Chiral Reagents for Asymmetric Synthesis [Handbook of Reagents for Organic Synthesis]

Cover......Page 1 Front Matter......Page 2 Preface......Page 5 Introduction......Page 6 General Abbreviations......Page 7 Table of Contents......Page 9 Recent Review Articles and Monographs......Page 17 Organic Synthesis Procedures Featuring Chiral, Non-Racemic Reagent Preparation, Volumes 68-78......Page 23 3.1 (S)-Aceto(carbonyl)(cyclopentadienyl)-(triphenylphosphine)iron......Page 37 3.2 Allylcyclopentadienyl[(4R,trans)- and (4S,trans)-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato-O,O']titanium.........Page 39 3.3 B-Allyldiisocaranylborane......Page 42 3.4 (1R,2S)-1-Amino-2,3-dihydro-1H-inden-2-ol......Page 43 3.5 (S)-1-Amino-2-hydroxymethylindoline......Page 46 3.6 (S)-1-Amino-2-methoxymethylpyrrolidine......Page 48 3.7 2-Amino-3-methyl-1,1-diphenyl-1-butanol......Page 52 3.8 3-Amino-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol......Page 54 3.9 (S)-4-Anilino-3-methylamino-1-butanol......Page 56 3.10 (S)-2-(Anilinomethyl)pyrrolidine......Page 57 3.11 L-Aspartic Acid......Page 58 3.12 2-Azabicyclo[2.2.1]hept-5-en-3-one......Page 60 4.1 Baker's Yeast......Page 61 4.2 (1R,5R)-2H-1,5-Benzodithiepin-3(4H)-one 1,5-Dioxide......Page 64 4.3 1-Benzoyl-2-t-butyl-3,5-dimethyl-4-imidazolidinone......Page 66 4.4 (2S,4S)-3-Benzoyl-2-t-butyl-4-methyl-1,3-oxazolidin-5-one......Page 67 4.5 1-Benzoyl-2(S)-tert-butyl-3-methylperhydropyrimidin-4-one......Page 69 4.6 Benzyl(methoxymethyl)methylamine......Page 72 4.7 (S)-4-Benzyl-2-oxazolidinone......Page 73 4.8 N-Benzyloxycarbonyl-L-serine beta-Lactone......Page 84 4.9 2-[2-[(Benzyloxy)ethyl]-6,6-dimethylbicyclo[3.3.1]-3-nonyl]-9-borabicyclo[3.3.1]nonane......Page 86 4.10 (R,R)-1-(2'-Benzyloxymethylphenyl)-2,5-dimethylphospholane......Page 87 4.11 N-Benzylquininium Chloride......Page 88 4.12 (S)-4-Benzyl-2,2,5,5-tetramethyloxazolidine......Page 89 4.13 (Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium Perchlorate......Page 90 4.14 (Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I)Tetrafluoroborate......Page 92 4.15 (1R,1'R,2R,2'R)-[1,1'-Bicyclopentyl-2,2'-diylbisdiphenylphosphine]......Page 97 4.16 1,1'-Binaphthalene-2,2'-dithiol......Page 99 4.17 (R)-1,1'-Bi-2,2'-naphthol......Page 102 4.18 (R)-1,1'-Bi-2,2'-naphthotitanium Dichloride......Page 107 4.19 (R)-1,1'-Bi-2,2'-naphthotitanium Diisopropoxide......Page 110 4.20 (S)-2,2'Binaphthoyl(R,R)-di(1-phenylethyl)aminoylphosphine......Page 111 4.21 1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate......Page 113 4.22 Bis(alpha-camphorquinone dioximato)cobalt......Page 114 4.23 (R,R)-1,2-Bis(aminocarbonylphenyl-2'-diphenylphosphino)cyclohexane......Page 115 4.24 Bis(bicyclo[2.2.1]hepta-2,5-diene)-rhodium Perchlorate-(R)-1-(S)-1',2-Bis(diphenylphosphino)ferrocenylethanol......Page 120 4.25 (1S,9S)-1,9-Bis{[(t-butyl)dimethylsilyloxy]methyl}-5-cyanosemicorrin......Page 121 4.26 (R,R)-Bis(tert-butylmethylphosphino)methane......Page 123 4.27 2,2-Bis{[2-[4(S)-tert-butyl-1,3-oxazolinyl]}propane......Page 124 4.28 Bis(cyclohexyl isocyanide)gold(I) Tetrafluoroborate-(R)-N-[2-(N,N-Dimethylamino)ethyl]-N-methyl-1-(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine......Page 131 4.29 Bis(1,5-cyclooctadiene)rhodium Tetrafluoroborate-(R)-2,2'Bis(diphenylphosphino)-1,1'-binaphthyl......Page 134 4.30 (S,S)-1,2-Bis(2,5-diethylphospholano)benzene......Page 135 4.31 1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene (S,S)-Me-DuPhos, 1,2-Bis((2R,5R)2,5-dimethylphospholano)benzene (R,R)-Me-DuPhos......Page 139 4.32 [Bis(4R,5S)-4,5-diphenyl-1,3-oxazolin-2-yl]methane [Bis(4S,5R)-4,5-diphenyl-1,3-oxazolin-2-yl]methane......Page 142 4.33 (R)- & (S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl......Page 144 4.34 (2R,3R)-2,3-Bis(diphenylphosphino)butane......Page 148 4.35 (R)-7,7'-Bis(diphenylphosphinomethyl)-2,2'-dimethoxy-1,1'-binaphthyl......Page 149 4.36 (eta5,eta5-1S,2R,4S,5R-1,4-Bis(indenyl)-2,5-diisopropylcyclohexane)titanium Dichloride......Page 150 4.37 2,6-Bis[(4S)-4-isopropyloxazolin-2-yl]pyridine......Page 151 4.38 2,6-Bis[(S)-4'-isopropyloxazolin-2'-yl](pyridine)rhodium Trichloride......Page 152 4.39 trans-2,5-Bis(methoxymethyl)pyrrolidine......Page 154 4.40 Bis[(4S)-(1-methylethyl)oxazolin-2-yl]methane......Page 156 4.41 (R)-3,3'-Bis(triphenylsilyl)binaphthomethylaluminum......Page 160 4.42 (-)-endo-Bornyltriazolinedione......Page 161 4.43 (4R,5R)-2-Bromo-1,3-bis[(4-methylphenyl)sulfonyl]-4,5-diphenyl-1,3,2-diazaborolidine......Page 163 4.44 3-Bromocamphor-8-sulfonic Acid......Page 167 4.45 3-Bromo-5,6-diphenyl-2,3,5,6-tetrahydro-4H-oxazin-2-one......Page 168 4.46 Brucine......Page 171 4.47 4-t-Butoxycarbonyl-5,6-diphenyl-2,3,5,6-tetrahydro-4H-oxazin-2-one......Page 174 4.48 (R,R)-2-Butyl-4,5-bis(dimethylaminocarbonyl)-1,3-dioxaborolane......Page 175 4.49 t-Butyl 2-t-Butyl-3-methyl-4-oxo-1-imidazolidinecarboxylate......Page 178 4.50 (R)-2-t-Butyl-6-methyl-4H-1,3-dioxin-4-one......Page 180 4.51 (R,R)-2-t-Butyl-5-methyl-1,3-dioxolan-4-one......Page 182 4.52 (R)-(+)-t-Butyl 2-(p-Tolylsulfinyl)acetate......Page 184 4.53 (R)-(+)-t-Butyl 2-(p-Tolylsulfinyl)propionate......Page 185 5.1 (-)-(1S,4R)-Camphanic Acid......Page 187 5.2 10-Camphorsulfonic Acid......Page 188 5.3 10-Camphorsulfonyl Chloride......Page 192 5.4 10,2-Camphorsultam......Page 194 5.5 (Camphorylsulfonyl)oxaziridine......Page 200 5.6 (R,S)-CAMPHOS......Page 204 5.7 Chloro(cyclopentadienyl)bis[3-O-(1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranosyl)]titanium......Page 205 5.8 Chloro(eta5-cyclopentadienyl)[(4R,trans)-2,2-dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato(2-)-Oalpha,Oalpha']titanium......Page 207 5.9 (+)-B-Chlorodiisopinocampheylborane......Page 209 5.10 N,N'-(1R,2R)-1,2-Cyclohexanediylbis-2-pyridinecarboxamide......Page 210 5.11 (R)-(+)-Cyclohexyl(2-anisyl)methylphosphine......Page 212 5.13 (1,5-Cyclooctadiene)[(3R,4R)-3,4-bis(diphenylphosphino)-1-methylpyrrolidine]rhodium Tetrafluoroborate......Page 213 5.14 Cyclopentadienyl(3,5-dimethoxybenzyl)(nitrosyl)(triphenylphosphine)rhenium......Page 214 5.15 (2R,3R)-(Z)-cyclo-Phenylalanine......Page 216 6.1 (1S,2S)-1,2-Diaminocyclohexane......Page 218 6.2 (R,R)-1,2-Diamino-1,2-di-tert-butylethane......Page 224 6.3 Dibornacyclopentadienyltrichlorozirconium......Page 225 6.4 (R)-2,10-Dichloro-5H-dinaphtho[2,1-g:1,2-i][1,5]dioxacycloundecin-3,6,9(7H)-trione......Page 226 6.5 (-)-Dichloro(ethylene)(alpha-methylbenzylamine)platinum(II)......Page 228 6.6 Dichloro[2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane]palladium(II)......Page 229 6.7 10-Dicyclohexylsulfonamidoisoborneol......Page 230 6.8 Dihydro-5-(hydroxymethyl)-2(3H)-furanone......Page 232 6.9 (2S)-(+)-2,5-Dihydro-2-isopropyl-3,6-dimethoxypyrazine......Page 235 6.10 Dihydroquinidine Acetate......Page 237 6.11 Dihydroquinine Acetate......Page 240 6.12 Diisopinocamphenylborane......Page 241 6.13 Diisopinocampheylboron Trifluoromethanesulfonate......Page 244 6.14 (R*,R*)-alpha-(2,6-Diisopropoxybenzoyloxy)-5-oxo-1,3,2-dioxaborolane-4-acetic Acid......Page 246 6.15 Diisopropyl 2-Allyl-1,3,2-dioxaborolane-4,5-dicarboxylate......Page 248 6.16 Diisopropyl 2-Crotyl-1,3,2-dioxaborolane-4,5-dicarboxylate......Page 250 6.17 9-O-(1,2;5,6-Di-O-isopropylidene-alpha-D-glucofuranosyl)-9-boratabicyclo[3.3.1]-nonane, Potassium Salt......Page 252 6.18 Dilongifolylborane......Page 253 6.19 (R)-2-[1-(Dimethylamino)ethyl]benzenethiol......Page 254 6.20 (R)-N-[2-(N,N-Dimethylamino)ethyl]-N-methyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine......Page 256 6.21 (1R,2S,3R,4S)-3-Dimethylamino-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol[(-)DAIB]......Page 259 6.22 (4R,5R)-2,2-Dimethyl-4,5-bis(hydroxydiphenylmethyl)-1,3-dioxolane-Titanium(IV) Chloride......Page 261 6.23 (R,R)-2,5-Dimethylborolane......Page 265 6.24 (S)-N,N-Dimethyl-N'-(1-t-butoxy-3-methyl-2-butyl)formamidine......Page 267 6.25 (-)-(S,S)-alpha,alpha'-Dimethyldibenzylamine......Page 268 6.26 (4S)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde......Page 271 6.27 (4R)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde......Page 274 6.28 (R)-N,N-Dimethyl-1-[(S)-2(diphenylphosphino)ferrocenyl]ethylamine......Page 280 6.29 2-[(4S)-4-(1,1-Dimethylethyl)-4,5-dihydro-2-oxazolyl]-6-methylpyridine......Page 281 6.30 (4S)-4-(1,1-Dimethylethyl)-2-{1-[(11bS)-dinaphtho[2,1-d:1',2'-f]-[1,3,2]dioxaphosphepin-4-yloxy]-1-methylethyl}-4,5-dihydrooxazole......Page 282 6.31 Dimethyl L-Tartrate......Page 284 6.32 (S,S)-2,2'-(Dimethylmethylene)bis(4-t-butyl-2-oxazoline)......Page 285 6.33 [4S-(4alpha,5beta)]-1-(1,3-Dimethyl-2-oxido-4,5-diphenyl-1,3,2-diazaphospholidine-2-yl)piperidine......Page 289 6.34 cis-3-[N-(3,5-Dimethylphenyl)benzenesulfonamido]borneol......Page 294 6.35 (S)-(+)-5,5-Dimethyl-4-phenyl-2-oxazolidinone......Page 295 6.36 (1R,2S,4R,5S)-2,5-Dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]heptane......Page 298 6.37 N,S-Dimethyl-S-phenylsulfoximine......Page 299 6.38 (S)-(-)-N-[(2,2')-Dimethylpropionyl]-2-[(diphenyphosphino)methyl]pyrrolidine......Page 300 6.39 trans-2,5-Dimethylpyrrolidine......Page 302 6.40 2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolatotitanium Diisopropoxide......Page 305 6.41 S,S-Dimethyl-N-(p-toluenesulfonyl)sulfilimine......Page 309 6.42 S,S-Dimethyl-N-(p-toluenesulfonyl)sulfoximine......Page 310 6.43 Di-(-)-(1R,2S)-2-phenyl-1-cyclohexyl Diazenedicarboxylate......Page 311 6.44 (R)-(-)-2,2-Diphenylcyclopentanol......Page 313 6.45 (R,R)-1,2-Diphenyl-1,2-diaminoethane N,N'-Bis[3,5-bis(trifluoromethyl)benzenesulfonamide]......Page 316 6.46 (R,R)-1,2-Diphenyl-1,2-[di(pentafluorophenyl)phosphanoxy]ethane......Page 318 6.47 (S,S)-1,2-Diphenylethylenediamine......Page 320 6.48 (S)-Diphenyl(1-methylpyrrolidin-2-yl)methanol......Page 324 6.49 2'-(Diphenylphosphino)-N,N-dimethyl-[1,1'-binaphthalen]-2-amine......Page 326 6.50 (S)-2-[2-(Diphenylphosphino)phenyl]-4-phenyloxazoline......Page 327 6.51 alpha,alpha-Diphenyl-2-pyrrolidinemethanol......Page 329 6.52 (S)-3,3-Diphenyl-1-[trimethylsilylmethyl]tetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole......Page 332 6.53 (2R,3R)-Dipivaloyltartaric Acid......Page 333 6.54 Dirhodium(II) Tetrakis(methyl 2-pyrrolidone-5(S)carboxylate)......Page 336 7.1 (1R,2S)-Ephedrine......Page 339 7.2 Ephedrine-borane......Page 342 7.3 Epichlorohydrin......Page 344 7.4 Esterases......Page 346 7.5 (R,R)-[Ethylene-1,2-bis(eta5-4,5,6,7-tetrahydro-1-indenyl)]titanium (R)-1,1'-Bi-2,2'-naphtholate......Page 349 7.6 (-)-[Ethylene-1,2-bis(eta5-4,5,6,7-tetrahydro-1-indenyl)]zirconium (R)-1,1'-Bi-2,2'-naphtholate......Page 350 7.7 (S)-Ethyl Lactate......Page 351 7.8 (3aR,7aR)-2-Ethyloctahydro-1H-1,3-dineopentyl-1,3,2-benzodiazaphosphole Oxide......Page 354 8.1 (+)-N-Fluoro-2,10-(3,3-dichlorocamphorsultam)......Page 359 9.1 Glycidol......Page 361 9.2 Glycidyl Tosylate......Page 365 9.3 N-Glyoxyloyl-(2R)-bornane-10,2-sultam......Page 368 10.1 (2S)-(2alpha,3beta,8abeta)-Hexahydro-3-(hydroxymethyl)-8a-methyl-2-phenyl-5H-oxazolo[3,2-a]pyridin-5-one......Page 369 10.2 (4aR)-(4aalpha,7alpha,8abeta)-Hexahydro-4,4,7-trimethyl-4H-1,3-benzoxathiin......Page 370 10.3 (S)-(2-Hydroxy-N,N-dimethylpropanamide-O,O')oxodiperoxymolybdenum(VI)......Page 372 10.4 3-Hydroxyisoborneol......Page 373 10.5 (S)-3-Hydroxy-5-methyl-2,4-imidazolidinedione......Page 376 10.6 (2S,2'S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine......Page 377 10.7 (1S,2S,5S)-2-Hydroxypinan-3-one......Page 378 10.8 2-Hydroxy-1,2,2-triphenylethyl Acetate......Page 379 10.9 (R)-2-Hydroxy-2'-methoxy-1,1'-binaphthyl......Page 381 11.1 (2,3-O-Isopropylidene)-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane......Page 387 12.1 Lanthanum(III)-Lithium-BINOL Complex [(R)-LLB and (S)-LLB]......Page 389 12.2 t-Leucine t-Butyl Ester......Page 391 12.3 Lipases......Page 393 12.4 (1R,2S)-1-Lithio-1-phenylsulfonyl-2-{[(tert-butyldiphenyl)silyl]oxymethyl} Oxirane......Page 398 12.5 Lithium Aluminum Hydride-2,2'-Dihydroxy-1,1'-binaphthyl......Page 401 13.1 (-)-(1R,2S,5R)-Menthyl (S)-p-Toluenesulfinate......Page 406 13.2 (R,S,R,S)-Me-PennPhos......Page 409 13.3 (R,R)-1,2-(Methanesulfonamido)cyclohexane......Page 411 13.5 (R)-N-[2-(2-Methoxyethoxy)-ethyl]-alpha-phenyl-1-piperidineethanamine......Page 414 13.6 (4S,5S)-4-Methoxymethyl-2-methyl-5-phenyl-2-oxazoline......Page 415 13.7 (S)-2-Methoxymethylpyrrolidine......Page 417 13.8 (S)-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetic Acid......Page 419 13.9 (S)-alpha-Methylbenzylamine......Page 422 13.10 (R)-Methyl 2-t-Butyl-3(2H)-oxazolecarboxylate......Page 426 13.11 (R)-4-Methylcyclohexylidenemethylcopper......Page 427 13.12 (S)-1-Methyl-2-[(dihydroisoindol-2-yl)methyl]pyrrolidine......Page 428 13.13 Methyl (4R,5R)-(E)-3-(1,3-Dimethyl-4,5-diphenyl-2-imidazolidinyl)propenoate......Page 429 13.14 (1R,2S)-N-Methylephedrine......Page 430 13.15 [2,2'-(1-Methylethylidene) [(4S)-4-(1,1-dimethylethyl)-4,5-dihydrooxazole-N3]copper(2+)bis[hexafluorophosphate]; bis(triflate)......Page 435 13.16 (R)-(-)-2-(-1-Methylhydrazino)-butan-1-ol......Page 439 13.17 2-(S)-[(Ar)sulfinyl]-2-cyclopenten-1-one (Ar = 4-Methylphenyl; 4-Methoxyphenyl; 1-naphthyl; 2,4,6-trimethylphenyl; 2,4,6-triisopropylphenyl)......Page 441 13.18 (S)-1-Methyl-2-(piperidinomethyl)-pyrrolidine......Page 444 13.19 beta-Methyl-beta-propiolactone......Page 449 13.20 (S)-(-)-4-(2-Methylpropyl)-2-(2-pyridyl)-2-oxazoline......Page 451 13.21 (+)-(S)-N-Methylsulfonylphenylalanyl Chloride......Page 452 13.22 alpha-Methyltoluene-2,alpha-sultam......Page 453 13.23 (R)-(+)-Methyl p-Tolyl Sulfoxide......Page 455 13.24 (R)-B-Methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine......Page 459 13.25 Monoisopinocampheylborane......Page 461 14.1 [(R)-alpha-(2-Naphthyl)aminomethyl]ferrocene......Page 464 14.2 1-(1-Naphthyl)ethylamine......Page 466 14.3 (R)-1-(1-Naphthyl)ethyl Isocyanate......Page 468 14.4 Norephedrine-Borane......Page 470 14.5 (R,R)-(-)-NORPHOS, (S,S)-(+)-NORPHOS......Page 471 15.1 [(2S)-(2alpha,3aalpha,4alpha,7alpha,7aalpha]-2,3,3a,4,5,6,7,7a-Octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-ol......Page 478 15.2 S-(1-Oxido-2-pyridinyl)-1,1,3,3-tetramethylthiouronium Hexafluorophosphate (HOTT)......Page 479 16.1 (R)-Pantolactone......Page 482 16.2 (2R,4R)-2,4-Pentanediol......Page 484 16.3 N-Phenylcampholylhydroxamic Acid......Page 485 16.4 (S)-(-)-5-(alpha-Phenylethyl)semioxamazide......Page 486 16.5 (-)-8-Phenylmenthol......Page 487 16.6 8-Phenylmenthyl Acrylate......Page 488 16.7 8-Phenylmenthyl Crotonate......Page 489 16.8 8-Phenylmenthyl Glyoxylate......Page 490 16.9 8-Phenylmenthyl Pyruvate......Page 491 16.10 (S)-(+)-1-Phenyl-2-propylamine......Page 492 16.11 (R)-(+)-Phenyl (p-Toluenesulfinyl)acetate......Page 493 16.12 B-3-Pinanyl-9-borabicyclo[3.3.1]nonane......Page 494 16.13 (S)-Proline......Page 495 16.14 N-Propenoyl Camphor-10,2-sultam......Page 500 16.15 Pseudoephedrine......Page 501 16.16 (1R,2S)-N-Pyrrolidinylnorephedrine......Page 512 17.1 Quinine......Page 514 18.1 Sodium Hypochlorite-N,N'-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride......Page 517 18.2 (-)-Sparteine......Page 518 18.3 (1R,5R,6R)-Spiro[4.4]nonane-1,6-diyl Diphenylphosphinous acid Ester (R-SpirOP)......Page 520 19.1 (3S,cis)-Tetrahydro-3-isopropyl-7a-methylpyrrolol[2,1-b]oxazol-5(6H)-one......Page 523 19.2 Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole......Page 525 19.3 (S)-(+)-2-(2,4,5,7-Tetranitro-9-fluorenylideneaminooxy)propionic Acid......Page 529 19.4 (R)-(+)-p-Tolylsulfinylacetic Acid......Page 530 19.5 (R)-(+)-alpha-(p-Tolylsulfinyl)-N,N-dimethylacetamide......Page 531 19.6 (3R)-(p-Tolylsulfinyl)-N-methoxyacetimidic Acid Ethyl Ester......Page 532 19.7 (R)-(+)-3-(p-Tolylsulfinyl)propionic Acid......Page 533 19.8 N-[4-(Trifluoromethyl)benzyl]-cinchoninium Bromide......Page 534 19.9 N,N,N'-Trimethyl-N'-(2-{[(1R)-1-phenyl-2-(1-piperidinyl)ethyl]amino}ethyl)-1,2-ethanediamine......Page 535 19.10 1,1,2-Triphenyl-1,2-ethanediol......Page 539 19.11 Tris(acetylacetonato)cobalt-Diethylaluminum Chloride-NORPHOS......Page 540 19.12 L-Tyrosine Hydrazide......Page 541 20.1 Vitamin B12......Page 543 List of Contributors......Page 547 Reagent Formula Index......Page 563 A......Page 571 B......Page 586 C......Page 599 D......Page 607 E......Page 622 F......Page 626 G......Page 627 H......Page 628 I......Page 634 K......Page 635 L......Page 638 M......Page 639 N......Page 645 O......Page 647 P......Page 650 R......Page 656 S......Page 659 T......Page 661 U......Page 664 Z......Page 665

Recognising the need for a cost effective reference work that deals not only with the most popular reagents in synthesis but also reaches the widest possible audience of practising organic chemists, the editors of 'The Encyclopedia of Reagents for Organic Synthesis' (EROS) have developed a list of the most important and useful reagents employed in the field, conveniently presented in four separate volumes.

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Handbook of Reagents for Organic Synthesis Reagents, Auxiliaries and Catalysts for C-C Bond Formation Robert M. Coates and Scott E. Denmark The University of Illinois, Urbana, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors, of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. The Handbook of Reagents for Organic Synthesis; Reagents Auxiliaries and Catalysts for C-C Bond Formation, provides practical and concise information on a diverse group of reagents. To familiarise the user with the spectrum of reagents contained within this volume, the editors have subdivided more than 200 entries into 22 classes based on their chemical structures and function. The articles, arranged alphabetically, contain all of the information found in EROS as well as expanded reagents listings. In addition, new listings of recently published review articles and monographs are included, as well as relevant Organic Syntheses procedures that deal with either the preparations or reactions of the featured reagents. This comprehensive and well referenced handbook will prove of great value to all practitioners in the field of organic chemistry.

Derived from the renowned, Encyclopedia of Reagents for Organic Synthesis (EROS), the related editors have created a new handbook which focuses on chiral reagents used in asymmetric synthesis and is designed for the chemist at the bench. This new handbook follows the same format as the Encyclopedia, including an introduction and an alphabetical arrangement of the reagents.

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Recognising the critical need for bringing a handy reference work that deals not only with the most popular reagents in synthesis to the laboratory of practising organic chemists, the editors of the acclaimed 'Encyclopedia of Reagents for Organic Synthesis' (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis.

This book presents articles on the most fundamental and versatile reagents for effecting organic transformations that were originally included in EROS. In selecting candidate entries for inclusion in this particular collection, the editors adopted a broad set of criteria for defining what exactly constitutes an acidic or basic reagent.

Each article contains all of the information found in EROS as well as expanded related reagents listings. Additional new listings of recently published review articles and monographs are included, as well as relevant 'Organic Syntheses' procedures that deal with either the preparations or reactions of the featured reagents. This thorough and comprehensive handbook will have widespread appeal.

Oxidizing and Reducing Agents S. D. Burke University of Wisconsin at Madison, USA R. L. Danheiser Massachusetts Institute of Technology, Cambridge, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. Handbook of Reagents for Organic Oxidizing and Reducing Agents, provides the synthetic chemist with a convenient compendium of information concentrating on the most important and frequently employed reagents for the oxidation and reduction of organic compounds, extracted and updated from EROS. The inclusion of a bibliography of reviews and monographs, a compilation of Organic Syntheses procedures with tested experimental details and references to oxidizing and reducing agents will ensure that this handbook is both comprehensive and convenient.

Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis.

Handbook of Reagents for Organic Synthesis: Oxidizing and Reducing Agents, provides the synthetic chemist with a convenient compendium of information concentrating on the most important and frequently employed reagents for the oxidation and reduction of organic compounds, extracted and updated from EROS. The inclusion of a bibliography of reviews and monographs, a compilation of Organic Syntheses procedures with tested experimental details and references to oxidizing and reducing agents will ensure that this handbook is both comprehensive and convenient.

[1] Reagents, auxiliaries, and catalysts for C-C bond formation / edited by Robert M. Coates and Scott E. Denmark [2] Oxidizing and reducing agents / edited by Steven D. Burke and Rick L. Danheiser [3] Acidic and basic reagents / edited by Hans J. Reich and James H. Rigby [4] Activating agents and protecting groups / edited by Anthony J. Pearson and William R. Roush [5] Chiral reagents for asymmetric synthesis / edited by Leo A. Paquette [6] Reagents for high-throughput solid-phase and solution-phase organic synthesis / edited by Peter Wipf All of us are aware of the sharp increase in demand for enantiomerically pure reagents and products that has transpired over the past twenty-five years or so. "Erythro-Directed Reduction of a B-Keto Amide: erythro-1-(3-Hydroxy-2-methyl-3-phenylpropanoyl)piperidine," Fujita, M.: Hiyama, T. Org. Synth. 1990, 69, 44. Aluminum turnings (oil-free) are etched with dilute Sodium Hydroxide to a point of strong hydrogen evolution and the solution is decanted.