Comprehensive Coordination Chemistry II - From Biology to Nanotechnology 2 ed. in 10 Vol.Set Volume 09 - Applications of Coordination Chemistry

McCleverty J.A. (ed.) Comprehensive Coordination Chemistry II - From Biology to Nanotechnology 2 ed. in 10 Vol.Set Volume 09 - Applications of Coordination Chemistry 2003 [pdf 1062sc 1063+1c. 10.85mb]Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest. Cover Page......Page 1 Introduction to Volume 9......Page 2 COMPREHENSIVE COORDINATION CHEMISTRY II......Page 4 Volumes......Page 5 Info on Volume 9......Page 6 9.1 Metal Complexes as Catalysts for Polymerization Reactions......Page 8 Introduction......Page 9 Isospecific propylene polymerization......Page 10 Elastomeric poly(propylene)......Page 12 Constrained geometry catalysts......Page 13 Nitrogen-based ligands......Page 14 Oxygen based ligands......Page 17 Group 3 and rare earth metal catalysts......Page 18 Group 5 metal catalysts......Page 19 Nitrogen- and oxygen-based ligands......Page 20 Group 8 metal catalysts......Page 21 Group 10 metal catalysts......Page 22 Main group metal catalysts......Page 24 Coordinative Polymerization of Styrenes......Page 25 Atom Transfer Radical Polymerization of Styrenes......Page 27 Anionic Initiators of the group 1, 2, and 3 Metals......Page 30 Well-defined Magnesium and Aluminum Initiators......Page 31 Lanthanide Initiators......Page 33 Early Transition Metal Initiators......Page 34 Titanacyclobutanes......Page 36 Group 6 Metal Initiators......Page 37 Ruthenium Initiators......Page 40 Introduction......Page 43 Aluminum-based Initiators......Page 44 Magnesium and Zinc Initiators......Page 49 Calcium Initiators......Page 50 Tin Initiators......Page 51 iron Initiators......Page 52 Yttrium and Rare-earth Initiators......Page 53 Titanium and Zirconium Initiators......Page 58 Tetraphenylporphyrin Aluminum and Zinc Initiators......Page 59 Copolymerization of Epoxides and Aziridines with Carbon Monoxide......Page 61 Copolymerization of Epoxides and Aziridines with Carbon Monoxide......Page 64 Polymerization of Isocyanates and Guanidines......Page 65 References......Page 66 Introduction......Page 82 Homogeneous Hydrogenation......Page 83 Metal Monohydride Mechanism......Page 84 Metal Dihydride Mechanism......Page 87 Asymmetric Hydrogenation Mechanisms......Page 89 Homogeneous Transfer Hydrogenation......Page 99 Metal Monohydride Mechanism......Page 100 Metal-Ligand Bifunctional Concerted Mechanism......Page 102 Mechanism of Aerobic Alcohol Oxidation......Page 103 Homogeneous Hydrogenolysis......Page 105 Hydrodesulfurization......Page 106 Hydrodenitrogenation......Page 112 Hydrogenation in Aqueous Systems......Page 117 Water-soluble hydrogenation catalysts......Page 118 Immobilization on solids......Page 121 Immobilization via biphasic catalysis......Page 124 Microheterogenization on organized amphiphiles in the colloidal or nanoscale dimension......Page 125 Enantioselective hydrogenation in aqueous systems......Page 127 Hydrogenations with CO/H2O mixtures......Page 128 Hydrogenation in Supercritical Carbon Dioxide......Page 129 Hydrogenation by Cluster Catalysis......Page 132 Hydrogenation In Biological Systems......Page 136 References......Page 140 9.3 Metal Complexes as Catalysts for Addition of Carbon Monoxide......Page 147 Rhodium Catalysts......Page 148 Immobilization studies (see also Chapter 9.9)......Page 152 Palladium and Nickel Catalysts......Page 153 Reductive carbonylation......Page 154 Studies on the mechanism of catalytic hydroformylation......Page 155 Cis-PtCl2(diphosphine)/SnCl2 systems......Page 157 Miscellaneous......Page 158 Palladium......Page 159 Cobalt......Page 160 Introduction to phosphine catalysts......Page 161 Introduction to phosphite catalysts......Page 164 Chiral diphosphine ligands......Page 172 Diphosphite ligands......Page 175 Miscellaneous......Page 176 Diphosphines as chiral ligands......Page 177 Diphosphite ligands......Page 178 Phosphine-phosphite ligands......Page 180 Two-phase catalysis......Page 182 Palladium-Catalyzed Alternating Copolymerization of Alkenes And Carbon Monoxide......Page 185 Introduction......Page 190 Palladium catalysts......Page 191 Amidocarbonylation......Page 192 Cobalt catalysts......Page 193 Hydroxycarbonylation......Page 194 Palladium/Phosphorus Complexes in Hydroxycarbonylation......Page 195 Palladium Species Involved in the Hydroxycarbonylation Reaction......Page 196 Methoxycarbonylation......Page 197 Mechanistic studies......Page 198 Phosphorus ligands in Pd methoxycarbonylation......Page 199 References......Page 200 Introduction......Page 213 Epoxidation of Allylic Alcohols......Page 214 Epoxidation using metalloporphyrin as catalysts......Page 217 Epoxidation using metallosalen complexes as catalysts......Page 222 Epoxidation of Electron-deficient Olefins......Page 229 Oxidation of Enol Ethers and their Derivatives......Page 231 Asymmetric Aziridination......Page 233 General Features of Asymmetric Dihydroxylation......Page 237 Mechanistic Considerations......Page 241 Iron-mediated Dihydroxylation......Page 244 Asymmetric Aminohydroxylation......Page 245 Cu-catalyzed cyclopropanation......Page 249 Rh-catalyzed cyclopropanation......Page 251 Ru-catalyzed cyclopropanation......Page 254 Co-catalyzed cyclopropanation......Page 256 Cu-catalyzed cyclopropanation......Page 257 Rh-catalyzed cyclopropanation......Page 258 Ru-catalyzed cyclopropanation......Page 259 Co-catalyzed cyclopropanation......Page 260 Mechanism of Cyclopropanation......Page 261 Conclusion......Page 264 References......Page 265 Introduction......Page 271 Developments Since CCC (1987)......Page 272 Ligand Effects in Rhodium-catalyzed Hydroboration of Vinylarenes......Page 275 Hydroboration of Substrates Containing C=C Bonds: Enynes and Alkynes......Page 276 Asymmetric Hydroboration......Page 277 Hydrocyanation......Page 281 Reactions of Nonactivated Alkenes......Page 282 Hydrocyanation of Activated Alkenes......Page 283 Developments in Achiral Catalytic Si-H Addition......Page 286 Asymmetric Hydrosilylation......Page 287 Enantioselective Hydrosilylation Employing Chiral Ferrocenyl Phosphine Ligands......Page 291 Intramolecular Asymmetric Hydrosilylation......Page 292 Mechanism and Early Transition Metal/Lanthanide Catalysts......Page 294 Rhodium and Iridium Catalysts......Page 297 Palladium and Platinum Catalysts......Page 300 Hydrophosphination (And Hydrophosphorylation)......Page 302 Hydrophosphination......Page 303 Hydrophosphorylation and Hydrophosphinylation......Page 304 References......Page 307 9.6 Metal Complexes as Catalysts for C-C Cross-coupling Reactions......Page 311 Introduction......Page 312 Major Methods of Cross-Coupling......Page 313 Cross-coupling with Organoboron Compounds......Page 314 Cross-coupling with Organotin Compounds......Page 316 Cross-coupling with Organozinc Reagents......Page 318 Cross-coupling with Organomagnesium and Organolithium Reagents......Page 321 Cross-coupling with Terminal Acetylenes......Page 322 The Development of the Cross-Coupling Methodology......Page 324 Mercury......Page 325 Indium......Page 326 Zirconium......Page 327 CH-nucleophiles......Page 328 Copper......Page 331 Activation of the nucleophilic reagent......Page 333 Compounds with Si-O bonds......Page 337 Tetraorganosilanes......Page 339 Leaving Groups......Page 340 Chlorides......Page 341 Esters as electrophiles in cross-coupling reactions......Page 342 Sulfur derivatives......Page 344 Se and Te derivatives......Page 346 Catalysts......Page 347 Chelating ligands with both phosphine and nonphosphine binding sites......Page 349 Bulky trialkyl- and dialkylphosphines......Page 351 Heterobimetallic complexes......Page 353 Phosphorus ligands other than phosphines......Page 354 Bidentate diphosphine ligands......Page 355 NC and OC-palladacycles......Page 357 Nonphosphorus ligands......Page 358 Heterocyclic carbene ligands......Page 359 Technological Aspects of Cross-coupling Chemistry......Page 362 Pd/C and Ni/C......Page 363 Polymer-immobilized catalysts......Page 364 Supercritical CO2......Page 365 References......Page 366 Introduction......Page 375 Early Examples......Page 377 Amination of aryl halides......Page 378 Amination of aryl triflates......Page 379 Third-generation Catalysts Bearing Alkylmonophosphines......Page 380 Sterically hindered bisphosphine ligands for aminations......Page 381 P,N, P,O, and dialkylphosphinobiaryl ligands......Page 382 Heterocyclic carbenes as ligands......Page 383 Aromatic C-N Bond Formation with Related Substrates......Page 384 Etherification......Page 387 Second-generation Catalysts Containing Sterically Hindered Alkylphosphines......Page 388 Carbon-Sulfur and Carbon-Selenium Bond-Forming Cross-Couplings......Page 390 Coupling of Aryl and Vinyl Halides with Phosphorus(V) Reagents......Page 392 Coupling of Aryl and Vinyl Halides with Phosphorus(V) Reagents......Page 393 Coupling with Silanes, Stannanes, and Germanes......Page 394 Coupling with Boranes......Page 395 Intermediates in the Coupling Chemistry......Page 396 References......Page 400 Alkali Metals......Page 405 Magnesium......Page 407 Scandium and Lanthanides......Page 408 Titanium......Page 411 Zirconium......Page 421 Hafnium......Page 422 Copper......Page 425 Silver and Gold......Page 427 Zinc......Page 428 Other Transition-Metal Lewis Acids......Page 430 Boron......Page 432 Aluminum......Page 435 Silicon......Page 436 Tin......Page 439 Others......Page 441 Conclusion/Classification of Lewis Acids......Page 443 References......Page 445 Introduction......Page 451 Incorporation by ion exchange reactions......Page 452 Incorporation by covalent anchoring......Page 455 Incorporation by ion exchange reactions......Page 456 Incorporating by covalent bonding......Page 457 Inorganic matrices......Page 458 Organic supports......Page 459 Supported Liquid Phase Catalysts (SLPC)......Page 460 Hydrogenation......Page 462 Supported titanium-based catalysts......Page 464 Supported salen-type complexes......Page 467 Heck reaction......Page 469 Trost-Tsuji allylic substitution......Page 471 Polymerization......Page 472 References......Page 473 9.10 Electrochemical Reactions Catalyzed by Transition Metal Complexes......Page 477 Basic Principles......Page 478 Metal Hydride Complexes: Electrogeneration and Electrocatalytic Dihydrogen Evolution......Page 479 Transition metal macrocycles......Page 480 Polypyridyl complexes......Page 481 Miscellaneous complexes......Page 482 Electrocatalytic hydrogenation of organics......Page 483 Electrocatalytic Reduction Of Carbon Dioxide......Page 484 Re(bpy)(CO)3Cl and related complexes......Page 485 [Ru(bpy)2(CO)2]2+ and related complexes......Page 486 Other polypyridyl metal complexes......Page 487 Porphyrin complexes......Page 488 Cyclam and other polyazamacrocyclic complexes......Page 489 Carboxylation of Organic Substrates......Page 490 Reductive homo- and heterocoupling of organic halides......Page 491 Electroreductive coupling of organic halides......Page 492 NiII and CoI Schiff base complexes......Page 493 NiII complexes of cyclams and other tetradentate N-ligands......Page 494 Vitamin B12 derivatives and model complexes......Page 495 Electrocatalytic Conversion of Nitrate to Ammonia......Page 496 Metal complexes of nitrogen macrocycles......Page 497 Electrochemical Sensors for Nitrite and Nitric Oxide Determination......Page 498 Electrocatalytic Four-electron Reduction of Dioxygen......Page 499 Electrocatalytic P-450 Model Systems......Page 501 The Gif-Orsay System......Page 502 Oxidation of Water......Page 503 Oxidation of Organics......Page 504 References......Page 506 Introduction......Page 514 Hydrolysis Reactions......Page 515 Heck Reactions......Page 517 Allylic Substitution......Page 519 Ring-closing Olefin Metathesis......Page 521 Olefin Polymerization......Page 523 Novel Strategies in the Design of Ligand Libraries......Page 527 Enantioselective Processes......Page 528 High-throughput ee-Assays......Page 529 Strategies Used in the Combinatorial Design and Preparation of Enantioselective Transition Metal Catalysts......Page 540 Conclusions and Perspectives......Page 550 References......Page 551 Introduction......Page 554 Nature of Bonding In Metal Complex Azo Colorants......Page 556 Azo/Hydrazone Tautomerism......Page 557 Nature of Azo-to-metal Bonding......Page 558 Lightfastness......Page 560 Color......Page 561 Azo Dyes......Page 562 Azo Pigments......Page 564 Phthalocyanine Dyes and Pigments......Page 565 Formazan Dyes......Page 566 Laser Printing Process......Page 568 Organic Photoconductors......Page 569 Toners......Page 571 Ink Jet Printing......Page 572 Ink Jet Printing Process......Page 573 Ink Jet Dyes and Pigments......Page 574 Infrared Absorbers......Page 577 Dark Oxidation Catalysts......Page 579 Singlet Oxygen Generators......Page 580 Toxicological And Ecotoxicological Considerations......Page 581 References......Page 582 Introduction......Page 585 Classes of Electrochromic Material......Page 586 Polypyridyl complexes in solution......Page 587 Oxidative electropolymerization of polypyridyl complexes......Page 588 Spatial electrochromism of polymeric polypyridyl complexes......Page 589 Sublimed bis(phthalocyaninato) lutetium(III) films......Page 590 Electrochemical routes to metallophthalocyanine electrochromic films......Page 592 Langmuir-Blodgett metallophthalocyanine electrochromic films......Page 593 Electrochromic properties of porphyrins......Page 594 Preparation of Prussian blue thin films......Page 595 Electrochemistry, in situ spectroscopy, and characterization of Prussian blue thin films......Page 596 Prussian blue electrochromic devices......Page 598 Prussian blue analogs......Page 599 Planar dithiolene complexes of Ni, Pd, and Pt......Page 601 Tris(pyrazolyl)borato-molybdenum complexes......Page 602 Ruthenium and osmium dioxolene complexes......Page 605 Read only media......Page 606 Write-once recordable media: CD-R and DVD-R......Page 609 Heat-mode recording......Page 611 Brief history of development of dyes for optical data storage......Page 612 Specific requirements for dyes for optical disk recording......Page 613 Phthalocyanines and related compounds......Page 614 Metal complexes of azo dyes......Page 618 References......Page 619 General Context and Scope of this Review......Page 624 The Origins of NLO Behavior in Molecular Materials......Page 625 Measurement of NLO Properties......Page 626 Why are Metal Complexes of Interest?......Page 629 Complexes of Nonchelating Pyridyl Ligands......Page 630 Complexes of Chelating Pyridyl Ligands......Page 635 Complexes of Porphyrin and Related Ligands......Page 641 Complexes of Phthalocyanine and Naphthalocyanine Ligands......Page 646 Complexes of Schiff Base Ligands......Page 653 Complexes of Thiocyanate Ligands......Page 658 Complexes of 1,2-Dithiolene and Related Ligands......Page 659 Cluster Complexes......Page 662 Miscellaneous Complexes......Page 670 Conclusions......Page 676 References......Page 678 9.15 Metal Compounds as Phosphors......Page 691 History of Phosphors and Past Uses......Page 692 Cathode Ray Tube Displays......Page 693 Electroluminescent Displays......Page 694 Field Emission Displays......Page 698 Phosphor Synthesis......Page 699 Homogeneous precipitation......Page 700 Microemulsion methods......Page 703 Molecular beam epitaxy and its derivatives......Page 704 Ion implantation......Page 705 Group II metal complexes......Page 706 Tris(8-hydroxyquinolato)aluminum and related complexes......Page 707 Lanthanide beta-diketonate complexes......Page 709 Other metal complexes......Page 710 Anti-Stokes Phosphors......Page 711 Quantum Cutters......Page 712 Photonics......Page 713 References......Page 714 9.16 Conversion and Storage of Solar Energy using Dye-sensitized Nanocrystalline TiO2 Cells......Page 720 Overview......Page 721 Operating Principles of the Dye-sensitized Solar Cell......Page 722 Fill Factor......Page 724 Photophysical Properties of Metal Complexes......Page 725 Preparation of Mesoscopic TiO2 Colloids......Page 726 Preparation of Films......Page 727 Requirements of the Sensitizers......Page 728 Spectral Tuning in "Push-Pull" Type Complexes......Page 729 Sensitizers Containing Functionalized Hybrid Tetradentate Ligands......Page 734 Hydrophobic Sensitizers......Page 736 Near IR Sensitizers......Page 738 Phthalocyanines containing 3d metals......Page 739 Surface Chelation......Page 741 X-ray Diffraction, X-ray Photoelectron Spectroscopy, and XAFS Spectroscopy Study......Page 742 ATR-FTIR Studies of Sensitizer Adsorption on TiO2 Oxide Surface......Page 743 Effect of Protons Carried by the Sensitizer on the Performance......Page 744 Comparison of IPCE Values Obtained with Various Sensitizers......Page 745 Electron Injection Kinetics......Page 747 New Redox Couples......Page 748 Solid Electrolytes/Hole-transport Materials......Page 749 Water Splitting by Visible Light using a Tandem cell......Page 750 Synthetic Strategies for Ruthenium Complexes......Page 751 Characterization......Page 753 Acknowledgements......Page 756 References......Page 757 Introduction......Page 760 Mineral Processing......Page 763 Leaching......Page 764 Leaching of Gold and Silver into Basic Media......Page 765 Leaching of Gold and Silver into Acidic Media......Page 766 Leaching of base metals into sulfate media......Page 767 Leaching of base metals into chloride media......Page 768 Separation And Concentration......Page 769 Solvent Extraction Processes......Page 770 Hydroxy-oxime Extractants......Page 771 Carboxylic Acids......Page 773 Amine Salt Extractants......Page 775 Solvating Extractants......Page 776 Extraction of CuII from sulfate solutions......Page 777 Extraction of CuII from chloride solutions......Page 779 Extraction of CuII from ammoniacal solutions......Page 781 Zinc......Page 782 Extraction of ZnII from sulfate media......Page 783 Extraction of ZnII from chloride media......Page 784 Nickel and Cobalt......Page 786 Co/Ni separation in sulfate solutions......Page 787 Co/Ni separation in chloride and ammoniacal solutions......Page 789 Precious Metals......Page 791 AuI, AuIII......Page 792 AgI......Page 794 PtIV, PtII......Page 795 PdII......Page 797 References......Page 798 Introduction......Page 810 Biological Assays......Page 811 Clinically Used Anticancer Agents. Cis-platinum Compounds......Page 813 AMD473 (ZDO-473)......Page 818 JM-216 (Satraplatin)......Page 819 BBR3464. A trinuclear platinum clinical agent......Page 820 Reactions with oligonucleotides......Page 822 Transplatinum compounds......Page 824 Ruthenium Complexes......Page 826 Arsenic Trioxide......Page 827 Manganese-based Superoxide Dismutase Mimics......Page 828 Titanium Compounds......Page 830 Silver and Mercury Salts......Page 831 Metal-containing Drugs as Antiparasitic Agents......Page 832 Lithium Carbonate......Page 833 Gold Compounds as Antiarthritic Agents......Page 834 References......Page 835 Introduction......Page 842 Relaxivity of GdIII Complexes......Page 844 Inner-sphere Proton Relaxivity......Page 846 Water/proton exchange......Page 848 Electron spin relaxation......Page 852 Toxicity of GdIII Complexes: Thermodynamic Stability and Kinetic Intertness......Page 854 Complex Stability Constants......Page 855 Blood Plasma Models......Page 857 Blood Pool Agents......Page 858 Linear polymers......Page 859 Dendrimers......Page 860 Micelles and liposomes......Page 862 Noncovalently Bound Macromolecular Agents......Page 863 pH-sensitive Agents......Page 867 Temperature-sensitive Agents......Page 871 Enzymatically Responsive Contrast Agents......Page 872 Contrast Agents Responsive to Metal Ion Concentration......Page 874 Chemical Exchange Saturation (CEST) Contrast Agents......Page 875 Targeting Contrast Agents......Page 876 References......Page 878 Introduction......Page 883 Diagnostic Imaging......Page 884 Radiotherapy......Page 885 Nuclear and Physical Properties Needed for Imaging and Therapy......Page 886 Copper......Page 887 Radiolanthanides......Page 888 Rhodium......Page 889 Lead and Bismuth......Page 890 Gallium, Indium, and Yttrium......Page 891 Copper......Page 894 Radiolanthanides......Page 897 Gold......Page 902 Thallium......Page 903 Actinium......Page 904 Bismuth and Lead......Page 905 References......Page 906 Introduction and Scope......Page 912 Organic Molecules as Luminescent Probes for Metal Ions......Page 913 Lanthanide Complexes as Probes: Basic Photophysical Properties......Page 916 Long-lived Luminescence and Time-gating......Page 917 Sensitization of Luminescence: Energy Transfer......Page 918 Triplet-mediated energy transfer......Page 920 Energy transfer mediated by LMCT......Page 921 Solvent Effects on Lanthanide Luminescence......Page 922 Long-wavelength Sensitization and Near-IR Luminescence......Page 923 Background......Page 926 The DELFIA Assay......Page 929 The CYBERFLUOR Assay......Page 930 Homogeneous Assays: DEFRET......Page 933 Assays with Near-IR Luminescent Lanthanides......Page 934 Lanthanide Complexes for Imaging......Page 935 Responsive Lanthanide Complexes as Sensors......Page 938 References......Page 940 9.22 Metal Complexes for Photodynamic Therapy......Page 944 Introduction......Page 945 Mechanistic Aspects......Page 946 Design Features for a Good Photosensitizer for PDT......Page 949 Photosensitizers in Clinical Use......Page 952 Metalation of the preformed ligand......Page 954 Metal Complex Stability......Page 955 Solubility......Page 958 Disaggregation......Page 959 Spectroscopic Properties......Page 960 Redox Properties......Page 963 Drug Delivery Systems......Page 965 Magnesium......Page 966 Lanthanides......Page 969 Ruthenium......Page 971 Nickel......Page 972 Palladium......Page 974 Copper......Page 976 Porphyrin complexes......Page 978 Zinc chlorins and bacteriochlorins......Page 979 Zinc phthalocyanines......Page 980 Zinc naphthalocyanines......Page 983 Cadmium......Page 984 Boron......Page 985 Aluminum......Page 986 Gallium......Page 989 Silicon......Page 990 Germanium......Page 991 Tin......Page 992 Conclusions......Page 993 References......Page 994 9.23 Coordination Complexes as Precursors for Semiconductor Films and Nanoparticles......Page 1003 Compound Semiconductors......Page 1004 Thin Films from Vapor-phase Deposition Techniques......Page 1006 New Delivery Approaches......Page 1009 Coordination Chemistry Methods Used for Purification of Metal Alkyl Precursors: "Adduct Purification"......Page 1010 Purification of Group 12 Metal Alkyls......Page 1013 Purification of Group 13 Metal Alkyls......Page 1015 Modified Adduct Purification Techniques......Page 1017 Precursors for Fabrication of II-VI Thin Films......Page 1018 Precursors for Fabrication of III-V Thin Films......Page 1019 Aluminum Compounds......Page 1020 Gallium Compounds......Page 1021 Indium Compounds......Page 1022 Nitrogen Compounds......Page 1024 Arsenic Compounds......Page 1025 Dialkyldichalcogenocarbamato compounds......Page 1027 Lewis base adducts of bis(dialkyldithiocarbamato) compounds......Page 1029 Mixed alkyl/dichalcogenocarbamate complexes......Page 1030 Monothiocarbamate and monothiocarboxylate compounds......Page 1031 Chalcogenide-based compounds with high volatility......Page 1032 Single-molecule Precursors for III-V Compounds......Page 1035 Monomeric precursor compounds......Page 1037 Nitride Films from Single-molecule Precursors......Page 1038 Group 13 azides as single-molecule precursors for nitrides......Page 1039 III-VI Materials from Single-molecule Precursors......Page 1042 CuInS2 and Related Ternary Semiconductors......Page 1045 Semiconductor Nanoparticles "Quantum Dots"......Page 1046 Methods of Preparation of Semiconductor Nanoparticles......Page 1047 II-VI particles......Page 1049 III-V particles......Page 1051 References......Page 1054 9.24 Appendix to Volume 9......Page 1062 V. 1. Fundamentals : Ligands, Complexes, Synthesis, Purification, And Structure -- V. 2. Fundamentals : Physical Methods, Theoretical Analysis, And Case Studies -- V. 3. Coordination Chemistry Of The S, P, And F Metals -- V. 4. Transition Metal Groups 3-6 -- V. 5. Transition Metal Groups 7 And 8 -- V. 6. Transition Metal Groups 9-12 -- V. 7. From The Molecular To The Nanoscale : Synthesis, Structure, And Properties -- V. 8. Bio-coordination Chemistry -- V. 9. Applications Of Coordination Chemistry -- V. 10. Cumulative Subject Index. Editors-in-chief, Jon A. Mccleverty, Thomas J. Meyer. Includes Bibliographical References And Indexes.