Bio-inorganic hybrid nanomaterials : strategies, syntheses, characterization and applications

This ready reference is the first to collate the interdisciplinary knowledge from materials science, bioengineering and nanotechnology to give an in-depth overview of the topic. As such, it provides broad coverage of combinations between inorganic materials and such key biological structures as proteins, enzymes, DNA, and other biopolymers. With its treatment of various application directions, including bioelectronic interfacing, tissue repair, porous membranes, sensors, nanocontainers, and DNA engineering, this is essential reading for materials engineers, medical researchers, catalytic chemists, biologists, and those working in the biotechnological and semiconductor industries. Cover Page......Page 1 Further Reading......Page 3 Title: Bio-inorganic Hybrid Nanomaterials - Strategies, Syntheses, Characterization and Applications......Page 4 ISBN 978-3527317189......Page 5 Contents (with page links)......Page 6 Preface......Page 14 Contributors......Page 16 1.1 Introduction: The Assembly of Biological Species to Inorganic Solids......Page 20 1.2 Bio-nanohybrids Based on Silica Particles and Siloxane Networks......Page 23 1.3 Calcium Phosphates and Carbonates in Bioinspired and Biomimetic Materials......Page 28 1.4 Clay Minerals and Organoclay Bio-nanocomposites......Page 32 1.5 Bio-Nanohybrids Based on Metal and Metal Oxide Nanoparticles......Page 39 1.6 Carbon-based Bio-nanohybrids......Page 41 1.7 Bio-nanohybrids Based on Layered Transition Metal Solids......Page 47 1.8 Trends and Perspectives......Page 50 Acknowledgements......Page 51 2.1 Introduction......Page 60 2.2 Monolayer on Solid Support......Page 64 2.3 Layered Alkylsiloxane......Page 72 2.4 Organic—Inorganic Hybrid Vesicle ‘‘Cerasome’’......Page 78 2.5 Mesoporous Silica Prepared by the Lizard Template Method......Page 84 2.6 Future Perspectives......Page 88 Acknowledgment......Page 90 3.1 Introduction......Page 94 3.2 Sol—Gel Processes......Page 96 3.3 Biocompatible Approaches......Page 103 3.4 One-Stage Approach Based on a Silica Precursor with Ethylene Glycol Residues......Page 107 Notes......Page 121 4.1 Introduction......Page 132 4.2 Immobilization of Protein on Mesoporous Silica......Page 135 4.3 Immobilization of Protein on Mesoporous Carbon and Related Materials......Page 143 4.4 Immobilization of Other Biopolymers on Mesoporous Materials......Page 152 4.5 Immobilization of Small Biomolecules on Mesoporous Materials......Page 156 4.6 Advanced Functions of Nanohybrids of Biomolecules and Mesoporous Materials......Page 160 Acknowledgment......Page 168 5.1 Introduction......Page 178 5.2 Biomimetic Approaches......Page 179 5.3 In vitro Synthesis of Hybrid Nanomaterials......Page 184 5.4 Perspectives: Towards a ‘‘Green Nanochemistry’’......Page 202 6.1 Introduction......Page 212 6.2 Fundamental Concept of Bioinspired Approach......Page 216 6.3 Alternate Soaking Process for Biomineralization and their Bio-functions......Page 218 6.4 Electrophoresis Process for Biomineralization......Page 222 6.5 Conclusions......Page 225 7.2 Porous Materials......Page 228 7.3 LbL Assembly......Page 232 7.4 LbL Assembly on MS Substrates......Page 233 7.5 LbL Assembly on Macroporous Substrates......Page 244 7.6 Summary and Outlook......Page 251 References......Page 252 8.1 Introduction......Page 258 8.2 Synthesis and Characterization of Organically Functionalized 2:1 Magnesium Phyllosilicates......Page 259 8.3 Magnesium Organophyllosilicates with Higher-order Organization......Page 262 8.4 Intercalation of Biomolecules within Organically Modi.ed Magnesium Phyllosilicates......Page 265 8.5 Hybrid Nanostructures Based on Organoclay Wrapping of Single Biomolecules......Page 273 8.6 Functional Mesolamellar Bio-inorganic Nanocomposite Films......Page 279 References......Page 281 9.1 Introduction......Page 290 9.2 Nano-structure Development......Page 291 9.3 Control of Nanostructure Properties......Page 301 9.4 Physicochemical Phenomena......Page 309 9.5 Foam Processing using Supercritical CO......Page 315 9.6 Porous Ceramic Materials via Nanocomposites......Page 326 9.7 Future Prospects......Page 328 References......Page 329 10.1 Introduction......Page 332 10.2 Molecular Recognition-based Hybrid Membranes......Page 333 10.3 Self-organized Hybrid Membrane Materials......Page 337 10.4 Dynamic Site Complexant Membranes......Page 349 Acknowledgement......Page 352 References......Page 353 11.1 Introduction......Page 358 11.2 Composite of Bioactive Ceramic Particles and Polymers......Page 359 11.3 Bone-bonding Mechanism of Bioactive Materials......Page 360 11.4 Sol—Gel-derived Bioactive Nano-hybrids......Page 364 11.5 Nano-hybrid Consisting of Bone-like Hydroxyapatite and Polymer......Page 373 11.6 Nano-hybrid Consisting of Hydroxyapatite and Protein......Page 379 References......Page 380 12.1 Introduction......Page 386 12.2 Bone: A Biological Hybrid Nanostructured Material......Page 388 12.3 Biomimetic Materials for Bone Repair. The Hybrid Approach......Page 391 12.4 Synthesis and Properties of Organic—Inorganic Hybrid Materials for Bone and Dental Applications......Page 394 12.5 Conclusion......Page 411 References......Page 412 13.1 Introduction......Page 420 13.2 Synthesis of Bio-inorganic Conjugates......Page 422 13.3 Bio-inorganic Conjugate for Efficient Gene Delivery......Page 426 13.4 Bio-inorganic Conjugate for Efficient Drug Delivery......Page 428 13.5 Cellular Uptake Mechanism of LDH......Page 431 References......Page 434 14.1 Halloysite Structural Characterization......Page 438 14.2 Macromolecule Loading and Sustained Release......Page 441 14.3 Nanoassembly on Tubules and at the Lumen Opening......Page 447 14.4 Catalysis in a Nanoconstrained Volume of the Tubule Lumen......Page 450 14.5 Multilayer Halloysite Assembly for Organized Nano.lms. Forming Low Density Tubule Nanoporous Materials......Page 455 14.6 Applications: Current and Potential......Page 457 References......Page 458 15.1 Introduction......Page 462 15.2 Enzymes versus Inorganic Host Properties......Page 464 15.3 Immobilization Strategy......Page 465 15.4 Bioinorganic Nanohybrids......Page 473 15.5 Enzyme—Host Structure Interactions......Page 490 References......Page 495 A......Page 504 B......Page 505 C......Page 507 D......Page 508 F......Page 509 H......Page 510 I......Page 511 L......Page 512 M......Page 513 O......Page 515 P......Page 516 R......Page 518 S......Page 519 T......Page 521 Y,Z......Page 522 Introduction to hybrid materials / Guido Kickelbick Nanocomposites of polymers and inorganic particles / Walter Caseri Hybrid organic/inorganic particles / Elodie Bourgeat-Lami Intercalation compounds and clay nanocomposites / Jin Zhu and Charles A. Wilkie Porous hybrid materials / Nicola Hüsing Sol-gel processing of hybrid organic-inorganic materials based on polysilsesquioxanes / Douglas A. Loy Natural and artificial hybrid biomaterials / Heather A. Currie ... [et al.] Medical applications of hybrid materials / Kanji Tsuru, Satoshi Hayakawa, and Akiyoshi Osaka Hybrid materials for optical applications / Luís António Dias Carlos, R.A. Sá Ferreira and V. de Zea Bermudez Electronic and electrochemical applications of hybrid materials / Jason E. Ritchie Inorganic/organic hybrid coatings / Mark D. Soucek "This ready reference is the first to collate the interdisciplinary knowledge from materials science, bioengineering and nanotechnology to give an in-depth overview of the topic. As such, it provides broad coverage of combinations between inorganic materials and such key biological structures as proteins, enzymes, DNA, and other biopolymers. With its treatment of various application directions, including bioelectronic interfacing, tissue repair, porous membranes, sensors, nanocontainers, and DNA engineering, this is essential reading for materials engineers, medical researchers, catalytic chemists, biologists, and those working in the biotechnological and semiconductor industries."--Jacket

Hybrid materials have currently a great impact on numerous future developments including nanotechnology. This book presents an overview about the different types of materials, clearly structured into synthesis, characterization and applications. A perfect starting point for everyone interested in the field, but also for the specialist as a source of high quality information.

Hybrid materials consist of both organic and inorganic components. They may offer a desired functionality or superior characteristics compared to their building blocks or other, simpler materials if the components are well chosen. Such materials are currently having a great impact on numerous future developments, including nano-technology Delivers the essence of nanocomposite technology from the perspective of applications. This book features chapters on functionalities and syntheses and processing, as well as material on the properties of polymer and bioactive nanocomposites, and the design and modeling aspects of nanocomposites. Filling the gap for a compact text that presents the topic from a general point of view while adopting a didactic approach, Hybrid Materials provides an overview of the different types of materials, clearly structured into synthesis, characterization and applications. These 10 volumes provide an excellent, in-depth overview of all nanoscale technologies and fabrication methods in materials engineering towards the life sciences. Each volume covers a specific topic, reviewing existing technologies as well as current developments.