11.5 Electrometric End-Point Detectio 11.6 Flow Electrolysis 11.7 Thin-Layer Electrochemistry 11.8 Stripping Analysis 11.9 References 11.10 Problems Chapter 12 Electrode Reactions With Coupled Homogeneous Chemical Reactions 12.1 Classification Of Reactions 12.2 Fundamentals Of Theory For Voltammetric And Chronopotentiometric Methods 12.3 Theory For Transient Voltammetry And Chronopotentiometry 12.4 Rotating Disk And Ring-Disk Methods 12.5 Ume Techniques 12.6 Sine Wave Methods 12.7 Controlled-Potential Coulometric Methods 12.8 References 12.9 Problems Chapter 13 Double-Layer Structure And Adsorption 13.1 Thermodynamics Of The Double Layer 13.2 Experimental Evaluation Of Surface Excesses And Electrical Parameters 13.3 Models For Double-Layer Structure 13.4 Studies At Solid Electrodes 13.5 Extent And Rate Of Specific Adsorption 13.6 Effect Of Adsorption Of Electroinactive Species 13.7 Double-Layer Effects On Electrode Reaction Rates 13.8 References 13.9 Problems Chapter 14 Electroactive Layers And Modified Electrodes 14.1 Introduction-Intellectual And Technological Motivations 14.2 Types, Preparation, And Properties Of Films And Modified Electrodes 14.3 Electrochemical Responses Of Adsorbed Monolayers 14.4 Overview Of Processes At Modified Electrodes 14.5 Blocking Layers 14.6 Other Methods Of Characterization 14.7 References 14.8 Problems Chapter 15 Electrochemical Instrumentation 15.1 Operational Amplifiers 15.2 Current Feedback 15.3 Voltage Feedback 15.4 Potentiostats 15.5 Galvanostats 15.6 Difficulties With Potential Control 15.7 Measurement Of Low Currents 15.8 Computer-Controlled Instrumentation 15.9 Troubleshooting Electrochemical Systems 15.10 References 15.11 Problems Chapter 16 Scanning Probe Techniques 16.1 Introduction 16.2 Scanning Tunneling Microscopy 16.3 Atomic Force Microscopy 16.4 Scanning Electrochemical Microscopy 16.5 References 16.6 Problems Chapter 17 Spectroelectrochemistry And Other Coupled Characterization Methods 17.1 Ultraviolet And Visible Spectroscopy 17.2 Vibrational Spectroscopy 17.3 Electron And Ion Spectrometry 17.4 Magnetic Resonance Methods 17.5 Quartz Crystal Microbalance 17.6 X-Ray Methods 17.7 References 17.8 Problems Chapter 18 Photoelectrochemistry And Electrogenerated Chemiluminescence 18.1 Electrogenerated Chemiluminescence 18.2 Photoelectrochemistry At Semiconductors 18.3 Electrochemical Detection Of Photolytic And Radiolytic Products 18.4 References 18.5 Problems Appendix A Mathematical Methods А. 1 Solving Differential Equations By The Laplace Transform Technique A. 2 Taylor Expansions A. 3 The Error Function And The Gaussian Distribution A. 4 Leibnitz Rule A.5 Complex Notation A. 6 Fourier Series And Fourier Transformation A. 7 References A. 8 Problems Appendix B Digital Simulations Of Electrochemical Problems B. 1 Setting Up The Model B. 2 An Example B. 3 Incorporating Homogeneous Kinetics B. 4 Boundary Conditions For Various Techniques B. 5 Simulations In Convective Systems B. 6 Miscellaneous Digital Simulations B. 7 References B. 8 Problems Appendix C Reference Tables INDEX A - E F - P Q - Z "This book takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions."--Résumé de l'éditeur "This book takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions"--Jacket A broad and comprehensive survey of the fundamentals for electrochemical methods now in widespread use. This book is meant as a textbook, and can also be used for self-study as well as for courses at the senior undergraduate and beginning graduate levels. Knowledge of physical chemistry is assumed, but the discussions start at an elementary level and develop upward. This revision comes twenty years after publication of the first edition, and provides valuable new and updated coverage.
دانلود کتاب Electrochemical Methods; Fundamentals and Applications (2nd Ed.) - Wiley
* Significant additions include ultramicroelectrodes, modified electrodes, and scanning probe methods.
* Many chapters have been modified and improved, including electrode kinetics, voltammetric methods, and mechanisms of coupled chemical reactions. Cover PREFACE CONTENTS MAJOR SYMBOLS Chapter 1 Introduction and overview of electrode processes 1.1 Introduction 1.2 Nonfaradaic Processes And The Nature Of The Electrode-Solution Interface 1.5 Semiempirical Treatment Of Nernstian Reactions With Coupled Chemical Reactions 1.6 The Literature Of Electrochemistry 1.7 References 1.8 Problems Chapter 2 Potentials And Thermodynamics Of Cells 2.1 Basic Electrochemical Thermodynamics 2.2 A More Detailed View Of Interfacial Potential Differences 2.3 Liquid Junction Potentials 2.4 Selective Electrodes 2.5 References 2.6 Problems Chapter 3 Kinetics Of Electrode Reactions 3.1 Review Of Homogeneous Kinetics 3.2 Essentials Of Electrode Reactions 3.3 Butler-Volmer Model Of Electrode Kinetics 3.4 Implications Of The Butler-Volmer Model For The One-Step, One-Electron Process 3.5 Multistep Mechanisms 3.6 Microscopic Theories Of Charge Transfer 3.7 References 3.8 Problems Chapter 4 Mass Transfer By Migration And Diffusion 4.1 Derivation Of A General Mass Transfer Equation 4.2 Migration 4.3 Mixed Migration And Diffusion Near An Active Electrode 4.4 Diffusion 4.5 References 4.6 Problems Chapter 5 Basic Potential Step Methods 5.1 Overview Of Step Experiments 5.2 Potential Step Under Diffusion Control 5.3 Diffusion-Controlled Currents At Ultramicroelectrodes 5.4 Sampled-Current Voltammetry For Reversible Electrode Reactions 5.5 Sampled-Current Voltammetry For Quasireversible And Irreversible Electrode Reactions 5.6 Multicomponent Systems And Multistep Charge Transfers 5.7 Chronoamperometric Reversal Techniques 5.8 Chronocoulometry 5.9 Special Applications Of Ultramicroelectrodes 5.10 References 5.11 Problems Chapter 6 Potential Sweep Methods 6.1 Introduction 6.2 Nernstian (Reversible) Systems 6.3 Totally Irreversible Systems 6.4 Quasireversible Systems 6.5 Cyclic Voltammetry 6.6 Multicomponent Systems And Multistep Charge Transfers 6.7 Convolutive Or Semi-Integral Techniques 6.8 Cyclic Voltammetry Of The Liquid-Liquid Interface 6.9 REFERENCES 6.10 Problems Chapter 7 Polarography And Pulse Voltammetry 7.1 Behavior At Polarographic Electrodes 7.2 Polarographic Waves 7.3 Pulse Voltammetry 7.3.1 Tast Polarography and Staircase Voltammetry 7.3.2 Normal Pulse Voltammetry 7.3.3 Reverse Pulse Voltammetry 7.3.4 Differential Pulse Voltammetry 7.3.5 Square Wave Voltammetry 7.3.6 Analysis by Pulse Voltammetry 7.4 References 7.5 Problems Chapter 8 Controlled-Current Techniques 8.1 Introduction 8.2 General Theory Of Controlledcurrent Methods 8.3 Potential-Time Curves In Constantcurrent Electrolysis 8.4 Reversal Techniques 8.5 Multicomponent Systems And Multistep Reactions 8.6 The Galvanostatic Double Pulse Method 8.7 Charge Step (Coulostatic) Methods 8.8 References 8.9 Problems Chapter 9 Methods Involving Forced Convection-Hydrodynamic Methods 9.1 Introduction 9.2 Theoretical Treatment Of Convective Systems 9.3 Rotating Disk Electrode 9.4 Rotating Ring And Ring-Disk Electrodes 9.5 Transients At The RDE And RRDE 9.6 Modulated Rde 9.7 Convection At UMEs 9.8 Electrohydrodynamics And Related Phenomena 9.9 References 9.10 Problems Chapter 10 Techniques Based On Concepts Of Impedance 10.1 Introduction 10.2 Interpretation Of The Faradaic Impedance 10.3 Kinetic Parameters From Impedance Measurements 10.4 Electrochemical Impedance Spectroscopy 10.5 Ac Voltammetry 10.6 Higher Harmonics 10.7 Chemical Analysis By Ac Voltammetry 10.8 Instrumentation For Electrochemical Impedance Spectroscopy 10.9 Analysis Of Data In The Laplace Plane 10.10 References 10.11 Problems Chapter 11 Bulk Electrolysis Methods 11.1 Classification Of Techniques 11.2 General Considerations In Bulk Electrolysis 11.3 Controlled-Potential Methods 11.4 Controlled-Current Methods 11.5 Electrometric End-Point Detectio 11.6 Flow Electrolysis 11.7 Thin-Layer Electrochemistry 11.8 Stripping Analysis 11.9 References 11.10 Problems Chapter 12 Electrode Reactions With Coupled Homogeneous Chemical Reactions 12.1 Classification Of Reactions 12.2 Fundamentals Of Theory For Voltammetric And Chronopotentiometric Methods 12.3 Theory For Transient Voltammetry And Chronopotentiometry 12.4 Rotating Disk And Ring-Disk Methods 12.5 Ume Techniques 12.6 Sine Wave Methods 12.7 Controlled-Potential Coulometric Methods 12.8 References 12.9 Problems Chapter 13 Double-Layer Structure And Adsorption 13.1 Thermodynamics Of The Double Layer 13.2 Experimental Evaluation Of Surface Excesses And Electrical Parameters 13.3 Models For Double-Layer Structure 13.4 Studies At Solid Electrodes 13.5 Extent And Rate Of Specific Adsorption 13.6 Effect Of Adsorption Of Electroinactive Species 13.7 Double-Layer Effects On Electrode Reaction Rates 13.8 References 13.9 Problems Chapter 14 Electroactive Layers And Modified Electrodes 14.1 Introduction-Intellectual And Technological Motivations 14.2 Types, Preparation, And Properties Of Films And Modified Electrodes 14.3 Electrochemical Responses Of Adsorbed Monolayers 14.4 Overview Of Processes At Modified Electrodes 14.5 Blocking Layers 14.6 Other Methods Of Characterization 14.7 References 14.8 Problems Chapter 15 Electrochemical Instrumentation 15.1 Operational Amplifiers 15.2 Current Feedback 15.3 Voltage Feedback 15.4 Potentiostats 15.5 Galvanostats 15.6 Difficulties With Potential Control 15.7 Measurement Of Low Currents 15.8 Computer-Controlled Instrumentation 15.9 Troubleshooting Electrochemical Systems 15.10 References 15.11 Problems Chapter 16 Scanning Probe Techniques 16.1 Introduction 16.2 Scanning Tunneling Microscopy 16.3 Atomic Force Microscopy 16.4 Scanning Electrochemical Microscopy 16.5 References 16.6 Problems Chapter 17 Spectroelectrochemistry And Other Coupled Characterization Methods 17.1 Ultraviolet And Visible Spectroscopy 17.2 Vibrational Spectroscopy 17.3 Electron And Ion Spectrometry 17.4 Magnetic Resonance Methods 17.5 Quartz Crystal Microbalance 17.6 X-Ray Methods 17.7 References 17.8 Problems Chapter 18 Photoelectrochemistry And Electrogenerated Chemiluminescence 18.1 Electrogenerated Chemiluminescence 18.2 Photoelectrochemistry At Semiconductors 18.3 Electrochemical Detection Of Photolytic And Radiolytic Products 18.4 References 18.5 Problems Appendix A Mathematical Methods А. 1 Solving Differential Equations By The Laplace Transform Technique A. 2 Taylor Expansions A. 3 The Error Function And The Gaussian Distribution A. 4 Leibnitz Rule A.5 Complex Notation A. 6 Fourier Series And Fourier Transformation A. 7 References A. 8 Problems Appendix B Digital Simulations Of Electrochemical Problems B. 1 Setting Up The Model B. 2 An Example B. 3 Incorporating Homogeneous Kinetics B. 4 Boundary Conditions For Various Techniques B. 5 Simulations In Convective Systems B. 6 Miscellaneous Digital Simulations B. 7 References B. 8 Problems Appendix C Reference Tables INDEX A - E F - P Q - Z "This book takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions."--Résumé de l'éditeur "This book takes the student from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. Treats application of electrochemical methods to elucidation of reaction mechanisms; double layer structure and surface processes, and their effects on electrode processes are developed from first principles; other key features include a chapter on operational amplifier circuits and electrochemical instrumentation, unique coverage of spectrometric and photochemical experiments, and Laplace transform and digital simulation techniques. Contains numerous examples, illustrations, end-of-chapter problems, references, uniform mathematical notation, and an extensive list of symbols, abbreviations, definitions, and dimensions"--Jacket A broad and comprehensive survey of the fundamentals for electrochemical methods now in widespread use. This book is meant as a textbook, and can also be used for self-study as well as for courses at the senior undergraduate and beginning graduate levels. Knowledge of physical chemistry is assumed, but the discussions start at an elementary level and develop upward. This revision comes twenty years after publication of the first edition, and provides valuable new and updated coverage.