Advances in materials science for environmental and energy technologies IV : ceramic transactions, volume 253

This proceedings contains a collection of 20 papers from the following five 2014 Materials Science and Technology (MS&T'14) symposia: Materials Issues in Nuclear Waste Management in the 21st Century Green Technologies for Materials Manufacturing and Processing V Nanotechnology for Energy, Healthcare and Industry Materials for Processes for CO 2 Capture, Conversion, and Sequestration Materials Development for Nuclear Applications and Extreme Environments TITLE PAGE 2 COPYRIGHT 3 PREFACE 19 MATERIALS ISSUES IN NUCLEAR WASTE MANAGEMENT 20 UPTAKE OF URANIUM BY TUNGSTIC ACID 21 ABSTRACT 21 INTRODUCTION 21 EXPERIMENTAL 22 RESULTS AND DISCUSSION 24 CONCLUSIONS 29 REFERENCES 30 ELECTRICAL CONDUCTIVITY METHOD FOR MONITORING ACCUMULATION OF CRYSTALS 32 ABSTRACT 32 INTRODUCTION 32 MATERIALS AND METHODS 33 RESULTS AND DISCUSSION 37 CONCLUSIONS 40 ACKNOWLEDGEMENTS 41 REFERENCES 41 CRYSTALLIZATION IN HIGH LEVEL WASTE (HLW) GLASS MELTERS: SAVANNAH RIVER SITE OPERATIONAL EXPERIENCE 43 ABSTRACT 43 INTRODUCTION 43 HISTORICAL OVERVIEW 45 DWPF MELTER 2 OPERATING DATA 53 SUMMARY 55 FOOTNOTES 56 REFERENCES 56 SCOPING MELTING STUDIES OF HIGH ALUMINA WASTE GLASS COMPOSITIONS 61 ABSTRACT 61 INTRODUCTION 61 EXPERIMENTAL APPROACH 62 RESULTS 65 DISCUSSION 72 CONCLUSIONS 73 ACKNOWLEDGEMENTS 74 REFERENCES 74 RESEARCH-SCALE MELTER: AN EXPERIMENTAL PLATFORM FOR EVALUATING CRYSTAL ACCUMULATION IN HIGH-LEVEL WASTE GLASSES 75 ABSTRACT 75 INTRODUCTION 75 MATERIALS 76 METHODS 77 RESULTS AND DISCUSSION 79 CONCLUSIONS 82 ACKNOWLEDGEMENTS 83 REFERENCES 83 CHARACTERIZATION OF HIGH LEVEL NUCLEAR WASTE GLASS SAMPLES FOLLOWING EXTENDED MELTER IDLING 84 ABSTRACT 84 INTRODUCTION 85 MELTER GLASS SAMPLING 86 MELTER CONDITIONS DURING IDLING 89 MELTER GLASS CHARACTERIZATION 91 DISCUSSION AND CONCLUSIONS 96 REFERENCES 97 SYNTHESIS OF MINERAL MATRICES BASED ON ENRICHED ZIRCONIUM PYROCHLORE FOR IMMOBILIZATION OF ACTINIDE-CONTAINING WASTE 101 ABSTRACT 101 INTRODUCTION 101 EXPERIMENTAL PROCEDURE 102 RESULTS AND DISCUSSION 104 CONCLUSION 109 REFERENCES 110 CORROSION EVALUATION OF MELTER MATERIALS FOR RADIOACTIVE WASTE VITRIFICATION 112 ABSTRACT 112 INTRODUCTION 112 DWPF MELTER DESIGN OVERVIEW 114 SCALED MELTER TESTING 117 DETERMINATION OF MELTER LIFETIME 122 CONCLUSION 125 REFERENCES 126 GREEN TECHNOLOGIES FOR MATERIALS MANUFACTURING AND PROCESSING 130 GREEN FLAME RETARDANT BASED ON A CERAMIC PRECURSOR 131 ABSTRACT 131 INTRODUCTION 131 EXPERIMENTAL 133 RESULTS AND DISCUSSION 135 CONCLUSION 138 ACKNOWLEDGEMENT 139 REFERENCES 139 SINGLE-SOURCE PRECURSOR APPROACH TO BARIUM DIMOLYBDATE 141 ABSTRACT 141 INTRODUCTION 141 EXPERIMENTAL 142 RESULTS AND DISCUSSION 144 CONCLUSION 148 ACKNOWLEDGEMENTS 149 REFERENCES 149 EFFECTS ON BIOMASS CHAR ADDITION ON COMBUSTION PROCESS OF PULVERIZED COAL 151 ABSTRACT 151 INTRODUCTION 151 EXPERIMENT 152 RESULTS AND DISCUSSION 153 CONCLUSIONS 157 ACKNOWLEDGEMENTS 158 REFERENCES 158 A COMPARATIVE ANALYSIS FOR CHARPY IMPACT ENERGY IN POLYESTER COMPOSITES REINFORCED WITH MALVA, RAMIE AND CURAUA FIBERS 160 ABSTRACT 160 INTRODUCTION 160 XPERIMENTAL PROCEDURE 161 RESULTS AND DISCUSSION 162 CONCLUSIONS 164 ACKNOWLEDGEMENTS 165 REFERENCES 165 RESEARCH ON SIMULTANEOUS INJECTION OF WASTE TIRES WITH PULVERIZED COAL FOR BLAST FURNACE 168 ABSTRACT 168 INTRODUCTION 168 RESEARCH OF THE BASIC PERFORMANCE OF COAL 170 RESEARCH OF THE WASTE TIRE 172 FEASIBILITY ANALYSIS OF INJECTING COAL MIXING WITH WASTE TIRES 173 CONCLUSIONS 176 ACKNOWLEDGEMENT 177 REFERENCES 177 RESEARCH ON USING BLAST FURNACE SLAG TO PRODUCE BUILDING STONE 178 ABSTRACT 178 INTRODUCTION 178 EXPERIMENTAL 179 CHARACTERIZATION 180 RESULTS AND DISCUSSION 180 DISCUSSION OF THE EFFECT OF COOLING CONDITION 182 CONCLUSION 184 ACKNOWLEDGEMENT 185 REFERENCES 185 A GREEN LEACHING METHOD OF DECOMPOSING SYNTHETIC CaWO4 BY HCI-H3PO4 IN TUNGSTEN PRODUCING PROCESS 187 ABSTRACT 187 INTRODUCTION 187 EXPERIMENT 188 RESULTS AND DISCUSSION 191 CONCLUSIONS 194 REFERENCES 195 NANOTECHNOLOGY FOR ENERGY, HEALTHCARE AND INDUSTRY 196 SYNTHESIS OF COATED NANO CALCIUM CARBONATE PARTICLES AND THEIR CHARACTERIZATION 197 ABSTRACT 197 INTRODUCTION 197 EXPERIMENTAL 198 RESULTS AND DISCUSSION 198 CONCLUSIONS 203 ACKNOWLEDGEMENT 203 REFERENCES 203 SYNTHESIS OF TiO2 NANOSTRUCTURES VIA HYDROTHERMAL METHOD 205 ABSTRACT 205 INTRODUCTION 205 EXPERIMENTAL 206 RESULTS AND DISCUSSION 208 CONCLUSION 210 ACKNOWLEDGEMENT 211 REFERENCES 211 CARBON NANOTUBE-BASED IMPEDIMETRIC BIOSENSORS FOR BONE MARKER DETECTION 213 ABSTRACT 213 INTRODUCTION 213 METHODOLOGY 215 RESULTS & DISCUSSION 216 CONCLUSION 219 ACKNOWLEDGEMENTS: 220 REFERENCES 220 MATERIALS AND PROCESSES FOR CO2 CAPTURE, CONVERSION, AND SEQUESTRATION 222 HIGH CO2 PERMEATION FLUX ENABLED BY AL2O3MODIFIER AND IN-SITU INFILTRATION OF MOLTEN CARBONATE INTO GD-DOPED CEO2 AS A CO2 SEPARATION MEMBRANE 223 ABSTRACT 223 INTRODUCTION 223 EXPRIMENTAL 224 RESULTS AND DISCUSSION 226 CONCLUSIONS 230 ACKNOWLEDGEMENT 230 REFERENCES 230 MATERIALS DEVELOPMENT FOR NUCLEAR APPLICATIONS AND EXTREME ENVIRONMENTS 232 SUPERPLASTICITY IN CERAMICS AT HIGH TEMPERATURE 233 ABSTRACT 233 1. INTRODUCTION 233 2. MICROSTRUCTURAL DESIGNS FOR ACHIEVING HIGH STRAIN RATE SUPERPLASTICITY 234 3. SUPERPLASTIC CERAMICS AND CERAMIC COMPOSITES 235 4. CONCLUSION 240 REFERENCES: 241 AUTHOR INDEX 245 EULA 248 Content: Preface ix MATERIALS ISSUES IN NUCLEAR WASTE MANAGEMENT Uptake of Uranium by Tungstic Acid 3 Hamed Albusaidi, Cory K. Perkins, and Allen W. Apblett Electrical Conductivity Method for Monitoring Accumulation of Crystals 13 Matthew K. Edwards, Josef Matya , Jarrod V. Crum, Charles C. Bonham, and Michael J. Schweiger Crystallization in High Level Waste (HLW) Glass Melters: Savannah River Site Operational Experience 23 Kevin M. Fox, David K. Peeler, and Albert A. Kruger Scoping Melting Studies of High Alumina Waste Glass Compositions 37 Jared O. Kroll, Michael J. Schweiger, John D. Vienna Research-Scale Melter: An Experimental Platform for Evaluating Crystal Accumulation in High-Level Waste Glasses 49 Josef Matya , Gary J. Sevigny, Michael J. Schweiger, and Albert A. Kruger Characterization of High Level Nuclear Waste Glass Samples Following Extended Melter Idling 59 David K. Peeler, Kevin M. Fox, and Albert A. Kruger Synthesis of Mineral Matrices Based on Enriched Zirconium Pyrochlore for Immobilization of Actinide-Containing Waste 73 K. Podbolotov and T. Barinova Corrosion Evaluation of Melter Materials for Radioactive Waste Vitrification 83 Marissa M. Reigel, Ken J. Imrich, and Carol M. Jantzen GREEN TECHNOLOGIES FOR MATERIALS MANUFACTURING AND PROCESSING Green Flame Retardant Based on a Ceramic Precursor 99 Bhawani Regmi and Allen W. Apblett Single-Source Precursor Approach to Barium Dimolybdate 109 Ahmed Moneeb Allen W. Apblett, Abdullah Al-Abdulrahman, and Abdulaziz Bagabas Effects on Biomass Char Addition on Combustion Process of Pulverized Coal 117 Yi-ran Liu, Yingli , and Bingchang Li A Comparative Analysis for Charpy Impact Energy in Polyester Composites Reinforced with Malva, Ramie and Curaua Fibers 127 Frederico Muylaert Margem, Andre Raeli Gomes, Luiz Gustavo Xavier Borges, and Sergio Neves Monteiro Research on Simultaneous Injection of Waste Tires with Pulverized Coal for Blast Furnace 135 Bingji Yan, Jianliang Zhang, Hongwei Guo, and Feng Liu Research on using Blast Furnace Slag to Produce Building Stone 145 Bingji Yan, Jianliang Zhang, Hongwei Guo, Zhiwen Shi, and Feng Liu A Green Leaching Method of Decomposing Synthetic CaWO4 by HCl-H3PO4 in Tungsten Producing Process 157 Liang Liu and Jilai Xue NANOTECHNOLOGY FOR ENERGY, HEALTHCARE AND INDUSTRY Synthesis of Coated Nano Calcium Carbonate Particles and their Characterization 169 S. E. Benjamin and Farah Mustafa Synthesis of TiO2 Nanostructures via Hydrothermal Method 177 Nursev Bilgin, Lutfi Agartan, Jongee Park, and Abdullah Ozturk Carbon Nanotube-Based Impedimetric Biosensors for Bone Marker Detection 187 Mitali Patil, Madhumati Ramanathan, Vesselin Shanov, and Prashant N. Kumta MATERIALS AND PROCESSES FOR CO2 CAPTURE, CONVERSION, AND SEQUESTRATION High CO2 Permeation Flux Enabled by Al2O3 Modifier and In-Situ Infiltration of Molten Carbonate into Gd-Doped CeO2 as a CO2 Separation Membrane 197 Jingjing Tong, Zachary Bills, Lingling Zhang, Jie Fang, Minfang Han, and Kevin Huang MATERIALS DEVELOPMENT FOR NUCLEAR APPLICATIONS AND EXTREME ENVIRONMENTS Superplasticity in Ceramics at High Temperature 207 Michael Opoku, Raghunath Kanakala, and Indrajit Charit Author Index 219 "The Materials Science and Technology 2014 Conference and Exhibition (MS & T'14) was held October 12-16, 2014 at the David L. Lawrence Convention Center, Pittsburgh, Pennsylvania. One of the major themes of the conference was Environmental and Energy Issues. Twenty papers from five symposia are included in this volume. These symposia included Materials Issues in Nuclear Waste Management in the 21st Century; Green Technologies for Materials Manufacturing and Processing VI; Nanotechnology for Energy, Healthcare and Industry; Materials and Processes for CO2 Capture, Conversion, and Sequestration; and Materials Development for Nuclear Applications and Extreme Environments."--Preface This proceedings contains a collection of 26 papers from the following six 2013 Materials Science and Technology (MS & T'13) symposia: Green Technologies for Materials Manufacturing and Processing V ; Materials Development and Degradation Management in Nuclear Applications ; Materials Issues in Nuclear Waste Management in the 21st Century ; Energy Storage III: Materials, Systems and Applications ; Nanotechnology for Energy, Healthcare and Industry ; Hybrid Organic-Inorganic Materials for Alternative Energy This proceedings contains a collection of 20 papers from the following five 2014 Materials Science and Technology (MS&T’14) symposia: Materials Issues in Nuclear Waste Management in the 21 st Century Green Technologies for Materials Manufacturing and Processing V Nanotechnology for Energy, Healthcare and Industry Materials for Processes for CO 2 Capture, Conversion, and Sequestration Materials Development for Nuclear Applications and Extreme Environments This proceedings contains a collection of 20 papers from the following five 2014 Materials Science and Technology (MS & T'14) symposia: -Materials Issues in Nuclear Waste Management in the 21st Century -Green Technologies for Materials Manufacturing and Processing V -Nanotechnology for Energy, Healthcare and Industry -Materials for Processes for CO2 Capture, Conversion, and Sequestration -Materials Development for Nuclear Applications and Extreme Environments