Conjugated Carbon-centered And Nitrogen Radicals / Konjugierte Kohlenstoff- Und Stickstoff-radikale (landolt-börnstein: Numerical Data And Functional ... Science And Technology - New Series) (vol 17)

Volume II/17 c is the third part of a supplement to the pre- vious compilations II/1 and II/9 a-d2 on magnetic properties of free radicals published in 1965 and 1977-1980, which covered the literature up to 1975. Due to the still very rapid development of the field and the inclusion of new sub- jects, the supplement covering the period 1975-85 had to be split into subvolumes, which will appear in fast succession. Togetherwith the ealier volumes, II/17 offers an up-to-date and comprehensive surveyand a collection of data on impor- tant chemical intermediates. General introduction....Pages 1-4 4.1 Introduction....Pages 5-7 4.2.1 Allyl and deuterated allyl radicals....Pages 8-10 4.2.2 Alkyl-substituted allyl radicals....Pages 10-12 4.2.3 Allyl radicals containing Cl....Pages 12-12 4.2.4 Allyl radicals containing oxygen....Pages 13-18 4.2.5 Allyl radicals containing sulfur....Pages 18-20 4.2.6 Allyl radicals containing nitrogen or phosphorus....Pages 20-23 4.2.7 Allyl radicals containing silicon....Pages 23-24 4.2.8 Allyl radicals containing Ag, Al, Au, Cu....Pages 24-25 4.2.9 Phenyl- and aryl-substituted allyl radicals....Pages 25-29 4.2.10 Aza-allyl and oxaallyl radicals....Pages 29-30 4.2.11 Semicyclic allyl radicals....Pages 30-32 4.2.12 Cyclopropenyl radicals....Pages 32-33 4.2.13 Isocyclic allyl radicals (cyclobutenyl, cyclopentenyl, ...)....Pages 33-35 4.2.14 Heterocyclic allyl radicals....Pages 36-48 4.2.15 Bicyclic allyl radicals....Pages 48-54 4.2.16 Allenyl (propargyl) radicals....Pages 54-57 4.3.1 Pentadienyl radicals....Pages 58-63 4.3.2 Pentenynyl radicals....Pages 64-65 4.3.3 Pentadiynyl radicals....Pages 65-66 4.3.4 Semicyclic pentadienyl radicals....Pages 66-70 4.3.6.1 Cyclopentadienyl and deuterated cyclopentadienyl radicals....Pages 70-71 4.3.6.2 Alkyl-substituted cyclopentadienyl radicals....Pages 71-80 4.3.6.3 Cyclopentadienyl radicals containing fluorine....Pages 80-81 4.3.6.5 Cyclopentadienyl radicals containing silicon....Pages 81-84 4.3.6.6 Cyclopentadienyl radicals containing gerrnanium or tin....Pages 84-85 4.3.6.7 Aryl-substituted cyclopentadienyl radicals....Pages 85-88 4.3.7.1 Cyclohexadienyl radicals without substituents at C(1)....Pages 88-91 4.3.7.2 Cyclohexadienyl radicals with one substituents at C(1)....Pages 91-99 4.3.7.3 Cyclohexadienyl radicals with two substituents at C(1)....Pages 100-105 4.3.7.4 Aza-cyclohexadienyl radicals....Pages 105-109 4.3.8 Pyryl radicals....Pages 109-118 4.3.9 Thiapyryl radicals....Pages 118-127 4.3.10.1 1-H-Pyridinyl radicals....Pages 127-134 4.3.10.2 1-Methyl-pyridinyl radicals....Pages 135-145 4.3.10.3 1-Ethyl-, 1-propyl-, 1-butyl- and 1-benzyl-pyridinyl radicals....Pages 145-147 4.3.10.4 1-Bis(alkoxycarbonyl)methylide pyridinyl radicals....Pages 147-148 4.3.10.5 1-Trimethylsilyl- and 1-triphenylsilyl-pyridinyl radicals....Pages 148-152 4.3.10.6 1-Trimethylgermyl- and 1-triphenylgermyl-pyridinyl radicals....Pages 152-156 4.3.10.8 1-Dialkylboryl-pyridinyl radicals....Pages 156-157 4.3.10.9 Aza-pyridinyl radicals....Pages 157-157 4.3.11 Phosphorinyl radicals....Pages 158-164 4.3.12 Sila-cyclohexadienyl radicals....Pages 164-164 4.4.3 Heptadienynyl radicals....Pages 165-166 4.4.4 Cycloheptatrienyl radicals....Pages 166-170 4.4.5 Cyclopentadienidemethyl radicals....Pages 170-171 4.4.6.1 Benzyl radicals without substituents at the exocyclic carbon atom C(7)....Pages 171-178 4.4.6.2 Benzyl radicals with one substituent at C(7)....Pages 178-185 7,7-Dialkyl-benzyl radicals....Pages 185-189 7-Methylene-benzyl radicals....Pages 189-190 Benzyl radicals with halogen containing substituents at C(7)....Pages 190-191 Benzyl radicals with O and O containing substituents at C(7)....Pages 192-206 Benzyl radicals with S and S containing substituents at C(7)....Pages 206-208 Benzyl radicals with N, P, or Se containing substituents at C(7)....Pages 209-216 Benzyl radicals with Si, Ge, Sn, or B containing substituents at C(7)....Pages 217-229 4.4.7 Benzyl-type radicals containing heterocyclic 6pi-electron ring systems....Pages 229-234 4.4.8 Bicyclic benzyl-type radicals....Pages 234-242 4.5 Radicals with 9 conjugated pi-electrons....Pages 242-250 4.7.1 Phenalenyl (perinaphthenyl) radicals....Pages 251-260 4.7.2.1 Diphenylmethyl radicals without substituents at the central carbon atom C(7)....Pages 260-260 7-Alkyldiphenylmethyl radicals....Pages 261-265 Diphenylmethyl radicals with halogen and halogen containing substituents at C(7)....Pages 265-267 Diphenylmethyl radicals with O and O containing substituents at C(7)....Pages 267-279 Diphenylmethyl radicals with S and S or Se containing substituents at C(7)....Pages 280-284 Diphenylmethyl radicals with N, P, Si, Ge, Sn, Pb, B or Cr containing substituents at C(7)....Pages 285-296 4.7.2.3 Diphenylmethyl-type radicals related to phenylindanyl....Pages 296-297 4.7.3.2 Fluorenyl radicals with alkyl and arylalkyl substituents at C(9)....Pages 298-299 4.7.3.4 9-Hydroxytluorenyl radicals and anion radicals from fluorenone and derivatives....Pages 300-313 4.7.3.6 Fluorenyl radicals with sulfur containing substituents at C(9)....Pages 314-314 4.7.3.8 Fluorenyl radicals with substituents containing Si, Ge and Sn at C(9)....Pages 315-316 4.7.4 Dibenzocyclohexadienyl and related radicals....Pages 317-317 4.7.5 Xanthyl radicals....Pages 318-320 4.7.6 Thioxanthyl and related radicals....Pages 321-324 4.7.7 Selenoxanthyl radicals....Pages 325-326 4.7.8 Acridinyl and related radicals....Pages 327-327 4.7.10.1 Diphenylmethyl-type radicals containing furan rings....Pages 328-332 4.7.10.2 Diphenylmethyl-type radicals containing thiophene and related rings....Pages 332-344 4.7.10.3 Diphenylmethyl-type radicals containing thiazol rings....Pages 344-346 4.7.10.4 Diphenylmethyl-type radicals containing pyridine rings....Pages 346-347 4.8 Radicals with 15 conjugated pi-electrons....Pages 347-348 4.9 Radicals with 17 conjugated pi-electrons....Pages 348-348 Part 1....Pages 349-357 Part 2....Pages 358-366 4.10.3 9-Phenylfluorenyl radicals....Pages 367-368 4.10.5 Phenylxanthyl radicals....Pages 369-370 4.10.6 Triphenylmethyl-type radicals containing 5-membered rings....Pages 370-370 4.11 Figures....Pages 371-377 4.12 References for 4....Pages 378-386 5.0 Introduction....Pages 387-387 5.1.1.1 Alkylaminyls....Pages 388-395 5.1.1.2 Vinylaminyls....Pages 396-397 5.1.1.3 Arylaminyls....Pages 397-398 5.1.1.4 Acylaminyls....Pages 398-405 5.1.2.1 Monocyclic aminyls....Pages 406-421 5.1.2.2 Fused polycyclic aminyls....Pages 422-437 5.2 Borylaminyl radicals....Pages 438-438 5.4.1 Acyclic hydrazyl radicals....Pages 439-451 Hydrazyls from three, four, and five-membered rings....Pages 452-463 Hydrazyls from six-membered rings....Pages 463-476 5.4.2.2 Fused polycyclic hydrazyls....Pages 477-478 5.4.3 Acyclic and cyclic hydrazonyl radicals....Pages 479-481 5.5.1.1 Leading atom of R1 and R2: Carbon....Pages 481-489 5.5.1.2 Leading atom of R1: Carbon....Pages 489-493 5.5.1.3 Leading atom of R2: Carbon....Pages 493-496 5.5.2 Cyclic oxyaminyl radicals....Pages 496-497 5.6 Phosphorylaminyl radicals....Pages 498-498 Leading atom of R: Carbon (part 1)....Pages 499-507 Leading atom of R: Carbon (part 2)....Pages 508-517 Leading atom of R: Other than carbon....Pages 517-522 5.7.1.2 Sulfinamidyl radicals....Pages 522-525 5.7.1.3 Sulfonamidyl radicals....Pages 525-528 5.7.2.1 Monocyclic thioaminyls....Pages 528-541 5.7.2.2 Fused polycyclic thioaminyls....Pages 541-550 5.7.2.3 Bridged thioaminyls....Pages 550-560 5.8 Silylaminyl radicals....Pages 560-562 5.9 Iminyl radicals....Pages 563-575 5.10 Diazenyl radicals....Pages 575-580 5.11 Triazenyl radicals....Pages 580-584 5.12.1.1 Iminoxyls of type RCH=N-O.....Pages 584-589 Leading atom of R: Carbon....Pages 589-602 Leading atom of R: Other than carbon (part 1)....Pages 602-612 Leading atom of R: Other than carbon (part 2)....Pages 613-621 5.12.2 Cyclic iminoxyl radicals....Pages 621-633 5.13 (Azo)oxyl radicals....Pages 633-634 5.14 Iminothiyl radicals....Pages 634-634 5.15 References for 5....Pages 635-642 List of symbols and abbreviations....Pages 643-644 Volume II/17d1 is the first part of the fourth subvolume of a supplement to the previous compilations II/1 and II/9a-d on magnetic properties of free radicals, published in 1965 and 1977 - 1980, which covered the literature up to 1975.