CRC Handbook of Thermodynamic Data of Polymer Solutions, 3-Volume Set: CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions

The **CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions** provides a new and complete collection of the practical thermodynamic data required by researchers and engineers for a variety of applications including: basic and applied chemistry; chemical engineering; thermodynamic research; computational modeling; membrane science and technology; and environmental and green chemistry. This book details such advanced applications as the separation of complex biochemical mixtures and the purification of proteins in aqueous two-phase systems. An advantage of The **CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions** is that the data is compiled into one comprehensive source. The data - which includes such developments as vapor-liquid and liquid-liquid equilibria, low-and high-pressure equilibrium data, enthalpic and volumetric data, and second virial coefficients - is necessary in studying intermolecular interactions, gaining insights into the molecular nature of mixtures, and providing the necessary basis for any developments of theoretical thermodynamic models. - **CRC Handbook of Thermodynamic Data of Polymer Solutions, Three Volume Set** CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions CRC Handbook of Thermodynamic Data of Copolymer Solutions CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions......Page 1 Foreword......Page 3 Preface......Page 4 About the Author......Page 5 Contents......Page 6 1.1. Objectives of the handbook......Page 8 Vapor-liquid equilibrium VLE measurements......Page 9 Liquid-liquid equilibrium LLE measurements......Page 18 High-pressure phase equilibrium HPPE measurements......Page 19 Measurement of enthalpy changes in polymer solutions......Page 20 PVT/density measurement for polymer melt and solution......Page 23 Determination of second virial coefficients A2......Page 24 Characterization of the polymers......Page 27 Measures for the polymer concentration......Page 28 Experimental data tables......Page 29 1.4. List of symbols......Page 31 1.5. References......Page 33 2.4. References......Page 85 2.1. Partial water vapor pressures or water activities for binary polymer solutions......Page 36 2.2. Partial solvent vapor pressures or solvent activities for ternary aqueous polymer solutions......Page 65 2.3. Classical mass-fraction Henry’s constants of water vapor in molten polymers......Page 81 3.1. Cloud-point and/or coexistence curves of quasibinary solutions......Page 88 3.2. Table of systems where binary LLE data were published only in graphical form as phase diagrams or related figures......Page 104 3.3.1. Nonelectrolyte solutions......Page 112 3.3.2. Electrolyte solutions......Page 174 3.4. Table of systems where ternary LLE data were published only in graphical form as phase diagrams or related figures......Page 290 3.5.1. Nonelectrolyte solutions......Page 308 3.5.2. Electrolyte solutions......Page 322 3.6. Table of systems where quaternary LLE data were published only in graphical form as phase diagrams or related figures......Page 335 3.7. Lower critical LCST and/or upper critical UCST solution temperatures of aqueous polymer solutions......Page 338 3.8. References......Page 346 4.1. Experimental data of quasibinary polymer solutions......Page 372 4.2. Table of systems where binary HPPE data were published only in graphical form as phase diagrams or related figures......Page 376 4.3. Experimental data of quasiternary solutions containing water and at least one polymer......Page 377 4.4. Table of systems where ternary HPPE data were published only in graphical form as phase diagrams or related figures......Page 381 4.5. References......Page 382 5.1. Enthalpies of mixing or intermediary enthalpies of dilution, and polymer partial enthalpies of mixing at infinite dilution, or polymer first integral enthalpies of solution......Page 384 5.2. Partial molar enthalpies of mixing at infinite dilution of water and enthalpies of solution of water vapor in molten polymers from inverse gas- liquid chromatography IGC......Page 420 5.3. Table of systems where additional information on enthalpy effects in aqueous polymer solutions can be found......Page 423 5.4. References......Page 431 6.1. PVT data of some polymers and their aqueous solutions......Page 438 6.2. Excess volumes and/or densities of aqueous polymer solutions......Page 455 6.3. Table of systems where additional information on volume effects in aqueous polymer solutions can be found......Page 478 6.4. References......Page 480 7.1. Experimental A2 Data......Page 484 7.2. References......Page 492 Appendix 1 List of systems and properties in order of the polymers......Page 494 Appendix 2 List of solvents in alphabetical order......Page 512 Appendix 3 List of solvents in order of their molecular formulas......Page 514 Providing the necessary basis for any developments of theoretical thermodynamic models, this book provides a complete collection of practical thermodynamic data for a variety of applications, including: basic and applied chemistry, chemical engineering, thermodynamic research, computational modeling, membrane science and technology, and environmental and green chemistry. The data -- which includes such developments as vapor-liquid and liquid-liquid equilibria, low-and high-pressure equilibrium data, enthalpic and volumetric data, and second virial coefficients -- is necessary when studying intermolecular interactions and gaining insights into the molecular nature of mixtures.