Comprehensive Coordination Chemistry II: From Biology to Nanotechnology, Volume 1: Fundamentals: Ligands, Complexes, Synthesis, Purification, and Structure

McCleverty J.A. (ed.) Comprehensive Coordination Chemistry II - From Biology to Nanotechnology 2 ed. in 10 Vol.Set Volume 01 - Fundamentals 2003 [pdf 819sc 806+1c. 11.35mb] Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.Table of Contents:Volume 1: Fundamentals: Ligands, Complexes, Synthesis, Purification, and StructureSection I: LigandsSection II: Synthesis, Purification, and Characterization of Coordination CompoundsSection III: Reactions of Coordinated LigandsSection IV: Stereochemistry, Structure, and Crystal EngineeringSection V: New Synthetic MethodsVolume 2: Fundamentals: Physical Methods, Theoretical Analysis, and Case StudiesSection I: Physical MethodsSection II: Theoretical Models, Computational Methods, and SimulationSection III: SoftwareSection IV: Case StudiesVolume 3: Coordination Chemistry of the s, p, and f MetalsVolume 4: Transition Metal Groups 3–6Volume 5: Transition Metal Groups 7 and 8Volume 6: Transition Metal Groups 9–12Volume 7: From the Molecular to the Nanoscale: Synthesis, Structure, and PropertiesVolume 8: Bio-coordination ChemistryVolume 9: Applications of Coordination ChemistryVolume 10: Indexes Cover Page......Page 1 Editors-in-Chief......Page 2 Volume Editors......Page 3 International Advisory Board......Page 4 Preface......Page 5 Comprehensive Coordination Chemistry Mapping Tables......Page 6 Coordination Chemistry: The Past, Present, and Possible Future......Page 15 Introduction to Volumes 1 and 2......Page 17 Introduction to Volume 3......Page 18 Introduction to Volume 4......Page 19 Introduction to Volume 5......Page 20 Introduction to Volume 6......Page 21 Introduction to Volume 7......Page 22 Introduction to Volume 8......Page 30 Introduction to Volume 9......Page 31 Permission Acknowledgments......Page 33 COMPREHENSIVE COORDINATION CHEMISTRY II......Page 34 Volumes......Page 35 Info on Volume 1......Page 36 Introduction......Page 38 Homocoupling of halopyridines......Page 39 Cross-coupling of halopyridines with pyridyl organometallics......Page 40 Cycloaddition methods......Page 41 Other Synthetic Methods......Page 42 Functionalized Bipyridines: Synthesis and Uses of Common Building Blocks......Page 43 Hydrocarbons......Page 45 Acid Derivatives......Page 47 Unsymmetrical Derivatives......Page 48 Synthesis......Page 49 Bipyridines with Pendant Macrocycles......Page 50 Multidentate Chelates......Page 51 Bipyridines in the Main Chain......Page 52 Carbohydrates......Page 53 Biisoquinolines......Page 54 References......Page 55 Introduction and Basic Transformations......Page 61 Halogenation......Page 62 Alkylation and Catalyzed Cross-coupling......Page 63 Molecular Recognition and Phenanthroline-based Ionophores......Page 64 Chromophore-containing Phenanthrolines......Page 65 Oligophenanthrolines......Page 67 Polymer Supports for Phenanthrolines......Page 70 Phenanthroline-based Dendrimers......Page 71 References......Page 72 Introduction and Scope......Page 76 4 ́-Substituted......Page 77 6-Substituted......Page 79 4,4 ́-Disubstituted......Page 81 6,6 ́-Disubstituted......Page 82 Trisubstituted Terpyridines......Page 83 Other Fused......Page 84 Oligopyridines......Page 86 References......Page 87 Complexes with the 1,8-Naphthyridine Ligand......Page 89 Complexes with Functionalized Derivatives of the 1,8-Naphthyridine Ring......Page 90 Other Multidentate Ligands Derived from the 1,8-Naphthyridine Ring......Page 93 References......Page 94 Introduction and Scope......Page 96 Overview......Page 97 From halopyridazines......Page 98 From pyridazine-carbaldehydes and pyridazine-ketones......Page 99 From 1,2,4,5-tetrazines......Page 101 Preparation of precursors: 1,4-dihalophthalazines, 1,4-dicyanophthalazine, and 1,4-dihydrazinophthalazine......Page 103 From 1,4-dihydrazinophthalazine......Page 105 Condensed phthalazine-derived ligands......Page 106 Coordination Chemistry......Page 107 Overview......Page 109 Preparation of precursors: imidates, amide hydrazones, and hydrazides......Page 111 Ligand Preparations......Page 112 Coordination Chemistry......Page 121 Concluding Remarks......Page 123 References......Page 126 Introduction......Page 129 Structure and Tautomerism of beta-Diketones......Page 130 Synthesis of beta-Diketones......Page 131 Coordination Modes of beta-Diketones......Page 133 Monoanionic beta-diketonates......Page 134 Synthesis from Metals......Page 135 Synthesis from Metal Acetates, Nitrates, Sulfates, or Carbonates......Page 136 Synthesis from Metal Alkyls or Aryls......Page 137 Tri-, Tetra-, and Polyketones......Page 138 Diketones with Substituents Containing Additional Donor Atoms......Page 139 Acylpyrazolones and Analogue beta-Diketones with a Heterocycle Fused to the Chelating Ring......Page 141 References......Page 144 Neutral Phenylcyanamides (pcydH)......Page 148 Physical Properties of Phenylcyanamides......Page 149 Coordination Geometry......Page 150 Ruthenium Complexes......Page 151 Cobalt Complexes......Page 152 Copper, Silver, and Gold Complexes......Page 153 Summary......Page 154 References......Page 155 Synthetic Methods for Benzimidazole Derivatives......Page 156 Modular Approach......Page 158 Chelate Ligands Composed of a Combination of Bidentate Ligands......Page 159 Chelate Ligands Composed of a Combination of Tridentate Ligands......Page 160 Chelate Ligands Composed of Miscellaneous Combinations......Page 161 Chemical Functions of Coordination Compounds with Imidazole/Benzimidazole Ligands......Page 162 References......Page 164 Scope and Limitations......Page 166 Introduction to Bridging Ligands......Page 167 Diazines and Polyazines......Page 168 Linked Pyridines......Page 169 Bridging Ligands with Donor Atoms Outside the Ring......Page 171 Bridging Ligands with Multiple Donor Atoms in a Ring......Page 172 Bridging Ligands with Pyridine Subunits......Page 173 Conjugated spacers......Page 174 Bridging Ligands with Phenanthroline Subunits......Page 175 Fused ring systems......Page 176 Linked phenanthrolines......Page 177 Pyridine-based Bridging Ligands......Page 178 Other Bridging Ligands......Page 179 Linked Bridging Ligands......Page 180 Porphyrin-containing Bridging Ligands......Page 181 Cavity Bridging Ligands......Page 182 References......Page 184 Introduction......Page 189 Preparation of Poly(pyrazolyl)borates......Page 191 Specific Bpx Ligands......Page 193 Regiochemistry in ligand synthesis......Page 211 Steric effects......Page 212 Coordination Modes......Page 213 Soft S-Donor Scorpionates......Page 214 Hydrobis(mercaptoimidazolyl)Borates (Bmx)......Page 215 Hydrotris(mercaptoimidazolyl)Borates (Tm)......Page 216 Poly(Imidazolyl)Borates......Page 217 Poly-(triazolyl)- (HnB(tz)4-n), -(tetrazolyl)-borates (HnB(tet)4-n)......Page 218 Poly(benzotriazolyl)Borates (HnB(Btz)4-n)......Page 219 Coordination modes of bis(pyrazolyl)alkanes......Page 220 Synthesis of symmetrical bis(pyrazolyl)alkanes......Page 222 Synthesis of unsymmetrical bis(pyrazolyl)alkanes......Page 223 Tris(pyrazolyl)Alkanes......Page 224 Synthesis of tris(pyrazolyl)methanes......Page 225 Unsymmetrical tris(pyrazolyl)methane......Page 227 C-alkylated tris(pyrazolyl)methane......Page 228 Poly(Pyrazolyl)Silanes......Page 229 Tris(Pyrazolyl)Methanesulfonato......Page 230 Heteroscorpionates......Page 231 Poly(Azolyl)-Phosphine, -Phosphinate, Phosphazene and Phosphine-Oxide......Page 232 Bis(azolyl)-metallates......Page 233 References......Page 234 Introduction......Page 241 Substituted Diamines......Page 242 Polyamines......Page 245 Diamine-Diamide Ligands......Page 248 2,6-Substituted Pyridines......Page 249 Xylyl-based Ligands......Page 250 Multidentate Ligands Containing Pyridazine, Phthalazine, Pyrazolyl, Thiazolyl, Oxadiazolyl, Triazine, and Thiophene Bridges......Page 251 Multidentate Ligands Containing More than Two Pyridine Rings......Page 253 Polyethyleneglycols and Glymes......Page 254 Tripodal Ligands with Nitrogen as the Bridgehead Atom......Page 256 Tripodal Ligands with Carbon as the Bridgehead Atom......Page 261 Macrocyclic Ligands......Page 262 Crown Ethers......Page 263 Other Preorganized Macrocycles......Page 264 Photoresponsive macrocycles......Page 265 pH-responsive macrocycles......Page 266 Siderophore-type Macrocycles......Page 267 Dendrimeric Ligands......Page 268 Polycarboxylic Acids......Page 270 References......Page 276 1.12 Phosphorus Ligands......Page 282 Synthetic routes......Page 283 By reduction......Page 285 Miscellaneous methods......Page 287 Secondary Phosphines......Page 288 Using metal phosphides......Page 289 Reactions of secondary phosphines......Page 290 Tertiary Phosphines......Page 291 Using other organometallics......Page 292 Alkali-metal derivatives......Page 293 Hydrophosphinations......Page 294 From polyphosphines......Page 295 Preparation by classic methods......Page 296 Functionalized Tertiary Phosphines......Page 297 Ditertiary Phosphines......Page 299 Polydentate Tertiary Phosphines......Page 301 Synthetic routes to water-soluble tertiary phosphines......Page 303 Synthetic routes to fluorinated tertiary phosphines......Page 305 Coordination chemistry of fluorinated tertiary phosphines and catalytic applications......Page 306 Synthesis of tertiary phosphine oxides......Page 307 Properties of tertiary phosphine oxides......Page 308 Synthetic routes......Page 309 Synthesis of phosphinites, phosphonites, and phosphites......Page 311 Coordination chemistry......Page 314 By aminolysis reactions......Page 315 Coordination chemistry of (phosphino)amines......Page 317 References......Page 318 Introduction......Page 326 Tripod Ligands with Three Equal Phosphane Donors......Page 327 Tripod Ligands with Three Different Phosphane Donors......Page 328 Tripod Ligands with Chiral Phosphane Donors......Page 330 Tripod Ligands Containing Two Potentially Different Phosphane Donors......Page 331 Tripod Ligands Containing One Phosphane Donor......Page 333 Tripod Ligands Containing RCp Donor Groups......Page 334 Tripod Ligands with Different Types of Linker and Donor Groups......Page 336 Tripod Ligands with a Phosphane Donor Bonded to the Central Carbon......Page 339 Tripod Ligands with a Neopentane-like Scaffolding......Page 341 Tripod Ligands with a Central Nitrogen......Page 342 Tripod Ligands with a Central Phosphorus......Page 343 Tripod Ligands Based on Miscellaneous Scaffoldings......Page 345 Heterocycles as Tripod Ligands......Page 347 References......Page 349 Introduction......Page 352 Oxidation of bis(phosphino)amines - method A......Page 353 Sodium hydride......Page 354 Alcoholysis of bis(dichlorophosphoryl)amide (tetrachlorodioxodiphosphazane)......Page 355 Hydrolysis of other functional diphosphazene derivatives......Page 356 In situ formation of imidodiphosphinato ligands......Page 357 Acidity And Preparation Of Alkali Metal And Other Salts......Page 358 Spectroscopic And Structural Characterization......Page 363 Coordination Patterns......Page 364 Metal Complexes......Page 370 References......Page 371 Introduction......Page 377 Dithiophosphinic acids, R2P(S)SH......Page 378 Coordination patterns......Page 379 Dithiophosphinates......Page 380 Dithiophosphates......Page 382 Dithiophosphonates......Page 383 Metal complexes......Page 385 Synthesis......Page 387 Coordination patterns......Page 389 Metal complexes......Page 390 General......Page 391 Coordination patterns......Page 392 Metal complexes......Page 393 Metal complexes......Page 395 References......Page 397 Introduction......Page 405 Arsine Synthesis......Page 406 Stibine Synthesis......Page 407 Bismuthine Synthesis......Page 410 Bonding......Page 411 Coordination modes......Page 413 References......Page 415 Thioethers......Page 418 Selenoethers......Page 419 Telluroethers......Page 420 Bonding......Page 422 References......Page 423 Introduction......Page 426 Thioether Macrocycles......Page 427 Coordination Chemistry and Properties......Page 428 Selenoether Macrocycles......Page 430 Telluroether Macrocycles......Page 433 Abbreviations......Page 435 References......Page 436 Introduction......Page 438 General Synthetic Method......Page 439 Tautomerism......Page 440 Monodentate Schiff Bases......Page 441 N,N and N,O Donors......Page 442 N,S(Se) Donors......Page 443 N,O Donors......Page 444 Other Donors......Page 445 Asymmetrical......Page 447 Symmetrical......Page 449 N,S, N,O,S and other Donors......Page 452 Chiral Tetradentate Schiff Bases......Page 453 Equilibrium Studies......Page 454 Compartmental Acyclic Schiff Bases......Page 455 Phenol-based Derivatives......Page 456 Di- and Triketone Derivatives......Page 458 End-off Ligands......Page 459 Polypodal Ligands......Page 460 Macrocyclic Schiff Bases......Page 462 Compartmental Macrocycles......Page 464 Noncompartmental Macrocycles......Page 466 Bibracchial Macrocycles......Page 467 Ring Contraction and Expansion......Page 468 References......Page 470 Introduction and Scope......Page 474 Cyclic Secondary Amines......Page 476 Azamacrocycles with Imine Functions......Page 477 Ketone and beta-enone-Amine Reactions......Page 478 beta-Keto Imine-Amine Reactions, Cyclidenes......Page 479 Beta-Dicarbonyl-Amine Reactions......Page 480 Azamacrocycles with Amide or Amidate Functions......Page 481 Macrocycles Formed by Mannich Condensations, Azacyclams......Page 484 Functionalized C-substituents......Page 485 Nitro- and Amine-substituents......Page 486 Nitromethyl and Aminomethyl Substituents......Page 487 Carboxyl Substituents......Page 488 C-pendants that Coordinate Exocyclic Cations......Page 489 Azamacrocycles with N-Substituents......Page 490 Carboxyalkyl Substituents......Page 491 Omega-Aminoalkyl Substituents......Page 492 Other N-substituents......Page 493 Bi- and Tricyclic Azamacrocycles......Page 494 Spiro-azamacrocycles......Page 495 N-X-N ́ Linked Bisazamacrocycles......Page 496 References......Page 498 Phosphine Macrocycles......Page 502 Arsine Macrocycles......Page 509 References......Page 511 Introduction......Page 512 Unsubstituted Calixarenes......Page 513 Aryloxides......Page 515 Oxygen and Nitrogen Donor Atoms......Page 516 References......Page 517 Introduction......Page 519 Strategic Considerations in Porphyrin Synthesis......Page 520 2,3,7,8,12,13,17,18-Octaethylporphyrin (H2OEP (1))......Page 521 5,10,15,20-Tetraphenylporphyrin (H2TPP (2))......Page 525 Transformation of dipyrromethenes into porphyrins......Page 526 Syntheses of dipyrromethanes......Page 527 Transformation of dipyrromethanes into porphyrins......Page 528 5,15-Diaryl and 5,15-Dialkylporphyrins......Page 531 References......Page 532 Introduction......Page 533 General Synthetic Considerations......Page 534 Substituted Phthalocyanine Ligands......Page 535 Nonuniformly Substituted Pcs......Page 536 Azaphthalocyanines......Page 537 Extended Phthalocyanines......Page 538 References......Page 539 1.25 Metal Aqua Ions......Page 541 Geometry of Aqua Ligands......Page 542 Group 1: Li+(aq), Na+(aq), K+(aq), Rb+(aq),Cs+(aq)......Page 543 Group 3: Scandium, Yttrium, the Lanthanides, and Actinides......Page 544 Group 4: Titanium, Zirconium, and Hafnium......Page 546 Group 5: Vanadium, Niobium, and Tantalum......Page 548 Group 6: Chromium, Molybdenum, and Tungsten......Page 550 Group 7: Manganese, Technetium, and Rhenium......Page 553 Group 8: Iron, Ruthenium, and Osmium......Page 555 Group 9: Cobalt, Rhodium, and Iridium......Page 556 Group 11: Copper, Silver, and Gold......Page 559 Group 12: Zinc, Cadmium, and Mercury......Page 560 Group 13: Boron, Aluminum, Gallium, Indium, and Thallium......Page 561 Group 14: Germanium, Tin, and Lead......Page 562 Range of Labilities of Aqua Metal Ions......Page 563 Formation of Metal Complexes......Page 565 Classification of Mechanisms......Page 566 Volume of Activation......Page 567 Group 2: Be2+, Mg2+......Page 569 Six-coordination Divalent Transition Metal Aqua Ions......Page 570 Six-coordinate Trivalent Transition Metal Aqua Ions......Page 573 Transition Metal Oxo/Aqua Ions......Page 574 Trivalent Lanthanide Metal Ions......Page 575 References......Page 577 Solvent Properties......Page 582 Donor number......Page 583 Classification based on chemical constitution......Page 584 Other classification......Page 585 Ionic Solvents......Page 586 The Cations......Page 587 BF4- or PF6- containing ionic liquids......Page 588 Solvent Properties of Ionic Liquids......Page 589 References......Page 590 Choosing the "Right" Chromatography......Page 592 General Separation Techniques......Page 593 Separations of Chiral Complexes and Isomers......Page 594 Capillary and Capillary Zone Electrophoresis of Complexes......Page 595 Size-exclusion Chromatography (SEC) for Metal Complexes......Page 596 IMAC Separations via Inorganic Complexes......Page 597 Immobilized Metal Complexes for Organic Separations (IMCOS)......Page 598 Computer-Aided Chromatography Involving Metal Complexes......Page 599 References......Page 601 Introduction......Page 603 Cooling......Page 604 Sublimation......Page 605 Slow Diffusion of Reactants......Page 606 Other Approaches to Obtaining Better Crystals......Page 607 Introduction......Page 608 Electron-acceptor/donor Properties of the Metal Center......Page 609 Electron-donor/acceptor Properties of the Ligands......Page 610 Acid-Base and Related Reactions......Page 611 Template Synthesis......Page 612 Summary and Conclusions......Page 613 References......Page 614 Bonding and Structural Types......Page 618 Infrared Spectral Characteristics......Page 620 Reactions with Electrophiles......Page 621 Oxidative Coupling......Page 622 Catalytic Reduction of Co2......Page 623 References......Page 624 General Properties of NO, Bonding Models, and the Enemark-Feltham Formalism......Page 626 Coordination number 6......Page 628 Coordination number 5......Page 633 eta1-ON (Isonitrosyls) and eta2-NO Complexes......Page 635 N2O Complexes......Page 636 Synthesis......Page 638 Nucleophilic additions to bound NO......Page 640 Reductive nitrosylation......Page 641 Synthesis of N2O complexes......Page 642 Catalyzed disproportionation of NO in basic medium......Page 643 References......Page 644 First-Row Transition Metals......Page 647 Second- and Third-Row Transition Metals......Page 650 References......Page 651 Reactions with Preservation of the {Cno} Fragment......Page 652 Reactions Centered at the O-atom......Page 653 Reactions Centered at the N- or the C-atom......Page 654 Reactions with N-O Bond Cleavage......Page 656 References......Page 657 Introduction......Page 659 Reactions with Aprotic Nucleophiles and Subsequent Electrophilic Additions......Page 660 Water and alcohols......Page 663 Formation of C-N bonds......Page 667 Cycloadditions......Page 671 Electrophilic Additions......Page 673 References......Page 677 Theoretical Background......Page 681 The Hardness Rule......Page 684 The Energetic Origin of the Lone-pair Effect......Page 685 References......Page 687 Solute-Solvent Interactions (SSI)......Page 688 Symmetry Effects by the Second Coordination Sphere......Page 689 Bond Strength and Covalency Effects Induced by the Second Coordination Sphere......Page 691 The Stabilization of High Oxidation States of the Late 3d-Metals by Second Coordination Sphere Effects......Page 693 References......Page 696 Introduction and Scope......Page 698 The Hydrogen Bond......Page 699 1D Assemblies Based on Silver(I) Complexes......Page 700 Halometallates as Hydrogen-bond Acceptors......Page 701 Layered Networks with other Transition-metal Ions......Page 702 Metalloporphyrins as Supramolecular Building Blocks......Page 703 Combining Coordination Polymers and Hydrogen Bonds......Page 704 References......Page 706 The Approaches to Biphasic Synthesis......Page 708 Solvent Combinations......Page 709 Ionic Liquid-Organic......Page 710 Ionic Liquid-Aqueous......Page 712 Biological Relevance......Page 713 References......Page 714 Hydrothermal Synthesis of Organic-Inorganic Hybrid Materials: General Considerations......Page 715 The Organic Component......Page 716 Metal Organophosphonates......Page 718 Inorganic Oxides Incorporating Organoimine Ligands......Page 720 Bimetallic Oxide Networks......Page 722 Metal-Halide and -Pseudohalide Materials......Page 725 References......Page 726 Introduction......Page 728 Hydrolysis and Condensation......Page 730 Control of Morphology......Page 731 Modifiers......Page 732 Multinuclear Alkoxide Precursors: Homonuclear......Page 733 Multinuclear Alkoxide Precursors: Heteronuclear......Page 734 Organic-Inorganic Hybrid Materials......Page 735 Alkyltrialkoxysilanes and Silasesquioxanes......Page 736 Doping with Polymers......Page 737 Templating of Sol-Gel Materials......Page 738 Aqueous Colloidal Precursors: Condensation......Page 739 Examples of Sol-Gel Syntheses In Catalysis,Electroceramics, Electrochromics, and Biomaterials......Page 742 References......Page 743 Introduction......Page 748 Acoustic Cavitation......Page 749 Microjet Formation During Cavitation at Liquid-Solid Interfaces......Page 750 Spectroscopic Probes of Cavitation Conditions......Page 751 Homogeneous Sonochemistry: Bond Breaking and Radical Formation......Page 752 Applications of Sonochemistry to Materials Synthesis......Page 753 Heterogeneous Sonochemistry: Reactions of Solids with Liquids......Page 754 Conclusions......Page 755 References......Page 756 Mechanisms of Microwave Heating in Condensed Matter......Page 757 Comparison of Microwave and Conventional Heating......Page 758 Microwave Applicators......Page 759 Conclusions......Page 760 References......Page 761 Types of Self-Assembly and their Utility in Designed Synthesis......Page 762 Thermodynamic Self-Assembly......Page 763 Mismatching Ligand and Metal Preferences......Page 764 Entropy-driven Self-assembly......Page 765 Self-assembly Involving Geometric Complementarity......Page 766 Stoichiometry-driven Self-assembly......Page 767 "Rings-and-strings" Self-assembly......Page 769 Multiple-interaction Self-assembly......Page 772 References......Page 773 Basic Principles......Page 775 Reference Electrode......Page 776 Electrolytes......Page 777 Electrocrystallization Conditions......Page 778 Additional Parameters......Page 780 Electrolysis at Sacrificial Electrodes......Page 781 Organometallic complexes......Page 782 Electrochemical oxidation of a complex......Page 783 Concomitant formation of complex and material......Page 784 Dedication......Page 785 References......Page 786 Introduction......Page 788 Multi-electron Transfer and Noninnocent Ligands......Page 790 ECE Reactions and Catalysis......Page 792 Dimers and Higher Nuclearity Complexes......Page 793 Porphyrins, Phthalocyanines, and Macrocyclic Complexes......Page 794 Raman Spectroelectrochemistry......Page 795 Carbonyls......Page 796 Non-carbonyl Ligands with Multiple Bonds: Nitrosyls, Cyanides, Nitriles, Isonitriles, Thiocyanates......Page 797 Epr Spectroelectrochemistry......Page 798 References......Page 799 Introduction......Page 803 Methods for Introduction and Replacement of Metal Ligands in Proteins......Page 804 Identification of Protein-derived Metal Ligands in the Absence of Structural Information......Page 807 Residues in the second coordination shell......Page 808 Trans-substitution as a Means to Modify Ligand Chemistry......Page 809 Identification of Protein Ligands in the Absence of Structure Using trans-Substitution......Page 810 Structure-Energy-Function Studies of Known Ligands using trans-Substitution......Page 812 Mimicking Naturally Occurring Metal Sites......Page 814 Glossary......Page 815 References......Page 816 Appendix to Volume 1......Page 819 V. 1. Fundamentals : Ligands, Complexes, Synthesis, Purification, And Structure -- V. 2. Fundamentals : Physical Methods, Theoretical Analysis, And Case Studies -- V. 3. Coordination Chemistry Of The S, P, And F Metals -- V. 4. Transition Metal Groups 3-6 -- V. 5. Transition Metal Groups 7 And 8 -- V. 6. Transition Metal Groups 9-12 -- V. 7. From The Molecular To The Nanoscale : Synthesis, Structure, And Properties -- V. 8. Bio-coordination Chemistry -- V. 9. Applications Of Coordination Chemistry -- V. 10. Cumulative Subject Index. Editors-in-chief, Jon A. Mccleverty, Thomas J. Meyer. Includes Bibliographical References And Indexes.