پیوندهای شیمیایی و انرژی پیوندها

Chemical Bonds and Bonds Energy, Second Edition provides information pertinent to the fundamental aspects of contributing bond energy and bond dissociation energy. This book explores the values that are useful in the interpretation of significant phenomena such as product distribution and reaction mechanisms. Organized into 12 chapters, this edition begins with an overview of the quantitative relationship among three basic properties of an atom, namely, nonpolar covalent radius, electronegativity, and homonuclear single covalent bond energy. This text then examines the quantitative means of evaluating the partial atomic charges that result from initial differences in the electromagnetivity of atoms that form a compound. Other chapters consider the recognition of the reduction of bond weakening not by multiplicity and in certain types of single covalent bonds. The final chapter deals with the application of the principal ideas and techniques to the oxidation of ethane. This book is a valuable resource for organic and inorganic chemists. Content: Front Matter Page iii Copyright page Page iv Preface Pages ix-x Preface to First Edition Pages xi-xii ONE - The Delightful Science of Chemistry: A Preview of a New View Pages 1-25 TWO - Significant Atomic Properties of the Chemical Elements Pages 26-51 THREE - Selected Values of Atomic Properties Pages 52-68 FOUR - The Physical States of Nonmetals Pages 69-74 FIVE - Polar Covalence I: Electronegativity Equalization, Partial Charge, and Bond Length Pages 75-94 SIX - Polar Covalence II: The Calculation of Polar Bond Energy Pages 95-110 SEVEN - Chemical Combinations of Hydrogen Pages 111-122 EIGHT - The Chemical Behavior of Oxygen Pages 123-141 NINE - Halide Chemistry Pages 142-155 TEN - Bond Dissociation Pages 156-176 ELEVEN - Chemical Bonds in Organic Compounds Pages 177-191 TWELVE - Summary: Application to the Oxidation of Ethane Pages 192-204 Table of Logarithms Page 205 Index Pages 207-218 Physical Chemistry: A Series of Monographs Pages ibc1-ibc2 R. T. Sanderson. Includes Bibliographical References And Index.